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Caesium substitution in the titanate hollandites Ba x Cs y (Ti 3+ y +2 x Ti 4+ 8−2 x - y )O 16 from 5 to 400 K

R. W. Cheary1991-06-01Acta Crystallographica Section B Structural Science

Les parametres cristallins a et c augmentent avec la concentration en Cs depuis a=10,1688 et c=2,9595 A dans Cs 0,40 Ba 0,79 Ti 8 O 16 a 5 K jusqu'a a=10,2682 et c=2,9643 A dans Cs 1,36 Ti 8 O 16 a 5 K. La dilatation est isotope seulement dans Cs 1,36 Ti 8 O 16 avec 8.10 −6 K −1 a 300 K. Etude de l'influence de la pre…

Crystal Structures and PropertiesMicrowave Dielectric Ceramics SynthesisNuclear materials and radiation effects

Fourier transform infrared study of amorphous N2O4 solid: Destabilization with inert impurities

A. Givan、A. Loewenschuss1991-06-01The Journal of Chemical Physics

Amorphous N2O4 solid was formed on predeposited oxygen or krypton layers. Evaporation of the underlying layer and redeposition of the inert impurities resulted in decomposition of the ionic nitrosonium nitrate clusters within the solid nitrogen tetroxide. Infrared features indicate NO+NO−3 decomposition to occur via m…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsGas Sensing Nanomaterials and Sensors

Modulation of partial discharge activity in GIS insulators by X-ray irradiation

J.M. Braun、S. Rizzetto、Noboru Fujimoto 等 4 位作者1991-06-01IEEE Transactions on Electrical Insulation

A system was assembled which can perform high-sensitivity partial discharge (PD) measurements under combined electric stress and X-ray irradiation on 138-kV class gas-insulated switchgear (GIS) post insulators. Under X-ray irradiation, the PD pulse repetition rate is increased and the discharge inception voltage (DIV)…

Semiconductor materials and devicesHigh voltage insulation and dielectric phenomenaGa2O3 and related materials

Constitution of Ti–Al–C alloys in temperature range 1250–750°C

Gürel Çam、H. M. Flower、D. R. F. West1991-06-01Materials Science and Technology

An investigation has been made of the solid state constitution of the titanium rich portion of the Ti–Al–C system; partial isothermal sections have been established at 1250, 1050, and 750°C by means of electron microscopy (including energy dispersive X-ray analysis) and X-ray diffraction. In addition, a schematic liqu…

Aluminum Alloys Composites PropertiesIntermetallics and Advanced Alloy PropertiesMXene and MAX Phase Materials

Crystal structure of native cellulose

Yasuhiro Takahashi、Hideki Matsunaga1991-06-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCrystal structure of native celluloseYasuhiro Takahashi and Hideki MatsunagaCite this: Macromolecules 1991, 24, 13, 3968–3969Publication Date (Print):June 1, 1991Publication History Published online1 May 2002Published inissue 1 June 1991https://pubs.acs.org/doi/10.1021/ma000…

Advanced Cellulose Research StudiesLignin and Wood Chemistry

Research and Development of HTTR Coated Particle Fuel

Kousku FUKUDA、Toru OGAW、K. Hayashi 等 9 位作者1991-06-01Journal of Nuclear Science and Technology

The coated particle fuel has been developed within a framework of the HTTR (High Temperature engineering Test Reactor) Development Program at the Japan Atomic Energy Research Institute. The HTTR fuel is a prismatic block type containing TRISO-coated U02 particles. Research and development on the fuel has been progress…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesNuclear and radioactivity studies

X‐ray Photoelectron Spectroscopy Study of High‐ and Low‐Temperature Forms of Zirconium Titanate

Hiroyuki Ikawa、Toshiyuki Yamada、Kenji Kojima 等 4 位作者1991-06-01Journal of the American Ceramic Society

X‐ray photoelectron spectroscopy (XPS) spectra were measured for the high‐temperature forms (quenched from 1500°C) of zirconium titanate and its solid solutions, the low‐temperature forms (quenched from 1000°C), and cubic Ba(Zr 1/2 Ti 1/2 )O 3 . Two distinct differences in the XPS spectra were noted between the high‐…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisMicrowave Dielectric Ceramics Synthesis

An environmental cell transmission electron microscope

T. C. Lee、D.K. Dewald、J. Eades 等 5 位作者1991-06-01Review of Scientific Instruments

An aperture-limited, differentially pumped environmental cell has been developed and installed in a JEOL 4000 EX electron microscope. With this environmental cell it is possible to observe, at high spatial resolution, the detailed changes in microstructure that occur during the interaction between a solid and a gaseou…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Optical properties of dilute hydrogen tungsten bronze thin films

Mino Green、Zahid Hussain1991-06-01Journal of Applied Physics

Transmission and reflection spectra in the range of 0.5–4.1 eV have been obtained for HxWO3 polycrystalline thin films of 5-nm mean grain size. The composition range x=0–0.16 has been investigated. The measurements were refined to give the absorption coefficient and other optical parameters versus photon energy. The d…

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Dissolution Rates of Silicate Glasses in Water at pH 7

Gunarathna Perera、Robert H. Doremus、W. A. Lanford1991-06-01Journal of the American Ceramic Society

Dissolution rates of different glasses in buffered solutions of constant pH of 7 were measured by weight change, profilometry, and ion implantation with Rutherford backscattering. Rates with different techniques agreed within experimental error. Natural obsidian glass dissolved most slowly, at a rate comparable with t…

