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Thermal behavior and spherulitic superstructures of SBC triblock copolymers based on polystyrene (S), polybutadiene (B) and a crystallizable poly(ε‐caprolactone) (C) block

Vittoria Balsamo、Friederike von Gyldenfeldt、Reimund Stadler1996-10-01Macromolecular Chemistry and Physics

Abstract The dynamic crystallization and the melting behavior of polystyrene‐ block ‐poly(ε‐caprolactone) (PS‐ b ‐PCL, short notation SC), polybutadiene‐ block ‐poly(ε‐caprolactone) (PB‐ b ‐PCL, BC) and polystyrene‐ block ‐polybutadiene‐ block ‐poly(ε‐caprolactone) (PS‐ b ‐PB‐ b ‐PCL, SBC) have been studied using diff…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

High-pressure and temperature dependence of dielectric relaxation in supercooled di-isobutyl phthalate

Marian Paluch、J. Zioło、Sylwester J. Rzoska 等 4 位作者1996-10-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Results are presented for isothermal, high-pressure (up to p=300 MPa), and temperature (under atmospheric pressure) measurements of complex dielectric permittivity in supercooled di-isobutyl phthalate. The relaxation times determined from the temperature study obey the temperature Vogel-Fulcher-Tammann (VFT) law. The…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesPolymer Nanocomposites and Properties

Landau–de Gennes theory of the chevron structure in a smectic liquid crystal

Nataša Vaupotič、Samo Kralj、Martin Čopič 等 4 位作者1996-10-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

The covariant form of the Landau--de Gennes free energy is used to study the chevron structure formed by cooling from the Sm-A to the nonchiral Sm-C phase in a surface-stabilized cell with planar boundary conditions. We show that the chevron is the thermodynamic equilibrium structure. The chevron structure is studied…

Liquid Crystal Research AdvancementsTheoretical and Computational PhysicsPlant Reproductive Biology

Poly(3-hydroxybutyrate) depolymerases bind to their substrate by a C-terminal located substrate binding site

Astrid Behrends、Britta Klingbeil、Dieter Jendrossek1996-10-01FEMS Microbiology Letters

Binding of (i) purified wild-type poly(3-hydroxybutyrate) (PHB) depolymerase PhaZ4 of Pseudomonas lemoignei, (ii) a purified truncated form of PhaZ4, which lacked 55 C-terminal amino acids and (iii) commercial lactate dehydrogenase to aqueous suspensions of PHB, chitin or cellulose was studied. Only the wild-type PHB…

Biofuel production and bioconversionbiodegradable polymer synthesis and propertiesPolyamine Metabolism and Applications

Formation, stability, and properties of in ‐ situ composites based on blends of a thermotropic liquid crystalline polymer and a thermoplastic elastomer

A. G. C. Machiels、K.F.J. Denys、J. van Dam 等 4 位作者1996-10-01Polymer Engineering and Science

Abstract This paper describes the preparation and properties of in‐situ composites based on polymers with no overlap in processing temperatures. The polymers used were Vectra A900, a thermotropic liquid crystalline copolyester (TLCP), and Arnitel em630, a thermoplastic elastomer. Blends were generated by feeding the t…

Liquid Crystal Research AdvancementsPolymer crystallization and propertiesSynthesis and properties of polymers

Optimization of a Ductile‐Particle‐Toughened Ceramic

Xudong Sun、J.A. Yeomans1996-10-01Journal of the American Ceramic Society

The nature of the interfacial bond has a major effect on the degree of toughening that can be achieved in a ductile‐particle‐reinforced ceramic‐matrix composite. The effect of variation of oxygen partial pressure during fabrication on the bonding in an alumina‐nickel composite has been investigated. Calculations sugge…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

Mechanism of photoinduced anisotropy in chalcogenide glasses

Keiji Tanaka、Koichi Ishida、Norimitsu Yoshida1996-10-01Physical review. B, Condensed matter

