Materials Literature
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Predictions of the possible post-transition symmetries of an R3̄c zone center continuous phase transition are made using recent extensions of the Landau theory. The Landau theory is summarized and direct group theoretical methods are applied to the R3̄c phase. General techniques for solving systems of nonlinear polyno…
Abstract Diffusion of m‐sulfobenzoic acid in nylon 6 was measured by using the S‐35 labelled acid as a tracer. A multimodal mechanism, identical to that in a preceding paper on sorption, was assumed, according to which the protonated acid diffused by dissolution, and the two dissociated acids diffused by competitive i…
Abstract Results of an investigation of the influence of processing conditions on the structure of branched polyethylene are presented. Under extreme conditions of processing the polymer was found to undergo changes of the molecular weight distribution, and small quantities of oxygen are bound in the form of carbonyl…
Abstract It is found that the virtual crystal model of a disordered binary alloy (in which the alloy is considered as an effective monatomic solid with atoms of intermediate characteristics between those of the two component metals) explains the tendency for a negative deviation of the alloy volume with respect to the…
A brief background of flame resistant rayon is presented, including alternative retardants. The paper covers performance data of flame resistant rayon made from poly(propoxyphosphazene) including vertical flame test results, heat shrinkage, smoke density, and thermal convective test results. Some toxicological data ar…
Aromatic/aliphatic regular copolyoxamides were prepared from aromatic diamine-oxamides and aliphatic diacid chlorides of various lengths of methylene groups by solution polymerization. The aromatic diamine oxamides, N,N′-bis(4-aminophenyl)oxamide and N,N′-bis(3-aminophenyl)oxamide were prepared and both were reacted w…
This paper describes measurements of the magnitude and distribution of residual fields around a tri-post insulator in compressed SF6, after being subjected to sustained dc voltages of several hundred kV, of negative and positive polarity. The effects of geometry associated with insulator leg fittings, particle-trap sl…
This paper discribes various optimum design conditions for a three-phase encapsulated gas insulated bus-bar (3 phase GIB) on the basis of the results of the quantitative analysis and the experiments with respect to the short circuit electromagnetic force. It reveals that the characteristics of the short circuit oscill…
Optical signs of type I and II micellar cholesteric lyotropic mesophases were for the first time determined. Lyomesophases were prepared from the following amphiphiles: potassium l-N-lauroyl-serinate, potassium laurate, sodium decylsulfate, cesium decylsulfate and decyl-ammonium chloride. Cholesterol was added to all…
Uniaxial and biaxial tests were compared in terms of their efficiency and accuracy in determining Poisson's ratios for thermally bonded nonwoven fabrics. The uniaxial test did not provide as true an estimate of the ratio as the biaxial test, because the binder fiber film characteristics dominated the effect on dimensi…
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The X-ray photoemission (XPS) spectra of the valence band and 2p core lines of metallic chromium are presented. A considerable deviation is observed in the shape of the valence band between the experimental spectrum and the theoretical one-electron spectrum. This discrepancy is mainly due to the d band being too broad…
When peracetylated wood, prepared in an acetic anhydride-pyridine medium, was saponified and recrystallized, almost no conversion of cellulose I to cellulose II took place. Neither was conversion detected, when thirteen species of wood, differing in density from 0.17 to 0.71, as well as in lignin content from 18.1 to…
Abstract Polystyrene‐oligoacrylamide graft copolymer was synthesized by the esterification between chloromethylated polystyrene and carboxyl group terminated acrylamide oligomers using phase transfer catalyst such as tetrabutylammonium chloride in toluene‐ and/or DMF/water. The graft copolymers having hydrophobic back…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOptical absorption and ESR spectra of monomeric rhodium(II) tetraphenylporphyrin in 2-methyltetrahydrofuran solution at 77 KMikio Hoshino, Katsutoshi Yasufuku, Shiro Konishi, and Masashi ImamuraCite this: Inorg. Chem. 1984, 23, 13, 1982–1984Publication Date (Print):June 1, 1…
Abstract The infrared and Raman spectra (600 to 10 cm −1 ) of polycrystalline samples and of single crystals of HfS 3 are investigated. A complete assignment is proposed and the frequencies of normal modes in HfS 3 , ZrS 3 , and TiS 3 are compared. Resonance Raman spectra of HfS 3 are recorded using a variety of Kr +…
Scientists working in the field of liquid crystals have become increasingly interested in the practical applications of dichroic dyes dissolved in liquid crystal matrices. This interest is due to a number of factors. Firstly an improved contrast of an image can be achieved in displays using this “guest-host” effect in…
It is shown that the relatively large concentration of impurities in cables is even higher in water trees. Gas bubbles observed in cavities filled with different salt solutions generate very high pressures able to fracture XLPE samples. It was also observed that fracture in XLPE under a cyclic mechanical load is frequ…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTProtonation of the methyl orange derivative of aspartate adsorbed on colloidal silver: a surface-enhanced resonance Raman scattering and fluorescence emission studyOlavi Siiman and Adam LeppCite this: J. Phys. Chem. 1984, 88, 12, 2641–2650Publication Date (Print):June 1, 198…
Abstract An (S,S)-CHIRAPHOS-coordinated six-membered ring complex NiCH2CH2CH2COO undergoes facile ring contraction to give a mixture of ((S,S)-CHIRAPHOS)-(R)-NiCH(CH3)CH2COO (2a) and ((S,S)-CHIRAPHOS)-(S)-NiCH(CH3)CH2COO (2b). Complex 2a is kinetically favored, whereas 2b is thermodynamically favored; a thermodynamica…