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Phase transition and anionic motion in solid [(CH3)2NH2]2SnCl6 as studied by the temperature dependence of 35Cl NQR frequencies and chlorine nuclear relaxation times determined with a pulsed NQR spectrometer

Keizo Horiuchi、Ryuichi Ikeda、Daiyû Nakamura1987-12-01Berichte der Bunsengesellschaft für physikalische Chemie

Abstract The temperature dependence of 35 Cl NQR frequencies of [(CH 3 ) 2 NH 2 ] 2 SnCl 6 was precisely determined between 78 and ca. 250 K. by means of an FT NQR spectrometer. The high‐frequency line of the two 35 Cl NQR signals having the intensity ratio of 2:1 already reported was observed to be split below 102 K.…

Advanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallographyElectron Spin Resonance Studies

The Use of Partial Discharge and Impulse Voltage Testing in the Evaluation of Interturn Insulation Failure of Large Motors

O. M. Nassar1987-12-01IEEE Transactions on Energy Conversion

Several 13.2 kV, 21,000 HP synchronous motors failed as a result of interturn insulation breakdown. Investigation of motor failures indicated that the cause was related to high magnitude, steep fronted surge waves (References 1 and 2). Partial discharge (corona) related failures were discounted without any actual meas…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationElectrical Fault Detection and Protection

Pressure-induced structural transitions and valence change inTlReO4: A high-pressure Raman study

A. Jayaraman、G. A. Kourouklis、L. G. Van Uitert1987-12-01Physical review. B, Condensed matter

The pressure dependence of the Raman-active vibrational modes in ${\mathrm{TlReO}}_{4}$ has been investigated up to 16 GPa, using the diamond-anvil cell. The abrupt changes in the Raman spectra indicate that three pressure-induced phase transitions occur at 0.5, 1.9, and 9.7 GPa. The first two transitions are not acco…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsSolid-state spectroscopy and crystallography

Development of dispersion in the mixing of calcium carbonate into polymer blends in an internal mixer

Yoshiyuki Suetsugu、James L. White、Thein Kyu1987-12-01Advances in Polymer Technology

Abstract An experimental study of agglomeration tendency and the compounding of calcium carbonates of varying particle size into polypropylene and polystyrene melts in an internal mixer and in a two roll mill is described. The tendency of particles to agglomerate was studied using the sedimentation volume method. Aggl…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesRheology and Fluid Dynamics Studies

Selected Methods of Investigation for Blood‐Contact Surfacesa

Robert Baier1987-12-01Annals of the New York Academy of Sciences

It is imperative that operating personnel and regulatory agencies have secure, advance, and accurate knowledge of the true surface properties of materials to be contacted with flowing blood. The actual devices must be characterized in their sterile, immediate pre-exposure states. Although very sensitive electronic ins…

Central Venous Catheters and HemodialysisPolymer Surface Interaction Studies

Pattern formation behind a moving cholesteric–smectic-Ainterface

Patrick Oswald、John Bechhoefer、Albert Libchaber 等 4 位作者1987-12-01Physical Review A

We study experimentally the patterns behind a moving cholesteric--smectic-A interface. There are three interface types, each of which corresponds to one of the three basic topologically possible configurations.

Liquid Crystal Research AdvancementsAdvanced Materials and MechanicsCharacterization and Applications of Magnetic Nanoparticles

Raman-gain estimates for high-gain optical fibers

M. E. Lines1987-12-01Journal of Applied Physics

The amplification of light signals by the mechanism of stimulated Raman scattering is discussed, with specific reference to certain heavy-metal germanate and arsenate glasses with Raman-gain-coefficients G of up to 20 times that of fused silica. Calculations are presented of the intrinsic scattering losses from Raylei…

Glass properties and applicationsLaser Material Processing TechniquesPhotonic Crystal and Fiber Optics

Flexibility and rigidity, requirements for the function of proteins and protein pigment complexes

Robert Huber1987-12-01Biochemical Society Transactions

Proteins may be rigid or flexible to various degrees as required for optimum function. Flexibility at the level of amino acid side-chains occurs universally and is important for binding and catalysis. Flexibility of large parts of a protein which rearrange or move are particularly interesting and will be discussed her…

Enzyme Structure and Function

Phase behavior of ternary polymer blends

A. C. Su、Joel Fried1987-12-01Polymer Engineering and Science

Abstract The effect of varying interaction parameters on the phase diagrams of ternary polymer blends was explored by simulating spinodals through use of the Flory‐Huggins lattice theory. Results indicate that miscibility is favored for the case of ternary mixtures of marginally miscible or marginally immiscible pairs…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

Structural Retention of Decatungstates upon Photoreduction

Yoh Sasaki、Toshihiro Yamase、Yuji Ohashi 等 4 位作者1987-12-01Bulletin of the Chemical Society of Japan

Abstract The crystal structures of oxidized and photoreduced decatungstates are compared. Three specimens of decatungstate complexes were prepared in mixed solvents of H2O–CH3CN and were characterized by X-ray diffraction. Unit cell parameters are as follows: (C6H16N)4[W10O32]·2CH3CN; DECA Mr=2841.4, monoclinic, P21⁄n…

Radical Photochemical ReactionsPhotochromic and Fluorescence ChemistryChemical Synthesis and Reactions

“PC-PDF”: A Search/Display System Utilizing the CD-ROM and the Complete Powder Diffraction File