Structural and optical anisotropies have been investigated in some chalcogenide glasses exposed to illumination of linearly polarized light. X-ray diffraction patterns of illuminated ${\mathrm{As}}_{2}$${\mathrm{S}}_{3}$ manifest a structural modification at \ensuremath{\sim}1 A${\mathrm{\r{}}}^{\mathrm{\ensuremath{-}…

Crystal Structures and PropertiesPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography

Structural variation and phase transformations of decagonal quasicrystals in the Al-Ni-Co system

A.‐P. Tsai1996-10-01Philosophical Magazine Letters

A variation in the structure of the decagonal phase with composition and phase transformations related to the decagonal phase have been observed in Al70Ni30-xCox alloys with x varying from 16 to 24. A decagonal phase with fundamental reflections at Al70Ni24Co6 converts to a (type I) superstructure around Al70Ni18Co12…

Quasicrystal Structures and PropertiesX-ray Diffraction in Crystallography

Organic Radicals Exhibiting Intermolecular Ferromagnetic Interactions with High Probability: 4-Arylmethyleneamino-2,2,6,6-tetramethylpiperidin-1-yloxyls and Related Compounds

Kensuke Togashi、Ron Imachi、K. Tomioka 等 8 位作者1996-10-01Bulletin of the Chemical Society of Japan

Abstract A series of 4-arylmethyleneamino-2,2,6,6-tetramethylpiperidin-1-yloxyls (4-arylmethyleneamino-TEMPO) and related compounds were synthesized, and their magnetic susceptibilities were measured by a SQUID magnetometer in the temperature range of 1.8—100 K. Of 165 radicals investigated, 52 kinds of radicals exhib…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

FTIR spectroscopy of lawsonite between 82 and 325 K

Eugen Libowitzky、George R. Rossman1996-10-01American Mineralogist

Lawsonite single crystals were investigated by polarized FfIR spectroscopy at wave numbers between 8000 and 1000 cm^(-1) and temperatures between 82 and 325 K. This temperature range contains three lawsonite phases-Cmcm > 273 K, 273 K > Pmcn > 150 K, P2_1cn < 150 K-which are characterized by different rota…

High-pressure geophysics and materialsCrystal Structures and PropertiesMineralogy and Gemology Studies

Parameter space representation of liquid crystal display operating modes

Hoi Sing Kwok1996-10-01Journal of Applied Physics

A parameter space approach is used to represent the operation of all liquid crystal displays. The Jones matrix nematic is used to analyze the static optical properties of liquid crystal displays with any twist angle, cell thickness, natural birefringence, and polarizer angles. All the usual display modes such as 90° T…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPhotonic Crystals and Applications

Purification of the Saccharomyces cerevisiae Cleavage/Polyadenylation Factor I

Marco M. Kessler、Jing Zhao、Claire Moore1996-10-01Journal of Biological Chemistry

The cleavage/polyadenylation factor I (CF I) is one of four factors required for mRNA 3' end formation in the yeast Saccharomyces cerevisiae. Here we describe the purification of CF I and its separation into two components, CF IA and CF IB. Both components are needed to reconstitute CF I activity in cleavage and poly(…

biodegradable polymer synthesis and propertiesAmyotrophic Lateral Sclerosis ResearchMicrobial metabolism and enzyme function

Structure and luminescence properties of an amorphous hydrogenated carbon

S. R. P. Silvaf、John Robertson、Rusli Rusli 等 5 位作者1996-10-01Philosophical Magazine B

A low hydrogen content form of amorphous hydrogenated carbon (a-C: H) was deposited from a magnetically confined plasma, for a range of self bias voltages. The structure was characterized in terms of its density, sp3 bonding fraction, H content, and H bonding. The Tauc optical gap was found to vary from 2 to 3 eV as t…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchNonlinear Optical Materials Studies

Rheology of concentrated solutions of poly(γ-benzyl-glutamate)

Gábor Kiss、Roger S. Porter1996-10-01Journal of Polymer Science Part B Polymer Physics

Steady shear viscosity, dynamic viscosity, dynamic modulus, and normal force were measured via rotational rheometry for concentrated solutions of racemic mixtures of poly(benzyl-glutamate) and poly(benzyl-D-glutamate) in m-cresol. A transition from the isotropic state to liquid-crystalline order with increase in conce…

