Materials Literature
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The effective permittivity of samples of barium titanate with porosities up to 40% v/v. has been determined, and an explanation given in terms of Wiener's mixture law. It is shown that the values of the form factor in this law can only be predicted with certainty over the ranges 0-30% and 70-100% porosity, and takes u…
A study of the kinetics of the heterogeneous hydrolysis of cellulose indicates that there are two distinct rates which have been attributed to the rapid hydrolysis of the loose amorphous regions and to the slow hydrolysis of the dense crystalline portions of the fiber. Based on this interpretation, a simple method for…
Using the crystal structure determination of rochelle salt made by Beevers and Hughes, a theory of the ferro-electric effect and clamped dielectric constant has been worked out using the displacement of the hydrogen nucleus in the 1-10 hydrogen bond as the ferroelectric dipole. This theory has only one disposable cons…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolyorganosiloxanes...Surface Active PropertiesH. Fox, Paula Taylor, and W. ZismanCite this: Ind. Eng. Chem. 1947, 39, 11, 1401–1409Publication Date (Print):November 1, 1947Publication History Published online2 February 2005Published inissue 1 November 1947https://pubs.acs.o…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCellulose Intercrystalline StructureR. F. Nickerson and J. A. HabrleCite this: Ind. Eng. Chem. 1947, 39, 11, 1507–1512Publication Date (Print):November 1, 1947Publication History Published online1 May 2002Published inissue 1 November 1947https://pubs.acs.org/doi/10.1021/ie50…
Abstract : Firings of caliber .50, 20mm, and 37mm A.P. projectiles were made on 4' x 4' x 3' blocks of granite, diabase, quartzite, oolitic limestone, and sandstone. The results of firing major caliber projectiles on limestone at Fort Knox, Kentucky, were obtained from the Armored Board. From the results of the firing…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermal Decomposition of Ammonium NitrateJ. T. KummerCite this: J. Am. Chem. Soc. 1947, 69, 10, 2559Publication Date (Print):October 1, 1947Publication History Published online1 May 2002Published inissue 1 October 1947https://pubs.acs.org/doi/10.1021/ja01202a507https://doi.o…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSolubility of Ca(OH)2 and CaSO4.2H2O in Dilute Alkali SolutionsW. C. Hansen and E. E. PresslerCite this: Ind. Eng. Chem. 1947, 39, 10, 1280–1282Publication Date (Print):October 1, 1947Publication History Published online1 May 2002Published inissue 1 October 1947https://pubs.…
Abstract The chemical reactivity of vinyl and diene polymers manifested during aging and degradation is similar to the reactivity manifested during polymerization; namely, the activated intermediates are radicals and the reaction proceeds by a chain mechanism. A discussion of the possible types of aggregative and disa…
of electrod epositing tu ngsten alloys with me tals of th e iron group have been developed. Some of the prope rties of the alloys ha ve bee n determined and indicate t hat the a lloys may be of commercia l valu e. The p latin g solu tion s consist essentially of t he appropriate m etal salt s, together with salts of c…
This paper describes a general study of the structural characteristics of chromium plate and of the mechanism of chromium plating. New fundamental data are presented on the crystal structure of chromium deposited from chromic acid solutions. In view of deposition conditions producing the various structural modificatio…
The general method of making an evaporated multiple-layer interference filter from two dielectrics is described for any desired wave-length range. The proper thickness of each layer to give maximum reflection in the desired region and at the desired angle of incidence is first computed, and next the visible reflectivi…
This paper contains a discussion of the water-adsorption properties of a class of long-chain materials with many polar groups, which includes most textile fibers. The process discussed is distinguished from the adsorption by substances such as metal and metallic oxide catalysts in that it is not strictly a surface phe…
Abstract The molecular weight‐viscosity relationships for polystyrene are reviewed and it is recommended that the Staudinger relationship be discarded in favor of the conventional modification of it, [η] = KM a . An emulsion‐prepared polystyrene was fractionated and the viscosities and osmotic molecular weight determi…
Abstract The tensile properties of a range of pure gum natural rubbers has been reviewed, and it has been shown that their principal features can be understood on the assumption that the tensile strength measured in a given test depends directly on the amount of crystallization at break. The most important single fact…
Abstract Some of the constituent amino-acids of fibroin (degummed silk) are determined. Special attention is directed to histidine, owing to its use in the calculation of the molecular weight of fibroin. A value of 0.45 % has been found by methods in which the histidine is isolated as nitranilate or di-(3:4-dichlorobe…
Abstract General formulae are obtained for the effect of a magnetic field on the electrical and thermal conductivities of a metal in which there are two overlapping bands of normal form. Simple formulae are set up which, though not strictly valid for all temperatures and fields, reduce to the correct expressions in th…
The freezing point diagram has been plotted for mixtures of acetic acid and urotropine containing 0 to 42% urotropine. Formation of a solid compound melting at 24.8 °C., and having the approximate composition (C 6 H 12 N 4 ) 3 ∙(C 2 H 4 O 2 ) 13 is indicated. Repeated purification of the materials failed to shift the…
The resolving power of electron microscopes is limited chiefly by the fact that the spherical aberration of electron lenses of the conventional or "coreless" type can never be eliminated. In this paper a new type of electron lenses is investigated, called coaxial lenses. These contain a central cylindrical conductor,…
Four homogeneous solid solutions were found in the silver-magnesium alloy system. The α-primary solid solution of magnesium in silver has a f.c.c. structure. The β-solid solution has a b.c.c. structure. The γ-solid solution appears to have a complicated structure. While others have identified it as hexagonal, no defin…