Glass properties and applicationsBuilding materials and conservationClay minerals and soil interactions

Equilibrium between homocub-1(9)-ene and homocub-9-ylidene

Ning Chen、Maitland Jones、Walter White 等 4 位作者1991-06-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEquilibrium between homocub-1(9)-ene and homocub-9-ylideneNing Chen, Maitland Jones Jr., Walter R. White, and Matthew S. PlatzCite this: J. Am. Chem. Soc. 1991, 113, 13, 4981–4992Publication Date (Print):June 1, 1991Publication History Published online1 May 2002Published ini…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistrySurface Chemistry and Catalysis

Electronic structure and magnetism ofSrFeO3andSrCoO3

S. Mathi Jaya、R. Jagadish、Rekha Rao 等 4 位作者1991-06-01Physical review. B, Condensed matter

The electronic-structure calculations of the perovskite oxides ${\mathrm{SrFeO}}_{3}$ and ${\mathrm{SrCoO}}_{3}$ in the nonmagnetic and magnetic phases are reported here. The calculations were performed with use of the self-consistent linear muffin-tin-orbital method within the atomic-sphere approximation. The calcula…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsThermal Expansion and Ionic Conductivity

Local Structure of Alkaline‐Earth Boroaluminate Crystals and Glasses: I, Crystal Chemical Concepts—Structural Predictions and Comparisons to Known Crystal Structures

Bruce C. Bunker、R. James Kirkpatrick、Richard K. Brow1991-06-01Journal of the American Ceramic Society

This paper presents a model which predicts glass structures based on local charge balance considerations. The model is shown to be consistent with known structures of borate, aluminate, and boroaluminate crystals and predicts that boroaluminate glasses should contain 3‐ and 4‐coordinate boron, 4‐, 5‐, and 6‐coordinate…

Glass properties and applicationsAdvanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallography

Analytic evaluation of field emission enhancement factors for ellipsoidal cones and elliptic cross-section wedges

H. G. Kosmahl1991-06-01IEEE Transactions on Electron Devices

An unambiguous comparison for the magnification factor, M, in field emission is derived by solving rigorously Laplace equations for the cases of individual prolate ellipsoids (cones) of revolution on one side, and for an elliptical wedge on the other side, under the assumption that a uniform electric field exists at s…

Carbon Nanotubes in CompositesGraphene research and applicationsMechanical and Optical Resonators

Mineralogy, geochemistry, and origin of Pacific red clays: A review

G.P. Glasby1991-06-01New Zealand Journal of Geology and Geophysics

Abstract Pacific red clays are dominantly allogenic in origin. The allogenic component is derived principally from aeolian dust from central Asia, Australia, and Central America. The highest input of dust is from central Asia. Sedimentation rates of red clays are therefore higher in the North Pacific than in the South…

Heavy metals in environmentGeochemistry and Elemental AnalysisClay minerals and soil interactions

Kaolinite–Mullite Reaction Series: The Development and Significance of a Binary Aluminosilicate Phase

A. K. Chakravorty、Dilip K. Ghosh1991-06-01Journal of the American Ceramic Society

The semiquantitative estimations of 980°C exothermic reaction products of kaolinite by quantitative X‐ray diffraction (QXRD) and chemical leaching techniques show the formation of a significant amount of amorphous aluminosilicate phase (∼ 30 to 40 wt%). The theoretically expected AlO 4 /AlO 6 ratio in the 980°C reacti…

Advanced ceramic materials synthesisGlass properties and applicationsRecycling and utilization of industrial and municipal waste in materials production

Effect of thermal curing on the structures and properties of aromatic polyimide films

Jwo‐Huei Jou、Peir Teh Huang1991-06-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEffect of thermal curing on the structures and properties of aromatic polyimide filmsJwo Huei Jou and Peir Teh HuangCite this: Macromolecules 1991, 24, 13, 3796–3803Publication Date (Print):June 1, 1991Publication History Published online1 May 2002Published inissue 1 June 19…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Microstructural evolution in nickel during rolling and torsion

D.A. Hughes、N. Hansen1991-06-01Materials Science and Technology

Microstructural evolution in high purity nickel was investigated by comparing the dislocation substructures formed following torsion deformation with those following rolling. Results from transmission electron microscopy observations and measurements of microdiffraction show a common evolutionary path in rolling and t…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsMetallurgy and Material Forming

The structure of cimetidine (C10H16N6S) solved from synchrotron-radiation X-ray powder diffraction data

Robert J. Cernik、Anthony K. Cheetham、C. K. Prout 等 6 位作者1991-06-01Journal of Applied Crystallography

The crystal structure of cimetidine (C10H16N6S) has been solved and refined from high-resolution synchrotron X-ray powder data collected on station 8.3 at Daresbury Laboratory. The structure is monoclinic, P21/n, Z = 4, a = 10.7029 (3), b = 18.8262 (1), c = 6.8266 (2) Å, β = 111.306 (2)°. The data were auto-indexed an…

Crystallography and molecular interactionsX-ray Diffraction in CrystallographyPolymer Synthesis and Characterization

Polymer alloys and blends: Recent advances

Basil D. Favis1991-06-01The Canadian Journal of Chemical Engineering

Abstract Polymer alloys and blends represent one of the fastest growing sectors of the plastics industry. To a large degree, the emphasis has now shifted from developing blends in the reactor to their creation through melt mixing on processing equipment such as extruders. As a result, intense activity is now being dir…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies