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The Protonation of Pyrroles

Y. Chiang、E. B. Whipple1963-09-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Protonation of PyrrolesY. Chiang and E. B. WhippleCite this: J. Am. Chem. Soc. 1963, 85, 18, 2763–2767Publication Date (Print):September 1, 1963Publication History Published online1 May 2002Published inissue 1 September 1963https://pubs.acs.org/doi/10.1021/ja00901a020htt…

Porphyrin and Phthalocyanine ChemistrySurface Chemistry and CatalysisVarious Chemistry Research Topics

Rhenium Catalysts. VII. Rhenium(VI) Oxide1

H. Smith Broadbent、William J. Bartley1963-09-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRhenium Catalysts. VII. Rhenium(VI) Oxide1H. Smith Broadbent and William J. BartleyCite this: J. Org. Chem. 1963, 28, 9, 2345–2347Publication Date (Print):September 1, 1963Publication History Published online1 May 2002Published inissue 1 September 1963https://pubs.acs.org/do…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsNanomaterials for catalytic reactions

On the Accuracy of the Bernoulli-Euler Theory for Beams of Variable Section

Bruno A. Boley1963-09-01Journal of Applied Mechanics

The stresses and deflections of thin rectangular beams of arbitrary variable depth, in pure bending, according to the theory of plane stress, are considered. They are obtained in the form of series; the first term of each series is identical with the strength-of-materials solution and the others represent the necessar…

Composite Structure Analysis and OptimizationHeat Transfer and Mathematical ModelingStructural mechanics and materials

Hydrogen penetration in water-accelerated fatigue of rolling surfaces

L. Grunberg、D. T. Jamieson、D. Scott1963-09-01Philosophical magazine

When a steel ball was rolled under load in contact with three similar balls in the presence of a mineral oil containing tritiated water, both tritium and hydrogen were absorbed by the steel surfaces. The amount of absorbed tritium increased with the time of stressing. All the data for the amount of tritium absorbed by…

Hydrogen embrittlement and corrosion behaviors in metalsMetal Alloys Wear and PropertiesMaterial Properties and Failure Mechanisms

Crosslinking Reactions of Carboxylic Elastomers

Harold P. Brown1963-09-01Rubber Chemistry and Technology

Abstract Carboxyl groups in elastomer molecules have been shown to contribute to the crosslinking or joining of these molecules through hydrogen bonding, salt formation, reaction with diepoxides or polyepoxides including epoxy resins, reaction with diamines or polyamines, esterification with di- or poly-hydric alcohol…

Synthesis and properties of polymersSilicone and Siloxane Chemistry

Effects of preferred orientation on the grain size dependence of yield strength in metals

D. V. Wilson、J. A. Chapman1963-09-01Philosophical magazine

The Petch equation ([sgrave] = [sgrave]0 + kl −½) is applied rather widely in investigations of the sources of the variation of yield stress [sgrave] with grain diameter l in polycrystalline metals. In general, however, the behaviour of randomly oriented aggregates has been considered, so that [sgrave]0 and k are rega…

Microstructure and mechanical propertiesMagnesium Alloys: Properties and ApplicationsAluminum Alloys Composites Properties

Electrocaloric Effect in Ferroelectric Rochelle Salt

G. G. Wiseman、Juergen Kuebler1963-09-01Physical Review

Measurements of the electrocaloric effect in crystalline Rochelle salt throughout the ferroelectric range have been made and have been used to determine the Devonshire "dielectric stiffness" coefficient, the ferroelectric Curie temperatures, and the spontaneous polarization close to both Curie temperatures. The result…

Ferroelectric and Piezoelectric MaterialsConducting polymers and applicationsSolid-state spectroscopy and crystallography

Migration of a Liquid Zone through a Solid: Part I

William A. Tiller1963-09-01Journal of Applied Physics

The migration of slab, cylindrical, and spherical zones through a block of solid under the influence of a temperature gradient has been analyzed theoretically. The relative rates of migration are in the above order if KS>KL and the reverse order if KS<KL (K=thermal conductivity, S=solid, L=liquid). The m…

Solidification and crystal growth phenomenaIntermetallics and Advanced Alloy PropertiesPhase-change materials and chalcogenides

Radiative Transition Probabilities within 4 fn Configurations: The Fluorescence Spectrum of Europium Ethylsulfate

J. D. Axe1963-09-01The Journal of Chemical Physics

The relative intensities of the transitions occurring in the fluorescence spectrum of Eu(C2H5SO4)3·9H2O have been measured at 77° and 4°K. The strengths of both the ``forbidden'' electric dipole transitions and magnetic dipole transitions which were observed are compared to theoretical expressions and the results are…

Glass properties and applicationsLanthanide and Transition Metal ComplexesQuantum optics and atomic interactions

Macroscopic Plastic Properties of Dislocation-Free Germanium and Other Semiconductor Crystals. I. Yield Behavior

J. R. Patel、Ayan Roy Chaudhuri1963-09-01Journal of Applied Physics

Dislocation-free crystals of the semiconductor elements germanium and silicon and the compounds indium antimonide and gallium antimonide have been deformed in tension over a range of temperatures, initial dislocation densities, and strain rates. In all of the dislocation-free crystals, plastic deformation occurs at st…

Microstructure and mechanical propertiesAdvanced Surface Polishing TechniquesIon-surface interactions and analysis

½<111> screw dislocations and the nucleation of {112}<111> twins in the b.c.c. lattice

A.W. Sleeswyk1963-09-01Philosophical magazine

It is shown that in the b.c.c. lattice the crystallography and the commonly observed low stacking-fault energy on {112} lead to the prediction that ½<111> screw dislocations will each dissociate into three 1/6<111> partials situated on {112} planes which intersect along the axis of the original screw dislocation. Calc…

Microstructure and mechanical propertiesHydrogen embrittlement and corrosion behaviors in metalsTitanium Alloys Microstructure and Properties

Bibliography

Equipo Editorial1963-09-01Materiales de Construccion

X-Ray Diffraction and Diffusion in Metal Film Layered Structures

John B. Dinklage、Rudolf Frerichs1963-09-01Journal of Applied Physics

Artificial layered structures that produce sharp diffraction of x rays are described. The structures were made by alternately evaporating 140 Pb and Mg layers onto a glass slide (d=27 Å). The diffracting efficiency of the layered structures is compared with other structures used in soft x-ray spectroscopy. The usefuln…

Metallic Glasses and Amorphous AlloysX-ray Spectroscopy and Fluorescence AnalysisX-ray Diffraction in Crystallography

Melting temperature and change of lamellar thickness with time for bulk polyethylene

James J. Weeks1963-09-01Journal of Research of the National Bureau of Standards Section A Physics and Chemistry

The melting temperature of linear polyethylene has been obtained as a function of the time and temperature of crystallization. Recrystallization was minimized by a special melting procedure. By interpreting the melting points as characteristic of a given lamellar thickness, it was found that the thickness of crystals…

Polymer crystallization and propertiesMicroplastics and Plastic PollutionMaterial Properties and Processing

Infrared Reflectance of Aluminum Evaporated in Ultra-High Vacuum

H. E. Bennett、M. Silver、E. J. Ashley1963-09-01Journal of the Optical Society of America

The specular reflectance of aluminum films evaporated in ultra-high vacuum has been measured with precision in the 0.3- to 32-μ wavelength region. The measured reflectance of these films, which is good to ±0.1%, is significantly higher than that of films prepared under the usual high-vacuum conditions. The reflectance…

Copper Interconnects and ReliabilityOptical Coatings and GratingsSurface Roughness and Optical Measurements

Diffusionless Phase Transformations in Zirconia and Hafnia

G. M. Wolten1963-09-01OpenAlex

A study, by high‐temperature diffractometry, of the monoclinic‐tetragonal phase changes in pure ZrO 2 and HfO 2 disclosed that the hysteresis loops associated with the transformations have similar shapes which are typical of many martensitic phase changes, but that the widths of the loops differ greatly for the two ma…

Advanced ceramic materials synthesisIntermetallics and Advanced Alloy PropertiesInorganic Chemistry and Materials

Ballistic Perforation Dynamics

Rodney F. Recht、Thomas W. Ipson1963-09-01OpenAlex

Analytical equations of the types required to define ballistic perforation dynamics are developed. These equations concern both blunt and sharp-nosed fragments, perforating plates normally and at oblique impact angles. Residual velocities are defined in terms of magnitude and direction. Analytical models and confirmin…

Geophysical Methods and ApplicationsHigh-Velocity Impact and Material BehaviorElectromagnetic Launch and Propulsion Technology