Materials Literature
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This book describes two-, three-, and four-dimensional crystallographic groups, primarily by the use of tables. Complete groups of four-dimensional tables are presented for the first time. The description of the four-dimensional crystallographic groups provides a clearer insight into dimension-independent crystallogra…
During the past 15 years, surfaces have been increasingly studied on the atomic scale. As a result, their atomic structure and composition and the dynamics of gas-surface interactions are much better understood. Modern surface science is beginning to have an impact on many technologies. Techniques are readily availabl…
Electron-optical properties of a gun with a point cathode are determined numerically by tracing a greater number of electron trajectories. In order to calculate the beam current density distribution, an attempt was made to describe the properties of the gun in terms of the parameters describing the initial conditions…
We explore the properties of a one-dimensional diatomic chain of atoms, where one species may occupy one of two off-center lattice sites. For a fixed configuration of atoms, this leads to a problem in lattice dynamics with disorder in the atomic force constants. Through use of perturbation theory, the vibrational free…
Abstract Die Korrosion von Aluminium unter Sauerstoff verläuft praktisch unabhängig vom pH‐Wert, und zwar sowohl unter Sauerstoffverbrauch als auch unter Wasserstoffentwicklung. Dieses Verhalten wird sowohl in einer Acetatpuffer/Natriumchloridlösung als auch in anorganischen (Salpeter‐, Schwefel‐Phosphor‐ und Salzsäur…
Abstract The glass transition temperatures ( T g 's) of several polystyrenes and styrene–alkyl methacrylate copolymers and terpolymers were measured using thermomechanical analysis (TMA) and differential scanning calorimetry (DSC). The polymers studied had number‐average molecular weights from 3000 to 250,000 g/mole.…
Abstract The solubility of hexaamminenickel(II) complexes in aqueous ammonia solution (0 to 37 g-free NH3/100g-solv.) was investigated at temperatures 0–55 °C. It rapidly decreases with increase in free ammonia concentration but increases with rise in temperature. Hexaamminenickel(II) carbonate, sulfate, and chloride…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructure and solid-state chemistry of 3-carboxy-2-naphthalenediazonium bromideJ. Zanos Gougoutas and J. JohnsonCite this: J. Am. Chem. Soc. 1978, 100, 18, 5816–5820Publication Date (Print):August 1, 1978Publication History Published online1 May 2002Published inissue 1 Augus…
Crystalline choline chloride is known to exhibit sensitivity to ionizing radiation. Measurements are reported for two other choline salts choline bromide and iodide on a differential scanning calorimeter and are extended to low temperatures to elucidate the radiation sensitivity of these salts.(AIP)
The phase-space density for planar channeled particles has been derived for the continuum model under statistical equilibrium. This is used to obtain the particle spatial probability density as a function of incident angle. The spatial density is shown to depend on only two parameters, a normalized incident angle and…
Most presently available fixed-beam transmission electron microscopes (FBEM) yield a resolution limit close to the theoretically predicted value which is determined by diffraction and by the spherical aberration of the objective lens. The larger the aperture the better is the collection efficiency of the elastically s…
Infrared and Raman spectra of poly(vinylidene chloride) (PVDC) single crystals are presented. Additionally, we report infrared spectra of a quenched, largely amorphous, sample of PVDC. Our results question the interpretation of previous vibrational studies of PVDC which conclude that the crystalline polymer chain is i…
An ordered ilmenite phase of the stannate CaSnO3 is evidence from powder patterns. the hexagonal and rhombohedral unit-cell parameters are respectively: a = 5.487 (1), c = 15.287 (6) Å, Z = 6 and a = 6.000 (2) Å, α = 54.42 (3)°, Z = 2; Dm = 5.16, Dx = 5.17 g cm −3.
This report reviews the recorded world knowledge on the electrical and thermal properties of undoped nickel oxide in a most comprehensive and detailed form marking it possible for all users of the subject to have access to the original data without having to duplicate the laborious and costly process of literature sea…
Silica layers doped with fluorine have been deposited inside a quartz glass tube from a gas mixture. The oxidation reaction was initiated by a nonisothermal microwave plasma maintained at pressures of about 10 Torr and wall temperatures in the region of 1000°–1100°C. From the experiments it was found that fluorine was…
The indexed powder patterns of MnTeMoO6, CoTeMoO6 and ZnTeMoO6 are given. The structures of these compounds are isotypic, with orthorhombic space group P21212. a = 5.294 (1), b = 5.139 (1), c = 8.960 (2) Å for M nTeMoO6; a = 5.262 (2), b = 5.062 (2), c = 8.857 (3) Å for CoTeMoO6; a = 5.255 (1), b = 5.044 (1), c = 8.90…
A compound having three sp2 centers in the bicyclo[2.2.0]hexane skeleton, viz. hydrocarbon (1), has been synthesized as shown (R = CO2Me → CH2OH → CH2OTs). Thermolysis transforms (1) into 5-methylene-1,3-cyclohexadiene, a model system for polymerization studies.
Temperature dependence of the piezoelectric constants, elastic compliance coefficients and thermal expansions of ferroelectric Ca 2 Pb(C 2 H 5 CO 2 ) 6 have been measured in a wide temperature region including the ferroelectric-paraelectric phase transition point. The piezoelectric constants d 31 and d 33 show marked…
Cadmium stannate selective coatings have been prepared by a pyrolytic method in which two parts of 0.2M CdCl2⋅5H2O solution in ethyl alcohol and one part 0.2M solution of SnCl4⋅3H2O in acetic acid has been sprayed onto a heated substrate of glass and quartz. The films were transparent in the visible portion of the spe…
Five phosphate esters - tri-p-tolyl phosphate, tributyl phosphate, tris(1,3-dichloro-2-propyl)phosphate, tris(2,3-dibromopropyl)phosphate, and tris(2-chloroethyl)phosphate- were subjected to thermal oxidative degradation in air at 370 degrees C. Degradation mechanisms were postulated and the toxic hazards assessed bas…