Materials Literature
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Relative cathodoluminescence quantum intensity measurements made on crystals containing a series of concentrations of each of the ions Ce 3+ , Eu 3+ , Tb 3+ , and Gd 3+ are reported as a function of temperature. For the first three of these activator ions the CL intensity increases with temperature, although the effic…
We report here the dependence on hydrostatic pressure up to 2.79 kbars of the two structures associated with the A 1 and A 2 transitions in the reflectivity spectra of graphite measured at room temperature in the photon energy range from 0.655 to 1.125 eV. By considering explicitly the effect of the trigonal warping u…
Abstract Activities of various bleaching earths for removal of β‐carotene from acetone solution were found to be in the decreasing order tonsil, fuller's earth, silica, and kaolin. Experimental evidence indicated that except for silica, in addition to physical adsorption, processes involving chemisorption and subseque…
This paper describes a statistical model for the strength of twisted bundles of stiff fibers. The model evolves from the classic model for bundle strength and is most applicable for short bundles with low friction between filaments; however, the model is believed to yield insight into the strength behavior of longer y…
Conformations of n-alkane molecules in the liquid state have been studied as a function of temperature and pressure using Raman scattering. Observations of conformationally sensitive Raman bands in hexane, heptane, octane, and hexadecane reveal no sign of the pressure-induced effects in polyethylene. Instead the Raman…
The author reviews several important aspects of the problem of one-dimensional metals, including a discussion of their instability, a survey of various materials which are more or less nearly one-dimensional, a fairly detailed treatment of the elementary excitations of charge density waves and a discussion of their el…
The skin relief influences the exterior aspect of the skin which is very sensitive to aging. It could also be related to the mechanical properties and structure of both dermis and stratum corneum. Consequently, quantitative measurement of the skin surface roughness would seem most useful, as it would permit a quantifi…
The effect known as ferroelectricity arises when forces between polarizable ions in a solid produce a spontaneous displacement of these ions which results in a lattice polarization below some characteristic (Curie) temperature. Fluctuations in this polarization may be thermally induced as in the case of classical ferr…
Expressions for the dielectric function of Si-SiO2 and Si-Si3N4 composites are obtained by combining the Si-centered tetrahedral model of Philipp with composite-media theory. The similarity between dielectric-function spectra of a-Si and Si3N4, with scaling parameters related by the plasma sum rule and the dielectric…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermal intramolecular cobalt(III)-iron(II) and cobalt(III)-titanium(III) electron-transfer reactions involving outer-sphere and inner-sphere precursor complexesHorst Bertram and Karl WieghardtCite this: Inorg. Chem. 1979, 18, 7, 1799–1807Publication Date (Print):July 1, 197…
Thermal expansion coefficient of Fe-Ni Invar alloys at low temperatures has been examined by using the itinerant electron model. It has been found that the experimental values obtained by Schlosser et al. and by Zakharov and Fedotov could be explained satisfactorily up to about 200 K by using the expression derived in…
Some optically active ferroic crystals (a few ferroelectrics and one ferroelastic) are known to exhibit reversal of the sign of spontaneous optical rotation in certain directions when a suitable electric field or uniaxial stress is applied. This phenomenon, to be called gyrotropy, is examined in the framework of Aizu'…
Dihydrofolate reductase plays a dual role in bacteriophage T4, first, as an enzyme of thymidylate metabolism, and second, as a protein component of the tail baseplate. Antibody to the purified enzyme has been used to study its synthesis and intracellular turnover. The antibody specifically precipitates one protein fro…
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A high-strength, high-ductility, austenitic stainless steel has been evaluated for use in surgical implants by performing in vivo tests in rats, rabbits, dogs, and rhesus monkeys. This stainless steel, a TRIP (Transformation Induced Plasticity) steel containing about 4% Mo, was compared with two alloys in current clin…
Abstract A series of copper and nickel biuret complexes has been studied by X-ray photoelectron spectroscopy (XPS). The results include one of the first reports of the XPS spectrum of a copper(III) complex. Significantly, this diamagnetic complex exhibits intense satellite structure in both the Cu 2P3/2 and Cu 2Pi/2 r…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMechanism of rearrangement of platinacyclobutanesCharles P. Casey, Daniel M. Scheck, and Alan J. ShustermanCite this: J. Am. Chem. Soc. 1979, 101, 15, 4233–4236Publication Date (Print):July 1, 1979Publication History Published online1 May 2002Published inissue 1 July 1979htt…
Transport coefficients of electrons in nitrogen are calculated over the range 10−16⩽E/N⩽7.3×10−15 V cm2 by solving the Boltzmann equation using the classical two-term expansion in spherical harmonics. However, as in the case of H2 treated in a previous paper, the sources of new electrons produced by ionization has bee…
Abstract A document examiner is often faced with determining the age of certain writing, whether done by ball-point pen, pencil, ink, typewriter, or something else; the problem is almost unsolvable because no method exists that yields reliable and direct results. Ways and means have often to be found that permit an in…
Two remarkable molybdenum complexes have been isolated on recation of aqueous solutions of Mo VI oxo anions with H 2 NOH or MeHNOH: the yellow NO complex (1) and the colorless NO‐free neutral complex (2) . This shows that many yellow Mo complexes characterized only in solution pribably contain NO ligands. equation ima…