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Anion ordering in mixed valence dicesium hexachloroantimonate (Cs2SbCl6) and related salts

Kosmos Prassides、Peter Day、Anthony K. Cheetham1983-05-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAnion ordering in mixed valence dicesium hexachloroantimonate (Cs2SbCl6) and related saltsKosmos Prassides, Peter Day, and Anthony K. CheethamCite this: J. Am. Chem. Soc. 1983, 105, 10, 3366–3368Publication Date (Print):May 1, 1983Publication History Published online1 May 20…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyInorganic Chemistry and Materials

Age‐Related Changes in the Collagen of Bovine Corium: Studies on Extractability, Solubility and Molecular Size Distribution

A. T. Miller、Endel Karmas、Mingshou Lu1983-05-01Journal of Food Science

ABSTRACT Bovine skin corium obtained from freshly slaughtered cattle of increasing biological age showed greater resistance to the action of acids, as measured by extractable collagen. Citrate‐soluble content of corium from fetal skin was 30.9%, while that of 3 to 6‐wk old calf was 6.4% and of 18‐month steer was 3.2%.…

Bone Tissue Engineering MaterialsCultural Heritage Materials AnalysisCollagen: Extraction and Characterization

New photostable anthraquinone dyes with high order parameters

F. C. Saunders、K. J. Harrison、E. P. Raynes 等 4 位作者1983-05-01IEEE Transactions on Electron Devices

New anthraquinone dyes have been developed with high-order parameters and solubilities in both positive and negative dielectric anisotropy liquid-crystal hosts. The dyes show high stability and allow the formulation of black mixtures which show good contrast in a range of display devices.

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPhotochromic and Fluorescence Chemistry

Mass distributions in monoenergetic-neutron-induced fission ofPu239

J.E. Gindler、L.E. Glendenin、Deborah J. Henderson 等 4 位作者1983-05-01Physical Review C

Fission product yields for 24 masses were determined for the fission of $^{239}\mathrm{Pu}$ with essentially monoenergetic neutrons of 0.17, 1.0, 2.0, 3.4, 4.5, 6.1, and 7.9 MeV. Fission product activities were measured by Ge(Li) $\ensuremath{\gamma}$-ray spectrometry of irradiated $^{239}\mathrm{Pu}$ targets and by c…

Nuclear physics research studiesNuclear Materials and PropertiesNuclear Physics and Applications

Predicting the Drape Coefficient of Knitted Fabrics

Marian Louise Gaucher、Martin W. King、Bruce G. Johnston1983-05-01Textile Research Journal

Multiple regression analysis was used to determine whether certain deformation properties (stiffness, shear, extensibility) and structural characteristics (fabric weight, thickness, and density) serve as reliable predictors of the drape of knitted fabrics. Stiffness, measured in terms of bending length, thickness, and…

Mechanical Behavior of CompositesDyeing and Modifying Textile FibersTextile materials and evaluations

Reduction of carbon monoxide by binuclear tantalum hydride complexes

Patricia A. Belmonte、F. Geoffrey N. Cloke、Richard R. Schrock1983-05-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReduction of carbon monoxide by binuclear tantalum hydride complexesPatricia A. Belmonte, F. Geoffrey N. Cloke, and Richard R. SchrockCite this: J. Am. Chem. Soc. 1983, 105, 9, 2643–2650Publication Date (Print):May 1, 1983Publication History Published online1 May 2002Publish…

Catalytic Processes in Materials ScienceCO2 Reduction Techniques and CatalystsCatalysis and Oxidation Reactions

Structural Phase Transition of Layer Compound (C2H5NH3)2FeCl4

Takashi Suzuki、M. Yoshizawa、Terutaka Gotô 等 6 位作者1983-05-01Journal of the Physical Society of Japan

The sequence of the structural phase transitions of the layer compound (C 2 H 5 NH 3 ) 3 FeCl 4 has been determined with the ultrasonic, dielectric and polarized microscope measurements as following; Phase I ( D 4 h 17 )–(378.8 K)–Phase II ( D 2 h 18 )–(203.5 K)–Phase III–(133.7 K)–Phase IV. The set of the critical ex…

Thermodynamic properties of mixturesNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

Factors affecting the staling of madeira slab cake

Robin C. Guy1983-05-01Journal of the Science of Food and Agriculture

Abstract Cake staling, which is associated with changes in crumb firmness and moistness, has been shown to be related to two basic processes occurring in the crumb. These are an intrinsic firming process of the cell‐wall material of the crumb and the macroscopic migration of moisture from the central areas of the crum…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesPolysaccharides Composition and Applications

Photochromism of monolayers of poly(methylmethacrylate) having spirobenzopyran side groups

R. Vilanove、H. Hervet、Hans Gruler 等 4 位作者1983-05-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotochromism of monolayers of poly(methylmethacrylate) having spirobenzopyran side groupsR. Vilanove, H. Hervet, H. Gruler, and F. RondelezCite this: Macromolecules 1983, 16, 5, 825–831Publication Date (Print):May 1, 1983Publication History Published online1 May 2002Publish…

Photonic Crystals and ApplicationsPorphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence Chemistry

Reversible exchange of (.eta.5-cyclopentadienyl)(dinitrosoalkane)cobalt complexes with alkenes. Kinetic and spectroscopic evidence for cyclopentadienyldinitrosylcobalt as a reactive intermediate

Paul Becker、Robert G. Bergman1983-05-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReversible exchange of (.eta.5-cyclopentadienyl)(dinitrosoalkane)cobalt complexes with alkenes. Kinetic and spectroscopic evidence for cyclopentadienyldinitrosylcobalt as a reactive intermediatePaul N. Becker and Robert G. BergmanCite this: J. Am. Chem. Soc. 1983, 105, 10, 2…

