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Determination of the ground state of manganese phthalocyanine in an argon matrix using magnetic circular dichroism and absorption spectroscopy

Bryce E. Williamson、Thomas C. VanCott、Michael E. Boyle 等 6 位作者1992-03-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDetermination of the ground state of manganese phthalocyanine in an argon matrix using magnetic circular dichroism and absorption spectroscopyBryce E. Williamson, Thomas C. VanCott, Michael E. Boyle, G. Christian Misener, Martin J. Stillman, and Paul N. SchatzCite this: J. A…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresMolecular spectroscopy and chirality

Basic magnesium carbonate flame retardants for polypropylene

M. Rigolo、R. T. Woodhams1992-03-01Polymer Engineering and Science

Abstract Magnesium hydroxide and magnesium carbonates have attracted attention as endothermic flame retardants that are sufficiently stable to be incorporated into thermoplastics without decomposition. In this survey, a basic form of magnesium carbonate, magnesium carbonate hydroxide pentahydrate [(MgCO 3 ) 4 · Mg(OH)…

biodegradable polymer synthesis and propertiesFlame retardant materials and propertiesSilicone and Siloxane Chemistry

Quantitative theory of the globule-to-coil transition. 2. Density-density correlation in a globule and the hydrodynamic radius of a macromolecule

Alexander Y. Grosberg、Д. В. Кузнецов1992-03-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTQuantitative theory of the globule-to-coil transition. 2. Density-density correlation in a globule and the hydrodynamic radius of a macromoleculeA. Yu. Grosberg and D. V. KuznetsovCite this: Macromolecules 1992, 25, 7, 1980–1990Publication Date (Print):March 1, 1992Publicati…

Protein Structure and DynamicsMaterial Dynamics and PropertiesElectrostatics and Colloid Interactions

Carbothermal Preparation of Silicon Nitride: Influence of Starting Material and Synthesis Parameters

Magnus Ekelund、B. Forslund1992-03-01Journal of the American Ceramic Society

C and SiO 2 of different types were mixed and heat‐treated (1410° to 1550°C), according to a standardized temperature program, in flowing N 2 at different pressures. It was found that a starting material combination of C (115 m 2 /g) and SiO 2 (50 m 2 /g) yielded pure Si 3 N 4 after about 2 h at 1550°C and 1.3 MPa. By…

Advanced ceramic materials synthesisCatalytic Processes in Materials ScienceSemiconductor materials and devices

Effect of Reoxidation on the Grain‐Boundary Acceptor‐State Density of Reduced BaTiO 3 Ceramics

In‐Chyuan Ho、Shen‐Li Fu1992-03-01Journal of the American Ceramic Society

To investigate the effect of reoxidation on the grain‐boundary acceptor‐state density of reduced barium titanate, n ‐doped BaTiO 3 ceramics are sintered in a reducing atmosphere (2% H 2 + 98% N 2 ) and then annealed in oxygen. After annealing at 1150°C for different times, the experimental results show a relationship…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Solution thermodynamics of the ferric complexes of new desferrioxamine siderophores obtained by directed fermentation

Silvia Konetschny-Rapp、Guenther Jung、Kenneth N. Raymond 等 5 位作者1992-03-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSolution thermodynamics of the ferric complexes of new desferrioxamine siderophores obtained by directed fermentationSilvia Konetschny-Rapp, Guenther Jung, Kenneth N. Raymond, Johannes Meiwes, and Hans ZaehnerCite this: J. Am. Chem. Soc. 1992, 114, 6, 2224–2230Publication Da…

Porphyrin and Phthalocyanine ChemistryLanthanide and Transition Metal ComplexesPolyoxometalates: Synthesis and Applications

Molecular modeling of polymer flammability: application to the design of flame-resistant polyethylene

Marc R. Nyden、Glenn P. Forney、James E. Brown1992-03-01Macromolecules

ABSTRACT Molecular dynamic simulations of the thermal degradation of polyethylene were used to identify factors which might be effective in reducing polymer flammability by promoting the formation of a residual char. Computer movies of the calculated trajectories indicate that cross-linked polymers, such as those obta…

Flame retardant materials and properties

Purification and Characterization of Dihydrodipicolinate Synthase from Pea

Catherine Dereppe、Guido Bold、Oreste Ghisalba 等 5 位作者1992-03-01PLANT PHYSIOLOGY

Dihydrodipicolinate synthase (EC 4.2.1.52), the first enzyme unique to lysine biosynthesis in bacteria and higher plants, has been purified to homogeneity from etiolated pea (Pisum sativum) seedlings using a combination of conventional and affinity chromatographic steps. This is the first report on a homogeneous prepa…

Enzyme Structure and FunctionPolyamine Metabolism and ApplicationsBiochemical and Molecular Research

Image analysis of shear-induced textures in liquid-crystalline polymers

J. T. Gleeson、Ronald G. Larson、D. W. Mead 等 5 位作者1992-03-01Liquid Crystals

Textures of several liquid-crystalline solutions of poly(benzylglutamate) and a solution of hydroxypropylcellulose were videorecorded during and after shear and the images were Fourier transformed. We find for all the solutions that bands perpendicular to the flow direction form after cessation of prolonged shearing i…

Liquid Crystal Research AdvancementsHydrogels: synthesis, properties, applicationsAdvanced Materials and Mechanics

The effects of Plateau borders in the two-dimensional soap froth. II. General simulation and analysis of rigidity loss transition

F. Bolton、D. Weaire1992-03-01Philosophical Magazine B

We have developed a computational simulation of the two-dimensional soap froth, including finite Plateau borders. As the gas fraction фis decreased, there is a loss of rigidity at approximately ф=0·84, at which point the structure is that of a dense random packing of hard discs with contact number equal to four. This…

Liquid Crystal Research AdvancementsComputer Graphics and Visualization TechniquesMaterial Properties and Processing

Finite element methods for micromagnetics

T.R. Koehler、D. R. Fredkin1992-03-01IEEE Transactions on Magnetics

The authors have formulated a numerical approach for application to micromagnetics problems and have implemented the corresponding three-dimensional finite element code. The program has been applied to the study of hysteretic behavior and domain walls in a variety of samples. The authors discuss the numerical method a…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsAdvanced Mathematical Modeling in Engineering

Time-resolved light scattering studies on the early stage of crystallization in isotactic polypropylene

Tetsuo Okada、Hiromu Saito、Takashi Inoue1992-03-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTime-resolved light scattering studies on the early stage of crystallization in isotactic polypropyleneTetsuo Okada, Hiromu Saito, and Takashi InoueCite this: Macromolecules 1992, 25, 7, 1908–1911Publication Date (Print):March 1, 1992Publication History Published online1 May…

Polymer crystallization and propertiesFiber-reinforced polymer composites

A brief discussion on the effect of temperature on the reaction of inorganic ions with soil

N. J. Barrow1992-03-01Journal of Soil Science

SUMMARY Published reports on the effect of temperature on the sorption of ions by soil, or soil constituents, are in conflict with regard to the direction of the effect and its interpretation. It is argued that, in many cases, increased sorption with increased temperature is due to an increased rate of the reaction th…

Groundwater and Isotope GeochemistrySoil and Unsaturated FlowClay minerals and soil interactions

Synthesis, structure, and properties of lanthanum strontium titanate (La1-xSrxTiO3) (0 .ltoreq. x .ltoreq. 1)

Joseph E. Sunstrom、Susan M. Kauzlarich、P. Klavins1992-03-01Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis, structure, and properties of lanthanum strontium titanate (La1-xSrxTiO3) (0 .ltoreq. x .ltoreq. 1)Joseph E. Sunstrom, IV, Susan M. Kauzlarich, and Peter KlavinsCite this: Chem. Mater. 1992, 4, 2, 346–353Publication Date (Print):March 1, 1992Publication History Pub…

Ferroelectric and Piezoelectric MaterialsInorganic Chemistry and MaterialsElectronic and Structural Properties of Oxides

Molecular analysis of the deletion mutants in the E homeotic complex of the silkworm Bombyx mori

Kohji Ueno、Chi‐chung Hui、Masakazu Fukuta 等 4 位作者1992-03-01Development

The E loci in Bombyx mori are expected to contain a homeotic gene complex specifying the identities of the larval abdominal segments. However, the molecular structure of this complex remains to be determined. We have started to analyze the structural changes in the E complex mutations. We used three newly isolated Bom…

Developmental Biology and Gene RegulationGenetic and Clinical Aspects of Sex Determination and Chromosomal AbnormalitiesSilk-based biomaterials and applications

Oxamidato complexes. 2. Copper(II) and nickel(II) complexes with oxamide-N,N'-diacetic acid: solution study, synthesis, crystal structures, and magnetic properties

Francesc Lloret、Jorunn Sletten、Rafael Ruiz‐García 等 6 位作者1992-03-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOxamidato complexes. 2. Copper(II) and nickel(II) complexes with oxamide-N,N'-diacetic acid: solution study, synthesis, crystal structures, and magnetic propertiesFrancesc Lloret, Jorunn Sletten, Rafael Ruiz, Miguel Julve, Juan Faus, and Michel VerdaguerCite this: Inorg. Che…

Magnetism in coordination complexes

A novel copper complex and CVD precursor: (.eta.2-butyne)copper(I) hexafluoroacetylacetonate

Thomas H. Baum、Carl E. Larson1992-03-01Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA novel copper complex and CVD precursor: (.eta.2-butyne)copper(I) hexafluoroacetylacetonateThomas H. Baum and Carl E. LarsonCite this: Chem. Mater. 1992, 4, 2, 365–369Publication Date (Print):March 1, 1992Publication History Published online1 May 2002Published inissue 1 Mar…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesPorphyrin and Phthalocyanine Chemistry

Measurement of blood‐brain barrier permeability using dynamic Gd‐DTPA scanning—a comparison of methods

Henrik Larsson、Paul S. Tofts1992-03-01Magnetic Resonance in Medicine

Two recently published methods of blood-brain barrier permeability measurement using Gd-DTPA scanning are compared by authors representing each group. The physiological models are reconciled. Results from both groups agree. These show that the transfer constant (the permeability surface area product per unit volume of…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesMRI in cancer diagnosis

Cocrystallization and phase segregation of polyethylene blends. 2. Synchrotron-sourced x-ray scattering and small-angle light scattering study of the blends between the D and H species

Kohji Tashiro、Michael M. Satkowski、Richard S. Stein 等 6 位作者1992-03-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCocrystallization and phase segregation of polyethylene blends. 2. Synchrotron-sourced x-ray scattering and small-angle light scattering study of the blends between the D and H speciesKohji Tashiro, Michael M. Satkowski, Richard S. Stein, Yingjie Li, Benjamin Chu, and Shaw L…

Polymer crystallization and propertiesAdvanced Cellulose Research StudiesCultural Heritage Materials Analysis

Phason softening and structural transitions in icosahedral quasicrystals

Yasushi Ishii1992-03-01Physical review. B, Condensed matter

The structural instability driven by soft phason modes in icosahedral quasicrystals is investigated. It is found that, depending on the physical parameters, three distinct soft modes induce the structural instabilities associated with the symmetry changes, ${\mathit{I}}_{\mathit{h}}$\ensuremath{\rightarrow}${\mathit{D…

Quasicrystal Structures and PropertiesMineralogy and Gemology Studies