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Structural Characterization of Filled Vulcanizates Part 1. Determination of the Concentration of Chemical Crosslinks in Natural Rubber Vulcanizates Containing High Abrasion Furnace Black

M. Porter1967-07-01Rubber Chemistry and Technology

Abstract The degree to which HAF black restricts the swelling of natural rubber vulcanizates in n -decane has been determined using a vulcanizing system in which the stoichiometry of crosslinking is unaffected by the carbon black. The dependence of the degree of restriction, as measured by the ratio of the volume frac…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesSynthesis and properties of polymers

Adsorption of alkylammonium cations by montmorillonite

Benny K.G. Theng、D. J. Greenland、J. P. Quirk1967-07-01Clay Minerals

Abstract The adsorption of various alkylammonium cations from aqueous solution by sodium and calcium montmorillonite has been studied. Adsorption occurred through an exchange reaction between the inorganic cations on the clay and the alkylammonium ions in solution. The affinity of the clay for these cations was linear…

Adsorption and biosorption for pollutant removalClay minerals and soil interactionsElectrostatics and Colloid Interactions

Über die Chemie der Oberfläche des Titandioxids. I. Bestimmung des aktiven Wasserstoffs, thermische Entwässerung und Rehydroxylierung

H.P. Boehm、Michael Herrmann1967-07-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Die Menge der an der Oberfläche gebundenen OH‐Gruppen wurde bei einem feinteiligen Anatas durch Deuterium‐Austausch, Acetylierung und Reaktion mit SOCl 2 bestimmt. Nach Entgasen bei 150° wurden etwa 4,9 OH‐Gruppen/100 Å 2 gefunden, gegenäber einer fär eine vollständig hydroxylierte Oberfläche abgeschätzten Me…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Solid-solid interfacial energy determinations in metal-ceramic systems

R. M. Pilliar、Jack Nutting1967-07-01Philosophical magazine

Small metal particles have been formed on α-Al2O3 films and equilibrated to give the minimum surface energy shapes. Determination of the equilibrated shape by transmission electron microscopy allows the interfacial energy of the solid-solid system to be determined. Values of γ interface are given for the systems Au, A…

Crystallization and Solubility Studiesnanoparticles nucleation surface interactionsX-ray Diffraction in Crystallography

Rare earths. IV. Dissociation energies of the gaseous monoxides of the rare earths

L. L. Ames、Patrick N. Walsh、David P. White1967-07-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRare earths. IV. Dissociation energies of the gaseous monoxides of the rare earthsLynford L. Ames, Patrick N. Walsh, and David WhiteCite this: J. Phys. Chem. 1967, 71, 8, 2707–2718Publication Date (Print):July 1, 1967Publication History Published online1 May 2002Published in…

Catalytic Processes in Materials ScienceInorganic Fluorides and Related CompoundsMaterial Science and Thermodynamics

Deformation of neutron-irradiated copper single crystals

John V. Sharp1967-07-01Philosophical magazine

The deformation of neutron-irradiated copper single crystals has been studied by transmission electron microscopy techniques. The width of the defect-free channels formed by the passage of dislocations has been measured as a function of temperature, dose and strain, in sections cut normal to the primary glide plane. T…

Microstructure and mechanical propertiesFusion materials and technologiesNuclear Materials and Properties

Darstellung, IR‐ und Elektronenspektren von Azido‐Metall‐Komplexen

Wolfgang Beck、Wolf Peter Fehlhammer、P. Pöllmann 等 5 位作者1967-07-01Chemische Berichte

Abstract Die Darstellung von Tetraphenylarsonium‐, ‐phosphonium‐ oder Ammonium‐Salzen der Azido‐Komplexe [Sn(N 3 ) 6 ] 3‐ , [Pb(N 3 ) 6 ] 2‐ , [Cr(N 3 ) 6 ] 3‐ , [Rh(N 3 ) 6 ] 2‐ , [Pt(N 3 ) 6 ] 2‐ . [Mn(N 3 ) 4 ] 2‐ , [Pd(N 3 ) 4 ] 2‐ , [Pd 2 (N 3 ) 6 ] 2‐ , [Pt(N 3 ) 4 ] 2‐ , [Au(N 3 ) 4 ] − , [Zn(N 3 ) 4 ] 2‐ , [Cd…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Mass spectrometry of porphyrins. II. Characterization of petroporphyrins

