Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermodynamics and the compositional variation of glass transition temperaturesP. R. CouchmanCite this: Macromolecules 1987, 20, 7, 1712–1717Publication Date (Print):July 1, 1987Publication History Published online1 May 2002Published inissue 1 July 1987https://pubs.acs.org/d…
A compositional model based on available structural evidence is proposed for amorphous calcium silicate hydrogel. It is applicable to gels in the (Ca/Si), solid range 1.0 to 1.4 and is formulated to take account of dimeric silicate species in the solid. Its composition is represented by Ca x H 6−2 x Si 2 O 7 · z Ca(OH…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTModeling of exothermic solid-solid noncatalytic reactionsJan Puszynski, Jan Degreve, and Vladimir HlavacekCite this: Ind. Eng. Chem. Res. 1987, 26, 7, 1424–1434Publication Date (Print):July 1, 1987Publication History Published online1 May 2002Published inissue 1 July 1987htt…
Uniform yttrium, lanthanum, cerium, and neodymium basic carbonate particles were prepared by homogeneous precipitation. Powders were characterized with respect to size, shape, crystal structure, and thermal decomposition behavior. Yttria precursor particles were spherical, monosized (0.4 {mu}m), and amorphous; whereas…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolymerization of polyurethane-polyester interpenetrating polymer network (IPN)Y. S. Yang and L. James LeeCite this: Macromolecules 1987, 20, 7, 1490–1495Publication Date (Print):July 1, 1987Publication History Published online1 May 2002Published inissue 1 July 1987https://d…
A simple theory describing the dynamics of two-dimensional arrays of soap bubbles is proposed, and compared with a recent experiment. The average area of bubbles scales linearly at late times. Agreement with experiment is satisfactory, although not conclusive.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInteraction between copper(II) ions separated by 7.6 .ANG.. Crystal structure and magnetic properties of (.mu.-iodanilato)bis[(N,N,N',N'-tetramethylethylenediamine)copper(II)] diperchlorateFabrice Tinti, Michel Verdaguer, Olivier Kahn, and Jean Michel SavariaultCite this: In…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFormation of Si-Si bonds from Si-H bonds in the presence of hydrosilation catalystsKatherine A. Brown-WensleyCite this: Organometallics 1987, 6, 7, 1590–1591Publication Date (Print):July 1, 1987Publication History Published online1 May 2002Published inissue 1 July 1987https:…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMononuclear manganese(IV) complexes of hydroxyl-rich Schiff base ligandsDimitris P. Kessissoglou, Xinhua Li, William M. Butler, and Vincent L. PecoraroCite this: Inorg. Chem. 1987, 26, 15, 2487–2492Publication Date (Print):July 1, 1987Publication History Published online1 Ma…
Abstract The synthesis and characterization of liquid crystalline side chain polymers with mesogenic groups laterally attached to the polymer main chain are described. By variation of the terminal group, mesogenic moiety or spacer length, a change in the glass transition temperature, the nematic to isotropic transform…
A new method for preparing the polymer films directly in the reduced atmosphere has been developed. In this process the polymerization can be carried out through depositing the component monomer vapors. Both pyromellitic dianhydride and 4,4′-diaminodiphenyl ether (oxydianiline) were evaporated at a molar ratio in term…
Nitric oxide adsorption, decomposition, and desorption were studied on Rh(100) in the temperature range from 88 to 1100 K using electron energy loss spectroscopy (EELS) and temperature programmed desorption (TPD). The EEL spectrometer was equipped with a multichannel detector for fast data acquisition. There are two a…
The structure of the elpasolite Cs2KCr(CN)6 has been determined at 7.0 K by neutron diffraction. 877 unique reflections refined to Rw = 0.020, ? = 1.4. The Cr(CN)6 unit is close to regular octahedral coordination geometry, with bond lengths of 207.4(4) for Cr-C and 116.6(6) pm for C-N. The C-Cr-C angles average to 90.…
Abstract The tetracyanoethylene anion radical ( \documentclass{article}\pagestyle{empty}\begin{document}${\rm TCNE}^{ \cdot ^ - } $\end{document} ) was detected by ESR spectroscopy in polytetrafluoroethylene (PTFE), which had been mechanically fractured in vacuo with tetracyanoethylene (TCNE) at 77 K. The assignment o…
Abstract The dispersion characteristics of five arid land soils were determined upon reaction with solutions having various levels of electrolyte concentration, C ( C = 0, 1, 4, 10, 30, 50, and 100 mmol c L −1 ), and sodium adsorption ratios, SAR (0, 5, 10, 20, and 40) with either Ca or Mg as the divalent counter‐ion.…
The skin-core structure of various injection-molded samples of PP differing by molecular weight and the injection conditions—essentially injection rate and holding pressure—has been studied by microscopy, DSC, WAXS, and IR dichroïsm on microtome sections. The depth distributions of the degree of crystallinity, macromo…
The electrochemical characteristics of electrodes composed of composites of conducting polymers and alkali‐metal alloys have been investigated. We have found that the addition of poly(p‐phenylene) (PPP) to alkali‐metal alloys greatly enhances the cyclability and the rate capability of alkali‐metal alloys. The impedanc…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNovel photoinduced carbon-carbon bond formation via metal-alkyl and -enolate porphyrins-visible light-mediated polymerization of alkyl methacrylate catalyzed by aluminum porphyrinMasakatsu Kuroki, Takuzo Aida, and Shohei InoueCite this: J. Am. Chem. Soc. 1987, 109, 15, 4737–…
A locus responsible for the Nd-s mutation of the silkworm, Bombyx mori, has been mapped very close to or within the fibroin light (L) chain gene on the 14th chromosome (Takei, F., K. Kimura, S. Mizuno, T. Yamamoto, and K. Shimura, 1984, Jpn. J. Genet., 59:307-313). A strain of B. mori carrying the homozygous Nd-sD mut…
The crystallization behavior of polyethylene terephthalate (PET) was investigated as a function of molecular weight, temperature of crystallization, and polycondensation catalyst system. A detailed analysis of the crystallization course has been made utilizing the Avrami expression. The crystallization rate constants…