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Allotropy in Some Rare-Earth Metals at High Pressures

G. J. Piermarini、C. E. Weir1964-04-03Science

Allotropes of lanthanum, cerium, praseodymium, and neodymiumc have been observed at elevated pressures with an x-ray diffraction camera which incorporates a diamondanvil, high-pressure cell. In each case a high-pressure modification was observed which has a face-centered cubic structure. At room temperature the unit c…

Rare-earth and actinide compoundsQuasicrystal Structures and PropertiesThermodynamic and Structural Properties of Metals and Alloys

17-Azasteroids. I1

S. Rakhit、Marcel Gut1964-04-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXT17-Azasteroids. I1Sumanas Rakhit and Marcel GutCite this: J. Org. Chem. 1964, 29, 4, 859–862Publication Date (Print):April 1, 1964Publication History Published online1 May 2002Published inissue 1 April 1964https://pubs.acs.org/doi/10.1021/jo01027a022https://doi.org/10.1021/j…

Phytochemical Studies and BioactivitiesPhytochemistry and Bioactive CompoundsSteroid Chemistry and Biochemistry

Pyrenoids, Raphes, and Other Fine Structure in Diatoms

Ryan W. Drum、H. Stuart Pankratz1964-04-01American Journal of Botany

Pyrenoids of 6 diatoms, Acnanthes minutissima, Cyclotella meneghiniania, Cymbella affinis, Gomphonema parvulum, Nitzschia sp., and Surirella ovalis, were examined comparatively with the electron microscope. All except those of G. parvulum were membrane-limited. The pyrenoid membrane forms a ridge around the pyrenoid o…

Diatoms and Algae Research

The vibrational spectrum of a disordered linear system

R L Agacy1964-04-01Proceedings of the Physical Society

Schmidt's functional equation determining the vibrational spectrum of a disordered, linear system is solved numerically for some chosen parameters. The resulting spectrum is found to agree very well with the corresponding spectrum obtained by Dean in 1960 but to differ appreciably from the results of the moment-trace…

Spectroscopy and Quantum Chemical StudiesSolid-state spectroscopy and crystallographyElectron Spin Resonance Studies

Rubber elasticity in highly crosslinked polyethyl acrylate

D. Katz、A. V. Tobolsky1964-04-01Journal of Polymer Science Part A General Papers

Abstract Copolymers of ethyl acrylate with three different dimethacrylates were prepared over the complete range of copolymer composition. Modulus temperature curves of these polymers were constructed and contrasted with the modulus temperature curves of phenol–formaldehyde type polymers. The ethyl acrylate–dimethacry…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and Properties

On the Origin of Unpaired Electrons in Metal-Free Phthalocyanine

Jacques M. Assour、S. E. Harrison1964-04-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOn the Origin of Unpaired Electrons in Metal-Free PhthalocyanineJ. M. Assour and S. E. HarrisonCite this: J. Phys. Chem. 1964, 68, 4, 872–876Publication Date (Print):April 1, 1964Publication History Published online1 May 2002Published inissue 1 April 1964https://pubs.acs.org…

Porphyrin and Phthalocyanine ChemistryElectrochemical Analysis and ApplicationsPhotoreceptor and optogenetics research

The Adsorption of Water Vapor onto Silver Iodide

Noubar Tcheurekdjian、A. C. Zettlemoyer、J. J. Chessick1964-04-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Adsorption of Water Vapor onto Silver IodideNoubar Tcheurekdjian, A. C. Zettlemoyer, and J. J. ChessickCite this: J. Phys. Chem. 1964, 68, 4, 773–777Publication Date (Print):April 1, 1964Publication History Published online1 May 2002Published inissue 1 April 1964https://…

Radioactive element chemistry and processingElectrochemical Analysis and ApplicationsCovalent Organic Framework Applications

X-Ray Determination of the Crystal Structure of Potassium Rhenium Hydride

Kerro Knox、A. P. Ginsberg1964-04-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTX-Ray Determination of the Crystal Structure of Potassium Rhenium HydrideK. Knox and A. P. GinsbergCite this: Inorg. Chem. 1964, 3, 4, 555–558Publication Date (Print):April 1, 1964Publication History Published online1 May 2002Published inissue 1 April 1964https://doi.org/10.…

Asymmetric Hydrogenation and CatalysisMachine Learning in Materials ScienceX-ray Diffraction in Crystallography

PYRENOIDS, RAPHES, AND OTHER FINE STRUCTURE IN DIATOMS

Ryan W. Drum、H. Stuart Pankratz1964-04-01American Journal of Botany

Pyrenoids of 6 diatoms, Acnanthes minutissima, Cyclotella meneghiniania, Cymbella affinis, Gomphonema parvulum, Nitzschia sp., and Surirella ovalis, were examined comparatively with the electron microscope. All except those of G. parvulum were membrane‐limited. The pyrenoid membrane forms a ridge around the pyrenoid o…

Marine and coastal ecosystemsAlgal biology and biofuel productionDiatoms and Algae Research

On the Properties of TaS3, TaSe3 and TaTe4

Einar Bjerkelund、Arne Kjekshus1964-04-01Zeitschrift für anorganische und allgemeine Chemie

The properties of TaS3, TaSe3 and TaTe4 have been studied by means of X-ray diffraction, density and magnetic susceptibility measurements: TaS3 crystallizes orthorhombic with TaSe3 crystallizes monoclinic with TaTe4 crystallizes tetragonal with The compounds have diamagnetic susceptibilities.