Earl W. Baker、Teh Fu Yen、John P. Dickie 等 5 位作者1967-07-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMass spectrometry of porphyrins. II. Characterization of petroporphyrinsEarl Wayne. Baker, Teh Fu. Yen, John P. Dickie, Robert E. Rhodes, and Leslie F. ClarkCite this: J. Am. Chem. Soc. 1967, 89, 14, 3631–3639Publication Date (Print):July 1, 1967Publication History Published…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesPorphyrin Metabolism and Disorders

Precision and sensitivity in electron microprobe analysis

T. O. Ziebold1967-07-01Analytical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPrecision and sensitivity in electron microprobe analysisThomas O. ZieboldCite this: Anal. Chem. 1967, 39, 8, 858–861Publication Date (Print):July 1, 1967Publication History Published online1 May 2002Published inissue 1 July 1967https://pubs.acs.org/doi/10.1021/ac60252a028ht…

Advancements in Photolithography TechniquesX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Effect of Elastic Constants on Stress In A Composite Under Plane Deformation

J. Dundurs1967-07-01Journal of Composite Materials

When a composite body consisting of two isotropic and elastic phases is subjected to prescribed surface tractions, generally the stress field depends on three parameters involving the elastic con stants. If the composite is in a state of plane deformation, and there are no net forces on internal boundaries, however, t…

Material Properties and ApplicationsStructural mechanics and materialsAdvanced Theoretical and Applied Studies in Material Sciences and Geometry

CURRENT SATURATION AND PHOTOFERROELECTRIC EFFECT IN SbSI

V. M. Fridkin、I. I. Groshik、V. A. Lakhovizkaya 等 5 位作者1967-06-15Applied Physics Letters

The illumination of the ferroelectric SbSI in the spectral region where a maximum of photoconductivity of this crystal took place (λ ≃ 6200 Å) decreased the ferroelectric polarization. This resulted in the appearance of a region of saturation of the V-I characteristic and in the decrease of the pyrocurrent, being meas…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyMaterial Science and Thermodynamics

Experimental and Theoretical Study of Phonon Scattering from Simple Point Defects in Sodium Chloride

R. F. Caldwell、M. V. Klein1967-06-15Physical Review

Thermal-conductivity measurements have been made as a function of temperature on sodium chloride crystals containing the nine monovalent substitutional impurities: ${\mathrm{F}}^{\ensuremath{-}}$, ${\mathrm{Br}}^{\ensuremath{-}}$, ${\mathrm{I}}^{\ensuremath{-}}$, ${\mathrm{Li}}^{+}$, ${\mathrm{K}}^{+}$, ${\mathrm{Rb}}…

Thermal properties of materialsThermal Radiation and Cooling TechnologiesThermal Expansion and Ionic Conductivity

Ionization potentials of ammonia

D.C. Frost、C. A. McDowell、D. A. Vroom1967-06-15Canadian Journal of Chemistry

The kinetic energy spectrum of photoelectrons ejected from ammonia by monochromatic 584 Å (21.21 eV) radiation has been determined using a spherical grid energy analyzer. Ionization potentials of 10.35 and 14.95 eV have been deduced from the spectrum and the relative transition probabilities to the ionic states have b…

Advanced Chemical Physics StudiesLuminescence Properties of Advanced MaterialsX-ray Spectroscopy and Fluorescence Analysis

Crystal structure of cesium methylsulfonate, CsCH3SO3

J. K. Brandon、I. D. Brown1967-06-15Canadian Journal of Chemistry

Cesium methylsulfonate, CsCH 3 SO 3 , crystallizes in space group Pnma with a = 9.526, b = 6.264, and c = 8.692 Å. Three-dimensional X-ray diffraction data have been collected photographically and refined to give a weighted agreement index (R) of 0.12. The structure is related to, but is not identical with, that of th…

