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A theoretical investigation of the influence of molecular relaxation and internal stress on diffusion in polymers

J Crank1953-08-01Journal of Polymer Science

Abstract Recent experiments have indicated that the diffusion properties of a penetrant‐polymer system may change with time as diffusion proceeds. It is thought that two possible explanations of these time effects are slow changes of polymer structure accompanying diffusion and internal stresses exerted by one part of…

Polymer crystallization and propertiesMembrane Separation and Gas TransportRecycling and Waste Management Techniques

Thermal Expansion of Zirconium between 298°K and 1600°K

Gordon B. Skinner、Herrick L. Johnston1953-08-01The Journal of Chemical Physics

The average coefficients of thermal expansion of hexagonal zirconium between 298°K and 1143°K are 5.5×10−6 deg−1 along the a axis, 10.8×10−6 deg−1 along the c axis, and 7.2×10−6 deg−1 for a randomly oriented polycrystalline sample. The average value of the linear coefficient of expansion of cubic zirconium between 114…

Intermetallics and Advanced Alloy PropertiesNuclear Materials and PropertiesTitanium Alloys Microstructure and Properties

Double Hysteresis Loop of BaTiO3at the Curie Point

Walter J. Merz1953-08-01OpenAlex

It is known that the Curie point $\ensuremath{\theta}$ of the ferroelectric BaTi${\mathrm{O}}_{3}$ shifts to higher temperatures when a dc bias field is applied. If the crystal shows a sharp transition, we expect by applying an ac field at the Curie temperature that the crystal would become alternately ferroelectric a…

Ferroelectric and Piezoelectric MaterialsLiquid Crystal Research AdvancementsSolid-state spectroscopy and crystallography

LXXXVI. A note on the Portevin-Le Chatelier effect

Alan Cottrell1953-08-01OpenAlex

Summary Substitutional solute atoms in aluminium usually diffuse too slowly to cause appreciable strain ageing at room temperature. However, if the concentration of vacancies is increased by plastic deformation or by quenching, the rate of diffusion may increase sufficiently to cause strain ageing during plastic defor…

Metal Forming Simulation TechniquesNon-Destructive Testing TechniquesX-ray Diffraction in Crystallography

Hyperfine Structures of the Resonance Lines of Indium (In115)

G. V. Deverall、K. W. Meißner、George J. Zissis1953-07-15Physical Review

In the process of developing an atomic beam light source for use at high oven temperatures an investigation of the indium resonance lines at 4511A and 4101A was carried out. The employment of a well-collimated atomic beam, excited by electron impact, and of a Fabry-Perot interferometer made it possible to resolve clea…

Advanced Chemical Physics StudiesLaser-induced spectroscopy and plasmaElectron and X-Ray Spectroscopy Techniques

A theoretical calculation of the stored energy in a work-hardened material

A. N. Stroh1953-07-07Proceedings of the Royal Society of London A Mathematical and Physical Sciences

Abstract The amount of energy stored in a cold-worked material is calculated on the assumption that the energy is due to piled-up groups of dislocations. It is found that a small percentage of the work done in deformation is stored, and that the amount of energy stored is proportional to the strain. These predictions…

Microstructure and mechanical propertiesHigh-Velocity Impact and Material BehaviorPowder Metallurgy Techniques and Materials

The thermal decomposition of anhydrous nitric acid vapour

Walther R. Ellis、Richard C. Murray1953-07-01Journal of Applied Chemistry

Abstract Calculations from published figures of the equilibrium constants for the decomposition 2HNO 3 H 2 O + 2NO 2 + 1/2O 2 show that the degree of dissociation of nitric acid vapour is quite considerable even at moderate temperatures and reaches 100% at 200° and 1 atmosphere pressure. The rate of dissociation has b…

Catalytic Processes in Materials ScienceThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Conductivity of Thin Films in a Longitudinal Magnetic Field

Ernest Koenigsberg1953-07-01Physical Review

An integral expression for the electrical conductivity of thin films in a longitudinal magnetic field is derived by an analysis of free electron trajectories in the film. This is evaluated in the limit of strong magnetic fields.

Semiconductor materials and devicesCopper Interconnects and ReliabilitySurface and Thin Film Phenomena

Electromechanical Response and Dielectric Loss of Prepolarized Barium Titanate under Maintained Electric Bias. Part I

H. G. Baerwald、D. Berlincourt1953-07-01The Journal of the Acoustical Society of America

In transducer applications of ferroelectric ceramics it is standard practice to rely for the electromechanical response on retained polarization. This is practicable only for moderate driving amplitudes and sufficiently low temperature. At higher driving fields dielectric losses increase inordinately and lead to event…

Ferroelectric and Piezoelectric MaterialsUltrasonics and Acoustic Wave PropagationAcoustic Wave Resonator Technologies

Electrode Contamination in Electron Optical Systems

K. M. Poole1953-07-01Proceedings of the Physical Society Section B

The results of a brief study of the origin and mode of formation of high resistance films on electrodes of demountable systems are presented. Evidence is given that the films are produced by the dissociation of organic molecules into radicals by electron bombardment and the polymerization of the latter. It is shown th…

