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High-yield epoxidations with hydrogen peroxide and tert-butyl hydroperoxide catalyzed by iron(III) porphyrins: heterolytic cleavage of hydroperoxides

Teddy G. Traylor、Shinji Tsuchiya、Young Seok Byun 等 4 位作者1993-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHigh-yield epoxidations with hydrogen peroxide and tert-butyl hydroperoxide catalyzed by iron(III) porphyrins: heterolytic cleavage of hydroperoxidesTeddy G. Traylor, Shinji Tsuchiya, Young Seok Byun, and Cheal KimCite this: J. Am. Chem. Soc. 1993, 115, 7, 2775–2781Publicati…

Metal-Catalyzed Oxygenation MechanismsPhotodynamic Therapy Research StudiesPorphyrin and Phthalocyanine Chemistry

Determination of Critical Concentrations of Silica and/or Calcia for Abnormal Grain Growth in Alumina

So Ik Bae、Sunggi Baik1993-04-01Journal of the American Ceramic Society

Minimum amounts of SiO 2 and CaO required for inducing abnormal grain growth in alumina were determined using ultrapure alumina (>99.999%) and sintering at 1900°C for 1 h in a contamination‐free condition. The critical concentrations of silicon in cationic mole fractions in alumina were 300 ppm without calcium, 200…

Advanced ceramic materials synthesisNuclear materials and radiation effectsAluminum Alloys Composites Properties

Stronger acceptors can diminish nonlinear optical response in simple donor-acceptor polyenes

Seth R. Marder、Christopher B. Gorman、Bruce G. Tiemann 等 4 位作者1993-04-01Journal of the American Chemical Society

There has been much recent effort in the design of optimal chromophores for second-order nonlinear optical (NLO) applications. Most studies of organic molecules have focused on donor-acceptor π-conjugated molecules containing aromatic groups. We will show that the NLO response of aromatic donor-acceptor chromophores i…

Nonlinear Optical Materials ResearchPorphyrin and Phthalocyanine ChemistrySpectroscopy and Quantum Chemical Studies

New ordered morphologies in ABC triblock copolymers

Clemens Auschra、Reimund Stadler1993-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNew ordered morphologies in ABC triblock copolymersClemens Auschra and Reimund StadlerCite this: Macromolecules 1993, 26, 9, 2171–2174Publication Date (Print):April 1, 1993Publication History Published online1 May 2002Published inissue 1 April 1993https://pubs.acs.org/doi/10…

Block Copolymer Self-AssemblyAdvanced Polymer Synthesis and CharacterizationTheoretical and Computational Physics

CH-.pi. interaction as an important driving force of host-guest complexation in apolar organic media. Binding of monools and acetylated compounds to resorcinol cyclic tetramer as studied by proton NMR and circular dichroism spectroscopy

Kenji Kobayashi、Yuji Asakawa、Yasuaki Kikuchi 等 5 位作者1993-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCH-.pi. interaction as an important driving force of host-guest complexation in apolar organic media. Binding of monools and acetylated compounds to resorcinol cyclic tetramer as studied by proton NMR and circular dichroism spectroscopyKenji Kobayashi, Yuji Asakawa, Yasuaki…

Conducting polymers and applicationsAdvanced NMR Techniques and ApplicationsMolecular spectroscopy and chirality

Flame retardancy of polymeric materials

作者信息未提供1993-04-01Additives for Polymers

Some of the unsolved problems and unanswered questions in the flame retardance of polymers are reviewed. They include, durable flame-retardant systems for cotton; FR treatment of cotton–PET blends; durable, weatherable, non-water-leachable, FR treatment of lignocellulosic products, especially wood; better understandin…

Flame retardant materials and properties

Sequencing of a Clostridium thermocellum gene (cipA) encoding the cellulosomal SL‐protein reveals an unusual degree of internal homology

U. T. Gerngross、Marek P.M. Romaniec、Teruyuki Kobayashi 等 5 位作者1993-04-01Molecular Microbiology

It is known that two proteins of the cellulosomal complex of Clostridium thermocellum (SL and SS) together degrade crystalline cellulose. SL is a glycoprotein of 210,000 Da which enhances the binding to cellulose and the activity of SS, an endoglucanase of 83,000 Da. We have previously reported the cloning of a DNA fr…

Biofuel production and bioconversionPolysaccharides and Plant Cell WallsAdvanced Cellulose Research Studies

Mechanism of quasi-one-dimensional electronic conductivity in discotic liquid crystals

N. Boden、Richard J. Bushby、J. Clements1993-04-01The Journal of Chemical Physics

Recently, it has been shown that a new class of quasi-one-dimensional conductors can be created by doping discotic liquid crystals with appropriate oxidants. This paper reports the elucidation of the mechanism of conduction in these new materials. In particular, the ac conductivity of 2,3,6,7,10,11-hexahexyloxytriphen…

Thermodynamic properties of mixturesLiquid Crystal Research AdvancementsMaterial Dynamics and Properties

Rigid nonlabile polyoxometalate cryptates [ZP5W30O110](15-n)- that exhibit unprecedented selectivity for certain lanthanide and other multivalent cations

I. I. CREASER、M Heckel、R. Jeffrey Neitz 等 4 位作者1993-04-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRigid nonlabile polyoxometalate cryptates [ZP5W30O110](15-n)- that exhibit unprecedented selectivity for certain lanthanide and other multivalent cationsInge Creaser, Mark C. Heckel, R. Jeffrey Neitz, and Michael T. PopeCite this: Inorg. Chem. 1993, 32, 9, 1573–1578Publicati…

Polyoxometalates: Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsNanocluster Synthesis and Applications

Volume-fraction dependence of elastic moduli and transition temperatures for colloidal silica gels

Mae Chen Grant、W. B. Russel1993-04-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Colloidal silica spheres bearing grafted octadecyl chains dispersed in hexadecane undergo a sol-gel transition with decreasing temperature. The gelation temperature depends on the volume fraction \ensuremath{\varphi} and, perhaps, the particle size. For \ensuremath{\varphi}>${\mathrm{\ensuremath{\varphi}}}_{gel}$(T…

Mesoporous Materials and CatalysisMaterial Dynamics and PropertiesAdsorption, diffusion, and thermodynamic properties of materials

CRYPTOGAMIC CRUSTS OF SEMIARID AND ARID LANDS OF NORTH AMERICA

Jeffrey R. Johansen1993-04-01Journal of Phycology

The Journal of Phycology was founded in 1965 by the Phycological Society of America. All aspects of basic and applied research on algae are included to provide a common medium for the ecologist, physiologist, cell biologist, molecular biologist, morphologist, oceanographer, taxonomist, geneticist, and biochemist. The…

Aquatic Ecosystems and Phytoplankton DynamicsDiatoms and Algae ResearchBiocrusts and Microbial Ecology

Titelei

作者信息未提供1993-04-01Applied Rheology