2D Materials and ApplicationsPhase-change materials and chalcogenidesAdvanced Physical and Chemical Molecular Interactions

Über Wismutoxide. VI. Überein Wismut (III)‐oxid mit höherem Sauerstoffgehalt (β‐Modifikation)

G. Gattow、Doreen Schütze1964-04-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Während durch extrem scharfes Abschrecken dünner Schichten von geschmolzenem Bi 2 O 3 das bei Zimmertemperatur metastabile β‐BiO 1,50 hergestellt werden kann, entstehen durch Umsetzung von Bi oder Bi 2 O 3 + C im Graphit‐Schiffchen mit Sauerstoff ≥ 800°C Präparate der Zusammensetzung β‐BiO > 1,50 . Die Pha…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsCatalysis and Oxidation Reactions

Kinetics of the Copper-Ferric Chloride Reaction and the Effects of Certain Inhibitors

Wes Burrows、C. T. Lewis、D. E. Saëre 等 4 位作者1964-04-01Industrial & Engineering Chemistry Process Design and Development

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTKinetics of the Copper-Ferric Chloride Reaction and the Effects of Certain InhibitorsW. H. Burrows, C. T. Lewis Jr., D. E. Saëre, and R. E. BrooksCite this: Ind. Eng. Chem. Process Des. Dev. 1964, 3, 2, 149–159Publication Date (Print):April 1, 1964Publication History Publish…

Inorganic and Organometallic ChemistryThermal and Kinetic AnalysisChemistry and Chemical Engineering

21—THE PERMEABILITY OF CROSS-WOUND COTTON YARN PACKAGES

M. J. Denton1964-04-01Journal of the Textile Institute Transactions

The effects of package dimensions, structure, and density on the flow of air and water through yarn packages have been investigated. Packages are considered as homogeneous porous bodies, and the experimental results are correlated by theoretical relationships based on Darcy's law and the Kozeny–Carman equation. The pa…

Textile materials and evaluationsMaterial Properties and Processing

Urethane Elastomers Containing Disulfide and Tetrasulfide Linkages

G. Owen、W. J. MacKnight、A. V. Tobolsky1964-04-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTUrethane Elastomers Containing Disulfide and Tetrasulfide LinkagesG. D. T. Owen, W. J. MacKnight, and A. V. TobolskyCite this: J. Phys. Chem. 1964, 68, 4, 784–786Publication Date (Print):April 1, 1964Publication History Published online1 May 2002Published inissue 1 April 196…

Polymer composites and self-healing

Paramagnetic Susceptibility of Eu2O3 from 300° to 1300°K

Sigurds Arajs、R. V. Colvin1964-04-01Journal of Applied Physics

The magnetic susceptibility of Eu2O3 has been studied as a function of temperature between 300° and 1300°K. The results can be satisfactorily explained by the Van Vleck theory of paramagnetism with Judd's energy levels of free Eu3+ ions.

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesIron oxide chemistry and applications

Phase Relations in the System UO 2 ‐UO 3 – Y 2 O 3

S. F. Bartram、E.F. Juenke、E.A. Aitken1964-04-01Journal of the American Ceramic Society

The phase relations in the system U02‐U03‐Yz03, particularly in the Y203‐rich region, were examined by X‐ray and chemical analyses of reacted powders heated at temperatures up to 1700°C in H 2 , CO 2 ‐CO 2 and air. Four phases were identified in the system at temperatures between 1000° and 1700°C: U308, face‐centered…

Radioactive element chemistry and processingNuclear Materials and PropertiesNuclear materials and radiation effects

Thermodynamic aspects of the magnetic transitions in the chromium tellurides Heat Capacities of Cr5Te6, Cr3Te4 and Cr2Te3 from 5 to 350°K

Fredrik Grønvold、Edgar F. Westrum1964-04-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Heat capacities of three chromium tellurides representing the compounds Cr 5 Te 6 and Cr 3 Te 4 with monoclinically‐deformed structures, and Cr 2 Te 3 with hexagonal structure were determined over the range from 5 to 350°K. Values of the heat capacities, enthalpy functions, and entropy increments are tabulate…

Magnetic and transport properties of perovskites and related materialsPhase-change materials and chalcogenidesHeusler alloys: electronic and magnetic properties

The scattering of long wavelength neutrons by defects in neutron-Irradiated graphite

D.G. Martin、R.W. Henson1964-04-01Philosophical magazine

The additional elastic scattering of monochromatic neutrons, wavelength 7·5 Å, produced by irradiating a sample of AGXP graphite to a dose of 6 × 1019 fast neutrons/cm2 at 30°C has been measured as a function of the scattering angle. If we make the reasonable assumptions that equal concentrations of vacancies and inte…

Nuclear reactor physics and engineeringNuclear Physics and ApplicationsGraphite, nuclear technology, radiation studies

AN INFRARED STUDY OF THE ADSORPTION OF AMMONIA ON POROUS VYCOR GLASS

Noel W. Cant、L. H. Little1964-04-01Canadian Journal of Chemistry

The infrared spectrum of ammonia adsorbed on porous glass at 20 °C and 150 °C has been studied in the region 1450–4000 cm −1 . No absorption band due to the asymmetric bending mode of ammonia was observed but in the NH stretching region, bands occurred at 3280 cm −1 , 3320 cm −1 , 3365 cm −1 , and 3400 cm −1 . The ban…

Glass properties and applicationsMesoporous Materials and CatalysisAerogels and thermal insulation

THE EFFECT OF WATER VAPOR UPON THE DEHYDRATION OF CaSO4•2H2O

H. G. McAdie1964-04-01Canadian Journal of Chemistry

Kinetics of the two-stage dehydration of CaSO 4• 2H 2 O have been examined under controlled water vapor pressures up to one atmosphere. For both stages water vapor initially accelerated the rate of dehydration and subsequently retarded it. Separate, temperature-dependent water vapor pressures were noted above which ea…

Spectroscopy and Quantum Chemical StudiesCalcium Carbonate Crystallization and InhibitionCrystallization and Solubility Studies