Materials Literature
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JV-Acetyl-L-cysteine, C5H9N03S,Afr= 163-20,crystallizes in the space group PI, with a = 5-766 (1), b = 6-433 (1), c = 5-014(1) A, a= 102-80(2), /} = 102-77 (1), y = 95-81 (1), Z = 1 and final R^F 7 ) = 0-024 for a total of 1232 independent reflections, at T -16 K. The structure was first deduced from * Structure and C…
A theory of hydrogen absorption by metal hydrides is formulated in the mean-field approximation. The distinction between the true saturation and an incipient saturation is emphasized. It is shown that the incipient saturation is a manifestation of the effect of $d$-band structure upon the absorption of hydrogen. Absor…
As a model for a crystal with displacive modulation a classical linear chain is discussed with up to third-neighbor interaction. This system has an infinite number of stable equilibrium configurations separated by high barriers. It has a zero-frequency phonon mode, a low-lying phason branch, and an amplitude mode.
The valence- and core-electron spectra have been investigated for a series of ${\mathrm{Cu}}_{x}{\mathrm{Pd}}_{1\ensuremath{-}x}$ alloys by means of ESCA (electron spectroscopy for chemical analysis). In the dilute limits a subtraction method is applied to derive the contribution of the low-concentration components to…
The electrical-resistance behavior of Ca is studied from 2 to 300 K at various pressures up to 440 kbar using a clamp-type sintered diamond-tipped opposed-anvil apparatus. It is found that the electrical resistance of Ca at room temperature increases monotonically as a function of pressure and reaches a maximum at abo…
We report measurements of the electrical resistivity, Hall coefficient, magnetoresistance, thermoelectric power, infrared reflectivity, and $c$-axis lattice parameter of single crystals of titanium disulfide ${\mathrm{Ti}}_{1+x}{\mathrm{S}}_{2}$ with varying degrees of nonstoichiometry. The strong correlations we find…
Poly(p-phenylene) sulfide, poly(m-phenylene) sulfide, and the newly synthesized polymer poly(thio-2,8-dibenzothiophenediyl) have been treated with strong electron acceptors (AsF5, SbF5) to form conducting complexes with p-type electronic conductivities up to 3 S/cm. Near IR to UV absorption spectra and temperature-dep…
Equations are derived and calculations are presented for the electrodynamic mechanism of enhanced Raman scattering by molecules at the surface of prolate and oblate spheroids in the small-particle limit. The molecules may be arbitrarily distributed; the particles may be arbitrarily oriented. Calculations are presented…
Recent experiments involving the propagation of extremely high frequency, short-wavelength acoustic phonons in semiconductors are described. Such phonons, which play an important role in thermal energy transpor and nonradiative recombination processes, can be used as sensitive microscopic probes of electronic, defect,…
There are significant differences in the field dependence of conductivity in low-density polyethylene as reported by various investigators. These differences are attributable partly to the presence of different kinds of impurities in variable concentrations in polyethylene samples of various origin, but are mainly due…
When crystals of Cs 2 CdCl 4 (K 2 NiF 4 -type structure) are doped with Cr 3+ a number of different impurity centres are formed which are readily distinguishable by EPR spectroscopy. The doped crystals contain both compensated and uncompensated Cr 3+ centres. The resonances from the uncompensated Cr 3+ exhibit axial s…
Internal friction, ultrasonic attenuation, and electric modulus measurements on $\ensuremath{\beta}$- alumina, which are inconsistent with simple Debye theory, are found to be in good agreement with each other when analyzed with use of the "universal" dielectric response theory. It is suggested that this theory may be…
Polystyrene spheres (diameter approximately 3000 AA) trapped at the air-water interface and interacting via dipole-dipole repulsion have been seen to form a two-dimensional triangular lattice. The authors report the first molecular dynamics study of such an interfacial colloidal crystal. It is shown that the system un…
Polycrystalline calcite was revealed by scanning electron microscopy of fractured skeletal ossicles of the sea star Echinaster spinulosus (Echinodermata, Asteroidea). Whisker-like calcite crystals were observed in specimens that were loaded in stress relaxation before being fractured; rapidly broken surfaces were smoo…
Abstract A low temperature solution condensation method with pyridine as acceptor‐catalytic reagent was applied to the synthesis of polyarylates from carbazole and bisphenol A/phenolphthalein. The polyarylates were classified with respect to their structure, thermal stability, and dielectric behavior.
An electrolytic plutonium decontamination process for stainless steel was developed for use as the final step in a proposed radioactive waste handling and decontamination facility to be constructed at the Rockwell International Rocky Flats plutonium handling facility. The process utilizes a basic (pH > 7) electrolyte…
Inelastic scattering processes of electrons can be classified according to the amount of energy transferred during the scattering process. High-energy losses (E≳100eV) are coupled with the excitation of electrons out of inner shells of the atoms. The study of these energy losses are presently of great interest because…
Pure aluminum was irradiated at 120°C with 200 keV electrons in an electron microscope to examine the dependence of the growth rate of interstitial loop (I-loop) on the direction of incident electrons. I-loops grew proportionally with the irradiation time at 120°C. When the specimens were irradiated so that the I-loop…
The temperature dependence of the swelling and the creep compliance has been investigated for swollen isotropic cellulose hydrogels. The measurements were performed in a high precision type of dilatometer between 5 and 65°C. The thermal expansion of the gels in silicone oil (closed system) and the temperature dependen…
Two new homologous series of liquid crystals viz. p-(p'-n-alkoxycinnamoyloxy) benzylidene p”-anisidines (1) and p-(p'-n-alkoxycinnamoyloxy) benzylidene anilines (2) comprising twenty four mesogens have been synthesized. Both are high melting series of mesomorphs. In the homologous series (1) the nematic mesophase is e…