Materials Literature
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Abstract The conventional “string‐of‐beads” statistical model for flexible chain polymers is modified for derivation of configurational and thermodynamic properties of long‐chain ring molecules (i.e., flexible linear chains with ends joined) in dilute solution near the Flory temperature. The effect of the intramolecul…
The suggested phase diagrams for the system B 2 O 3 ‐SiO 2 as drawn from the findings of previous investigators are presented. These diagrams show the wide controversy regarding this system. The principal difficulties in obtaining reliable equilibrium data are the volatilization of B 2 O 3 , the hydration of B 2 O 3 ‐…
Measurements of thermal conductivity for the range 3° to 300°K are reported for both pure and heavily doped n- and p-type GaAs single crystals, and n-type heavily doped polycrystalline GaAs1−xPx crystals with six compositions between x=0 and x=0.5. The alloy ingots have much lower K values due to alloy scattering, wit…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Effect of Molecular Weight on the Melting Temperature and Fusion of Polyethylene1J. G. Fatou and L. MandelkernCite this: J. Phys. Chem. 1965, 69, 2, 417–428Publication Date (Print):February 1, 1965Publication History Published online1 May 2002Published inissue 1 February…
Type 310 stainless steel in thin sections was embrittled by hydrogen. The temperature and strain rate dependence of this embrittlement was almost analogous to that well-established for hydrogenated body- centered cubic (b.c.c.) metals, differing only in that at low temperatures and relatively high strain rates complet…
Measurements have been made of coercive force, susceptibility, isothermal remanence, thermoremanence and thermal and alternating field demagnetization of annealed magnetite powders in nine size ranges from 1·5 μ to 120 μ. The samples were dispersed in plaster to occupy a few per cent by volume of the specimens and thu…
Plastically deformed diamond single crystals were irradiated with fast electrons and their optical absorption spectra determined. The results suggest that preferential irradiation damage occurred in regions of high strain and that the group B absorption bands in type I diamonds are associated with strain.
<div class="htmlview paragraph">Studies were conducted using spark-ignited reciprocating engines to evaluate ammonia as an alternate fuel for certain military applications. Conventional engines were found to perform poorly on ammonia. Several practical methods for improving engine performance while burning ammon…
The characteristics of the ``synchrotron light'' emitted by electrons in the NBS 180-MeV electron synchrotron were studied in detail. The electron beam cross section was approximately 1×2 mm. The angular distribution and polarization properties were determined for the visible radiation; photoelectric techniques result…
CONTENTS I. Introduction 46 II. Short description of the methods for the preparation of pyrographite 47 III. Physicochemical processes occurring during the preparation of pyrographite 47 IV. Structure of pyrographite 50 V. Properties of pyrographite 52 VI. Uses of pyrographite 56
Abstract The acid strengths of organometallic compounds were determined by the color reactions with H AMMETT indicators. The acid strength of triethylaluminum was enhanced by the modification with water. The triethylaluminum/water system showed the maximum acid strength at about 1:1 molar ratio of water/triethylalumin…
Abstract A new technique for performing electron nuclear double resonance experiments, based on the observation of electron spin echoes, has been developed. Radio-frequency resonance transitions are induced during the time interval between pulses II and III of a stimulated echo sequence, and cause a fall in the echo s…
A family of synthetic elastic fibers, designated spandex fibers, has been developed, providing new degrees of sheerness and effective "power" in elastic fabrics. These fibers have segmented polyurethane structures. They are durable, they are white and accept dye readily, and they can be set by heat. The development of…
Experimental results concerning electron ejection from the atomically clean (111) face of nickel by singly charged ions of He, Ne, and Ar are reported. Total yield and kinetic-energy distribution of ejected electrons were measured as functions of ion energy in the range 4 to 100 eV. Revised experimental procedures hav…
The Raman spin-lattice relaxation time ${T}_{1R}$ for the oxygen divacancy (${{E}_{1}}^{\ensuremath{'}}$) center in synthetic crystalline quartz measured in applied magnetic fields of 3 kOe is accurately given by $\frac{1}{{T}_{1R}}=B\frac{{e}^{{x}_{1}}}{{({e}^{{x}_{1}}\ensuremath{-}1)}^{2}}+C\frac{{e}^{{x}_{2}}}{{({e…
Received 18 December 1964DOI:https://doi.org/10.1103/PhysRevLett.14.71©1965 American Physical Society
A theoretical analysis is made of the effect of an external perturbation, such as an electric field, magnetic field, or stress, on the optical properties of color centers. Our analysis is restricted to centers with orbital singlet ground states. It is especially applicable to centers with orbitally degenerate excited…
The rate of self-diffusion in gold was measured by the radioactive-tracer-lathe-sectioning technique at 860, 910, and 960\ifmmode^\circ\else\textdegree\fi{}C and at hydrostatic pressures from 2.00 to 9.08 kbar. The diffusion rate was observed to decrease with increased pressure, and the activation volume for self-diff…
Neutron diffraction techniques have been employed to study the hydrogen-atom configuration in a single-phase sample of beta-PdH at several selected temperatures. The suggested low-temperature ($T\ensuremath{\ll}55\ifmmode^\circ\else\textdegree\fi{}$K) structure of this compound is one which conforms to the space group…
Received 14 December 1964DOI:https://doi.org/10.1103/PhysRevLett.14.64©1965 American Physical Society