R. Jenkins、Mark Holomany1987-12-01Powder Diffraction

Abstract The Powder Diffraction File (PDF) is a collection of single phase X-ray powder patterns, maintained and distributed by the JCPDS-International Centre for Diffraction Data. Over the past 10 years there has been increasing use of the PDF in computer readable form, but the limited amount of disk space available…

Advanced Condensed Matter PhysicsMachine Learning in Materials ScienceX-ray Diffraction in Crystallography

Adsorption Kinetics of Protein Mixtures A Tentative Explanation of the Vroman Effect

Peter Cuypers、George M. Willems、H.C. Hemker 等 4 位作者1987-12-01Annals of the New York Academy of Sciences

A model for protein adsorption kinetics has been presented. This model includes diffusion-limited adsorption, adsorption and desorption rate constants kon and koff, which are dependent on the surface concentration, and an interaction term for the mutual influence of the adsorbed protein molecules. It has been shown th…

Polymer Surface Interaction StudiesHemoglobin structure and functionElectrohydrodynamics and Fluid Dynamics

Synthesis, electrochemistry, and ligand-addition reactions of gallium(III) porphyrins

Karl M. Kadish、J. L. Cornillon、Athanassios G. Coutsolelos 等 4 位作者1987-12-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis, electrochemistry, and ligand-addition reactions of gallium(III) porphyrinsK. M. Kadish, J. L. Cornillon, A. Coutsolelos, and R. GuilardCite this: Inorg. Chem. 1987, 26, 25, 4167–4173Publication Date (Print):December 1, 1987Publication History Published online1 May…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresCO2 Reduction Techniques and Catalysts

Zur Stabilität von Doppelchloriden in den Systemen ACI/PrCl3(A NaCs)

H. J. Seifert、J. Sandrock、J. Uebach1987-12-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Die pseudobinären Systeme ACl/PrCl 3 (A = NaCs) wurden mittels DTA neu untersucht. Folgende Verbindungen wurden gefunden (erstmalig nachgewiesene Verbindungen sind unterstrichen) K 3 PrCl 6 ; K 2 PrCl 5 ; Rb 2 PrCl 5 , Cs 3 PrCl 6 , , CsPr 2 Cl 7 . Messungen der Lösungsenthalpien, der freien Enthalpien für d…

Solid-state spectroscopy and crystallographyInorganic Chemistry and MaterialsInorganic Fluorides and Related Compounds

Determination of Twist Elastic Constant K22 in 5CB by Four Independent Light-Scattering Techniques

Takehiro Toyooka、Guoping Chen、Hideo Takezoe 等 4 位作者1987-12-01Japanese Journal of Applied Physics

The twist elastic constant K 22 in 5CB was determined as a function of temperature by the following four independent methods; (1) electric field static light scattering, (2) electric field dynamic light scattering, (3) angular dependence of the scattered light intensity combined with a K 11 or K 33 measurement, and (4…

Liquid Crystal Research AdvancementsForce Microscopy Techniques and ApplicationsOptical Polarization and Ellipsometry

Four new apochlorotic diatoms

Chia-Wei Li、Benjamin E. Volcani1987-12-01British Phycological Journal

The morphology, culture, and nutrition of four new species of apochlorotic diatoms (Nitzschia lucisensibilis, N. fluorescens, N. albicostalis and Hantzschia achroma) are described. A key to the seven apochlorotic diatoms, including the three known species (N. putrida, N. leucosigma and N. alba), is included.

Analytical chemistry methods developmentAquatic Ecosystems and Phytoplankton DynamicsDiatoms and Algae Research

Minimal area design of power/ground nets having graph topologies

S. Chowdhury、M.A. Breuer1987-12-01IEEE Transactions on Circuits and Systems

This paper deals with one aspect of routing power and ground nets in integrated circuits composed of modules, where the nets are routed in the channels between the modules. Constraints are assumed on allowable voltage drops for maintaining proper logic levels and switching speed. A procedure for determining the width…

Low-power high-performance VLSI designVLSI and FPGA Design TechniquesCopper Interconnects and Reliability

Dipole orientation in Cr-modified BaTiO3 ceramics

H. Neumann、G. Arlt1987-12-01Ferroelectrics

A model for the time behaviour of the internal bias field determined by dipole orientation of the transition metaloxygen vacancy type is presented. The measurements of a coarse grained BaTiO3 ceramic doped with 0.5 mol% Cr (grain size about 50μm, density 96%) show that the computer calculations describe satisfactorily…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Molecular weight dependence of mechanical properties of poly(p,p′‐oxydiphenylene pyromellitimide) films

Willi Volksen、Patricia M. Cotts、Do Y. Yoon1987-12-01Journal of Polymer Science Part B Polymer Physics

Abstract The mechanical properties, i.e., Young's modulus, elongation, and tensile stress, were determined as functions of the molecular weight for films of poly(oxydi‐ p ‐phenylene pyromellitimide) prepared by thermal cyclization of the precursor poly(amic acid). The molecular weights of the samples were controlled b…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersTribology and Wear Analysis

Graphite Intercalation Compounds

Hiroshi Kamimura1987-12-01Physics Today

Graphite intercalation compounds are synthetic metals formed by inserting layers of atoms or molecules of a guest chemical species between the layers of carbon atoms that make up graphite. Because carbon occupies a middle position in the order of electronegativity of the elements in the periodic table, graphite welcom…

Advancements in Battery MaterialsGraphene research and applicationsFiber-reinforced polymer composites