Electron and X-Ray Spectroscopy TechniquesLaser Design and ApplicationsPhotocathodes and Microchannel Plates

A Molecular Theory of Stress Relaxation in Polymeric Media

Kenneth W. Scott、Richard S. Stein1953-07-01The Journal of Chemical Physics

The application of the kinetic theory of rubber elasticity to the description of the relaxation of cross-linked networks is only permissible in cases where the rate determining process is slow compared to the rate of diffusion of the polymer chains. Relaxation resulting from chemical reactions causing breaking of netw…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesEpoxy Resin Curing Processes

Oxides of the Transition Metals as Catalysts

Alfred Clark1953-07-01Industrial & Engineering Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOxides of the Transition Metals as CatalystsAlfred ClarkCite this: Ind. Eng. Chem. 1953, 45, 7, 1476–1480Publication Date (Print):July 1, 1953Publication History Published online1 May 2002Published inissue 1 July 1953https://pubs.acs.org/doi/10.1021/ie50523a034https://doi.or…

Catalytic Processes in Materials Science

The Thermal Expansion of Anisotropic Metals

Barney Childs1953-07-01Reviews of Modern Physics

A review of the present state of knowledge of the variation with temperature of the thermal expansion of anisotropic metals. The theoretical significance of the experimental data is discussed.DOI:https://doi.org/10.1103/RevModPhys.25.665©1953 American Physical Society

Material Properties and ApplicationsThermodynamic and Structural Properties of Metals and AlloysMetallurgical and Alloy Processes

The Solid Solution Series, Boron-Boron Carbide1

Robert D. Allen1953-07-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Solid Solution Series, Boron-Boron Carbide1Robert D. AllenCite this: J. Am. Chem. Soc. 1953, 75, 14, 3582–3583Publication Date (Print):July 1, 1953Publication History Published online1 May 2002Published inissue 1 July 1953https://pubs.acs.org/doi/10.1021/ja01110a501https…

Electrocatalysts for Energy ConversionBoron and Carbon Nanomaterials ResearchChemical and Physical Properties of Materials

Hall Effects of the Cobalt Nickel Alloys and of Armco Iron

S. Foner、Emerson M. Pugh1953-07-01Physical Review

Experimental investigations of the Hall effects in cobalt, the cobalt-nickel alloys, and Armco iron are described in detail. Precision measurements were made with magnetic fields up to 30 kilogauss in order to separate the ordinary and extraordinary effects. The ordinary effect in all the Co-Ni alloys was found to be…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Field Sensors Techniques

Collagen‐crystal relationships in bone. II. Electron microscope study of basic calcium phosphate crystals

M. Watson、R. A. Robinson1953-07-01American Journal of Anatomy

DEVELOPMENTAL DYNAMICS provides a focus for communication among developmental biologists who study the progressive and dynamic emergence of form and function during embryonic development. The journal is an international forum for the exchange of novel and substantive information on mechanisms that control development.…

Bone health and osteoporosis researchCalcium Carbonate Crystallization and InhibitionCollagen: Extraction and Characterization

Polymerization of Esters of Cinnamic Acid1

C. S. Marvel、G. H. McCain1953-07-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolymerization of Esters of Cinnamic Acid1C. S. Marvel and G. H. McCainCite this: J. Am. Chem. Soc. 1953, 75, 13, 3272–3273Publication Date (Print):July 1, 1953Publication History Published online1 May 2002Published inissue 1 July 1953https://pubs.acs.org/doi/10.1021/ja01109…

biodegradable polymer synthesis and properties

Wetting of Fluorinated Solids by Hydrogen-Bonding Liquids

A. H. Ellison、H. W. Fox、W. A. Zisman1953-07-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTWetting of Fluorinated Solids by Hydrogen-Bonding LiquidsA. H. Ellison, H. W. Fox, and W. A. ZismanCite this: J. Phys. Chem. 1953, 57, 7, 622–627Publication Date (Print):July 1, 1953Publication History Published online1 May 2002Published inissue 1 July 1953https://pubs.acs.o…

Surface Modification and SuperhydrophobicityMaterial Properties and Applications

Ultrasonically Induced Cavitation in Water: A Step-by-Step Process

G. W. Willard1953-07-01The Journal of the Acoustical Society of America

A 2.5-Mc, barium-titanate, spherically focusing radiator was used to produce cavitation in both degassed and aerated water entirely within the restricted, high intensity focal region, remote from the water boundaries. The sonic intensity rises to 1.8 kw/cm2, and the pressure amplitude to ±70 atmos at the focus. High-i…

Cavitation Phenomena in PumpsMicrofluidic and Bio-sensing TechnologiesUltrasound and Cavitation Phenomena

Infrared spectrophotometric studies on polyethylene. I. Structure

Frank M. Rugg、Joseph J. Smith、L. H. Wartman1953-07-01Journal of Polymer Science

Abstract A series of polyethylene resins made by making progressive changes in temperature, pressure, and catalyst content has been studied by infrared absorption spectroscopy. From the methyl content and the number‐averages molecular weight of each resin, it was found that as molecular weight increases degree of bran…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesPolymer Nanocomposites and Properties