Liquid Crystal Research AdvancementsHydrogels: synthesis, properties, applicationsPolymer crystallization and properties

New Thermostable Systems: Structure/Property Relationships of Nadic Terminated Telechelic Fluorine Polyimides

Marie‐Florence Grenier‐Loustalot、Laurent Billon1996-10-01Polymer International

Polyimides were synthesized by polycondensation of nadic anhydride monoester (NE), hexafluoroisopropylidene-2,2-bis (phthalic acid anhydride) (6HFDA) and Cardo diamine in aprotic/polar medium. After examining the microstructure and the composition of systems with a polymerization index n̄ = 2.075 and 5.18 by high perf…

Synthesis and properties of polymersTribology and Wear AnalysisSilicone and Siloxane Chemistry

Quantitative analysis of alkali feldspar minerals using Rietveld refinement of X-ray diffraction data

Sang‐Heon Shim、Soo Jin Kim、Jung Ho Ahn1996-10-01American Mineralogist

Other| October 01, 1996 Quantitative analysis of alkali feldspar minerals using Rietveld refinement of X-ray diffraction data Sang-Heon Shim; Sang-Heon Shim Seoul National University, Department of Geological Sciences, Seoul, South Korea Search for other works by this author on: GSW Google Scholar Soo Jin Kim; Soo Jin…

Geophysical and Geoelectrical MethodsGeochemistry and Geologic MappingX-ray Diffraction in Crystallography

Laser induced periodic structures in porous silicon

Valentin I. Vlad、A. Petriş、V. Chumash 等 4 位作者1996-10-01Applied Surface Science

Permanent relief holographic gratings with variable modulation depth have been induced in porous Si films using the interference of two beams obtained by a frequency-doubled Nd:YAG laser (γ = 530 nm) and a conventional optical setup. Consequently, the gratings have been confined in the porous Si film and the diffracti…

Semiconductor materials and devicesLaser Material Processing TechniquesSilicon Nanostructures and Photoluminescence

Neue Einsichten zur Stabilisierung des Hulsit-Strukturtyps am Beispiel von MnII,2MnIII(BO3)O2 und MnIISrMnIII(BO3)O3 / New Insights into the Stabilization of the Hulsite Structure During Crystal Structure Determination of MnII 2MnIII(BO3)O2 and MnIISrMnIII(BO3)O2

Anne Utzolino、K. Bluhm1996-10-01Zeitschrift für Naturforschung B

The compounds Mn II 2 Mn III (BO 3 )O 2 (I) and Mn II SrMn III (BO 3 )O 2 (II) were prepared by using a B 2 O 3 flux technique. Single crystals were investigated by X-ray diffraction. I showed orthorhombic symmetry, space group D 9 2h - Pbam (No. 55), a = 926.0; b = 1241.5; c = 304.96pm ; Z = 4 and II monoclinic symme…

Crystal Structures and PropertiesRadioactive element chemistry and processingNuclear materials and radiation effects

Lean Blowout in a Research Combustor at Simulated Low Pressures

G. J. Sturgess、S. P. Heneghan、M. D. Vangsness 等 5 位作者1996-10-01Journal of Engineering for Gas Turbines and Power

A propane-fueled research combustor has been designed to represent the essential features of primary zones of combustors for aircraft gas turbine engines in an investigation of lean blowouts. The atmospheric pressure test facility being used for the investigation made it difficult to approach the maximum heat release…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceCombustion and flame dynamics

The Resolution Function in Diffuse X-ray Reflectivity

Wim H. de Jeu、J. D. Shindler、E. A. L. Mol1996-10-01Journal of Applied Crystallography

A comprehensive discussion of the resolution function in specular and diffuse X-ray reflectivity is given. This is particularly relevant due to the proliferation of this technique in the field of liquid and solid surfaces and multilayer systems. A simple quantitatively correct interpretation of the diffuse reflectivit…

Iron oxide chemistry and applicationsX-ray Diffraction in CrystallographyPigment Synthesis and Properties