Magnetism in coordination complexesChemical Reaction MechanismsChemical Reactions and Mechanisms

Mechanism of thermal depolymerization of trimethylsiloxy‐terminated polydimethylsiloxane

Martel Zeldin、Bo‐Rong Qian、Sung Jae Choi1983-05-01Journal of Polymer Science Polymer Chemistry Edition

Abstract “Catalyst‐free” trimethylsilyl end‐blocked polydimethylsiloxanes of M n = 68,300 and 111,000 were isothermally depolymerized above 400°C. The volatilized products were a mixture of cyclic oligomers and trace quantities of Me 3 Si(OSiMe 2 ) n OSiMe 3 ( n = 0,1). The relative degree of polymerization was follow…

Organometallic Complex Synthesis and CatalysisCarbon dioxide utilization in catalysisSilicone and Siloxane Chemistry

Inverse dielectric function for a semi‐infinite solid

F. Bechstedt、R. Enderlein、D. Reichardt1983-05-01physica status solidi (b)

Abstract An old problem is addressed being the description of the dielectric response of electrons near the surface of an infinite half space to perturbing potentials and external charges. Taking into account spatial dispersion, expressions are derived for the screened potential and the inverse dielectric function wit…

Geophysical and Geoelectrical MethodsElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Spall studies of differently treated 2024A1 specimens

Z. Rosenberg、Gabi Luttwak、Y. Yeshurun 等 4 位作者1983-05-01Journal of Applied Physics

Commercial manganin stress gauges are used in planar impact experiments to determine spall strengths of variously heat-treated 2024A1 specimens. A one-dimensional Lagrangian code is used to find the best fit of calculated versus experimental stress histories by varying the spall strength in the code and using a simple…

Metal and Thin Film MechanicsFatigue and fracture mechanicsHigh-Velocity Impact and Material Behavior

X-ray photoelectron spectroscopy study of hydrogen plasma interactions with a tin oxide surface

Johannes Thomas1983-05-01Applied Physics Letters

Tin oxide thin films were exposed to an rf excited hydrogen plasma (100 mTorr) for various times. The plasma system was operated in a self-biased mode. X-ray photoelectron spectroscopy analysis of vacuum transferred samples shows that SnO2 is reduced. A thin self-limiting layer of elemental Sn forms on the reduced fil…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsElectronic and Structural Properties of Oxides

Diffusion in concentrated hard sphere dispersions: Effective two particle mobility tensors

Ian K. Snook、W. van Megen、R.J.A. Tough1983-05-01The Journal of Chemical Physics

In view of the practical difficulties already encountered plus those anticipated in the implementation of many-body hydrodynamic interactions, we examine a number of empirically screened two particle mobility tensors. The empirical screening constant(s), which depend on the dispersion concentration, are adjusted to gi…

Material Dynamics and PropertiesSpectroscopy and Quantum Chemical StudiesNMR spectroscopy and applications

Effect of Fly Ash on the Air-Void Stability of Concrete

Steven Gebler、Paul Klieger1983-05-01Special publication - Royal Society of Chemistry/Special publication

Concrete containing both portland cement and fly ash were evaluated to determine the effect of fly ash on air-void stability. Tests indicate that air contents of concrete containing Class C fly ash appear to be more stable than those of concrete containing Class F fly ash. The higher the organic matter content of a fl…

Concrete and Cement Materials ResearchMaterials Engineering and ProcessingEngineering and Material Science Research

Crystalline Fouling Studies

R. B. Ritter1983-05-01ASME Journal of Heat and Mass Transfer

In a study of fouling of heat exchangers, aqueous solutions of CaSO4 and Li2SO4 were circulated through electrically heated tubes at controlled conditions. Measured induction periods and fouling rates of both salts were found to be primarily functions of the supersaturation of the solutions. Secondary correlating para…

Calcium Carbonate Crystallization and InhibitionMagnetic and Electromagnetic Effects

Wave scattering and guidance by dielectric waveguides with periodic surfaces

S. L. Chuang、J. A. Kong1983-05-01Journal of the Optical Society of America

Stratified media with periodic surfaces have been used in waveguide-input and waveguide-output couplers and distributed-feedback lasers. We apply the extended-boundary-condition approach to treat the problem of scattering and guidance by stratified media with period surfaces for both the TE and TM polarizations in a u…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Exchange interaction in multinuclear transition-metal complexes. 3. Synthesis, x-ray structure, and magnetic properties of Cu2L(CH3COO)2.2CH3OH (L2- = anion of N,N'-bis((2-(o-hydroxybenzhydrylidene)amino)ethyl)-1,2-ethanediamine), a one-dimensional Heisenberg antiferromagnet having through-bond coupled copper(II) ions

B. Chiari、William E. Hatfield、O. Piovesana 等 6 位作者1983-05-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTExchange interaction in multinuclear transition-metal complexes. 3. Synthesis, x-ray structure, and magnetic properties of Cu2L(CH3COO)2.2CH3OH (L2- = anion of N,N'-bis((2-(o-hydroxybenzhydrylidene)amino)ethyl)-1,2-ethanediamine), a one-dimensional Heisenberg antiferromagnet…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms

Projected ranges and effective stopping powers of electrons with energy between 20 eV and 10 keV

H Iskef、James W. Cunningham、D.E. Watt1983-05-01Physics in Medicine and Biology

Experimental projected ranges of electrons between 20 eV and 10 keV have been correlated by a simple scaling factor to yield 'best-fit' expressions applicable to all media. Extrapolated ranges, R ex (in mu g cm -2 ) may be determined from the expressions given. From an analysis of the transmission curves, the followin…

Advancements in Photolithography TechniquesX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques