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C2-oxygenated compounds composed mainly of ethanol were catalytically produced from CO and H2 under atmospheric pressure over pyrolysed Rh carbonyl clusters dispersed on specific metal oxides such as TiO2, ZrO2, and La2O3.
Abstract The parameters governing electron backscattering from thin films and from bulk solids are reviewed: Atomic scattering cross‐section, atomic number, single/multiple scattering, film thickness, scattering angular distribution, angle of incidence, diffraction effects. Their influence on some important contrast m…
Ultrasonic velocities at 5 and 10 MHz and spontaneous strains of KD 3 (SeO 3 ) 2 were measured and the results were compared with those for KH 3 (SeO 3 ) 2 . Elastic constants were obtained from the velocity data. The phase transition of KD 3 (SeO 3 ) 2 accompanies an instability of the soft s 44 mode alone, as in the…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPropagation and Depropagnation Rates in the Anionic Polymerization of ε-Caprolactone Cyclic OligomersKoichi Ito and Yuya YamashitaCite this: Macromolecules 1978, 11, 1, 68–72Publication Date (Print):January 1, 1978Publication History Published online1 May 2002Published iniss…
Summary The authors report on the presence of a new alga (which appears to belong to the Rhodophyta) in the thermal acidic environments near the solfatane fumaroles of Campi Flegrei (Naples, Italy). On the ground of the microscopical observations, the authors emphasize that the characteristics of this alga are so pecu…
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Abstract The crystal structure of isotactic poly(4‐methyl‐1‐pentene) was determined by x‐ray analysis. The unit cell is tetragonal, P 4 b 2, with α = 18.70 Å and c (fiber axis) = 13.68 Å; it contains four molecular chains each consisting of seven monomeric units in the fiber period. The molecular conformation is essen…
Laser flash photolysis has been used to characterise the triplet state of metal-free (H2Pc) and copper phthalocyanine (CuPc) in dilute (10–6 mol dm–3) solution in chloronaphthalene. This first observation of the triplet state of CuPc indicates that its lifetime is very short (∼35 ns), but the quantum efficiency of tri…
The paper describes the E, T phase diagram of lead zirconate in electric fields up to 1,400 kV/cm.
Grignard reactions on nickel meso-formyloctaethylporphyrin (1a) yield methyl and phenyl carbinols. The former is readily dehydrated to the meso-vinyl derivative, which by hydrogenation yields the meso-ethyl analogue, and by bromination and dehydrobromination affords the meso-ethynyl compound. The latter is readily oxi…
The circumstances under which steels exhibit intergranular fracture can be classified into four general categories: (1) owing to the presence of certain secondary phases at the grain boundaries; (2) owing to thermal treatments which cause impurity segregation to the grain boundaries without the precipitation of an obs…
Using derivative thermogravimetric analysis (DTG), polybutadiene is shown to degrade by two distinct weight loss events when heated dynamically. The volatile products of the first stage are almost exclusively depolymerization products (butadiene and vinylcyclohexene). The residue—cyclized and crosslinked polybutadiene…
The X-ray emission spectra (Mg-Kβ1,3, Mg-L2,3 M, and O-Kα), X-ray photoelectron spectra, and O-KLL Auger spectra from brucite, Mg[OH]2, are reported. The electronic structure of brucite is discussed using these spectra and a simple Hückel molecular-orbital model. The spectra indicate that the strongest interaction exi…
The kinetic mechanism of CVD deposition has been studied for ( i ) reaction at 675°–940°C for and , ( ii ) reaction at 400°–807°C for and , and ( iii ) reaction at 425°–578°C for and . In combination with the available literature data, the results of the present investigation have been interpreted to show atomic oxyge…
The surface tension γ has been measured for two cyanobiphenyls (5CB and 8CB) at temperatures near the nematic-isotropic transition temperature T c, using the Wilhelmy plate method. Reproducible results were obtained, but only by the exercise of considerable patience: for reasons that are discussed at the end of the pa…
Abstract The relative crystallinity of various moist potato starches were measured by X‐ray diffractometer. The diffraction patterns showed to become sharp with increasing of the amount of sorption moisture. Both areas of crystallinity portion were proportionally correlated with the amount of moisture. On the assumpti…
Earlier neutron-diffraction measurements [Willis (1964), Proc. Br. Ceram. Soc. 1, 9-19] on a single crystal of UO2.12 at 800°C showed that interstitial oxygen atoms enter the UO2 lattice at two kinds of site, which are displaced by about 1 Å along the (110) and (111) directions from the cubic-coordinated interstitial…
An explicit model of contact-charge exchange in polymers is proposed in which the steady-state exchanged charge resides in intrinsic molecular-ion states. The eigenvalue spectra of these states are inferred from metal/polymer contact-charge measurements using a theoretical formalism constructed for this purpose. This…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCryophotoclustering techniques for synthesizing very small, naked silver clusters Agn of known size (where n = 2-5). The molecular metal cluster-bulk metal particle interfaceGeoffrey A. Ozin and Helmut HuberCite this: Inorg. Chem. 1978, 17, 1, 155–163Publication Date (Print)…
From an analysis of the ac deconstriction of the hysteresis loop and microscopical observation of moving domain walls, it is concluded, that the ferroelectric domain stabilization in Mn-doped BaTiO3 crystals is due to bulk effects. Esr measurements have revealed that in reduced crystals Mn2+-V0 associates exist, havin…