Crystal structures of chemical compoundsCrystallography and molecular interactionsSolid-state spectroscopy and crystallography

Chalcogenides of the transition elements. V. Crystal structures of the disulfides and ditellurides of ruthenium and osmium

Sutarno、Osvald Knop、Kenneth I. G. Reid1967-06-15Canadian Journal of Chemistry

The crystal structures of RuS 2 , OsS 2 , RuTe 2 , and OsTe 2 were refined isotropically by least squares from powder diffractometer data using individual temperature factors. The resulting positional parameters of the chalcogen atoms in these C2-type structures are 0.3879 ± 14, 0.3865 ± 19, 0.3739 ± 9, and 0.3725 ± 1…

Chalcogenide Semiconductor Thin FilmsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Hall Effect in CoO, NiO, andα−Fe2O3

H. J. van Daal、A.J. Bosman1967-06-15Physical Review

The Hall coefficient ${R}_{H}$ and resistivity $\ensuremath{\rho}$ have been measured on ceramic samples of $p$-type CoO and NiO between 200 and 1500\ifmmode^\circ\else\textdegree\fi{}K and of $n$-type $\ensuremath{\alpha}\ensuremath{-}{\mathrm{Fe}}_{2}{\mathrm{O}}_{3}$ between 960 and 1500\ifmmode^\circ\else\textdegr…

Magnetic properties of thin filmsMultiferroics and related materialsMagnetic Properties and Synthesis of Ferrites

Shubnikov—de Haas Effect in SrTiO3

H. P. R. Frederikse、W. R. Hosler、W. R. Thurber 等 5 位作者1967-06-15Physical Review

The magnetoresistance of semiconducting SrTi${\mathrm{O}}_{3}$ has been investigated in high magnetic fields (up to 150 kOe). In the temperature range 1.4-2.1 \ifmmode^\circ\else\textdegree\fi{}K, for fields of more than 50 kOe, well-developed Shubnikov-de Haas-type oscillations have been observed. The data support a…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

The zinc sulphide polytypes 14L(7 7); 18L(4 2)3; 24L(7 5 5 7) and 36L(6 2 2 2)3

S. Mardix、O. Brafman、I. T. Steinberger1967-06-10Acta Crystallographica

The identification of the layer sequences of the polytypes listed above is reported. The birefringence of these structures is also given. Two of the identified structures [14L (7 7) and 24L (7 5 5 7)] have unitcell dimensions identical with those of structures previously reported [14L (5 4 2 3) and 24 L(5 3)3 respecti…

Magnetism in coordination complexesCrystal Structures and PropertiesOrganometallic Compounds Synthesis and Characterization

Phonon-Induced Ion-Ion Coupling in Paramagnetic Salts

R. Orbach、M. Tachiki1967-06-10Physical Review

The zero-point phonon vibrations in a paramagnetic crystal are shown to give rise to an effective ion-ion coupling. Expressions are derived for ion-energy transitions $\ensuremath{\Delta}$ both greater and less than the phonon-cutoff energy $\ensuremath{\hbar}{\ensuremath{\omega}}_{0}$. In the former case, the couplin…

Perovskite Materials and ApplicationsOrganic and Molecular Conductors ResearchSolid-state spectroscopy and crystallography

Synthesis and lattice constants of transition metal thioniobates with berthierite structure

M. Eibschütz、E. Hermon、S. Shtrikman1967-06-10Acta Crystallographica

Abstract : Compounds with chemical formula MNb2S4 where M is one of the divalent transition metals Mn, Fe, Co, Ni, Cu were synthesized. The lattice constants of these compounds, isomorphous with berthierite (FeSb2S4), were determined from the powder diffraction data, using Cohen's analytical method. (Author)

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyInorganic Chemistry and Materials