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A Systematic Application of the Potentiostatic Scratch Method in Order to Determine the Pitting Corrosion Resistance of Traditional and Advanced Stainless Alloys

D. Sinigaglia、B. Vicentini、G. Taccani 等 5 位作者1983-05-01Journal of The Electrochemical Society

The potentiostatic scratch method has been systematically applied to rank the pitting corrosion (PC) resistance of commercial and laboratory austenitic, superaustenitic, and extra low interstitial ferritic stainless steels in chloride solutions simulating the aggressivity of the human body and seawater. This technique…

Microstructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metalsNon-Destructive Testing Techniques

Role of higher triplet states in the anthracene-sensitized photoisomerization of stilbene and 2,4-hexadiene

Jack Saltiel、David E. Townsend、A. Sykes1983-05-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRole of higher triplet states in the anthracene-sensitized photoisomerization of stilbene and 2,4-hexadieneJack Saltiel, David E. Townsend, and Alan SykesCite this: J. Am. Chem. Soc. 1983, 105, 9, 2530–2538Publication Date (Print):May 1, 1983Publication History Published onl…

Photochemistry and Electron Transfer StudiesPhotochromic and Fluorescence ChemistryVarious Chemistry Research Topics

INFLUENCE OF RHEOLOGICAL PROPERTIES IN MASS TRANSFER PHENOMENA: SUPER CASE II SORPTION IN GLASSY POLYMERS

C. Gostoli、Giulio C. Sarti1983-05-01Chemical Engineering Communications

The sorption rate of swelling penetrants in glassy polymers has been considered as controlled both by the swelling kinetics and the penetrant diffusion through the swollen layer. The stress exerted on the glassy core at the moving boundary is the driving force for the swelling, and results from an osmotic stress and a…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesPolymer Foaming and Composites

Degradation of Sodium β″‐Alumina: Effect of Microstructure

Andrew C. Buechele、Lutgard C. De Jonghe、David C. Hitchcock1983-05-01Journal of The Electrochemical Society

The effect of microstructure on failure initiation of sodium beta″‐alumina solid electrolytes have been investigated by acoustic emission detection. Mode I failure initiation follows Weibull statistics with a modulus of about 2.5. The observed average critical current densities were 145 and 640 mA/cm −2 for large and…

Advanced ceramic materials synthesisThermal and Kinetic AnalysisThermal Expansion and Ionic Conductivity

A high‐resolution electron microscopic study of defects in sodium β′″‐alumina

R. Hull、David J. Smith、Colin Humphreys1983-05-01Journal of Microscopy

SUMMARY A high‐resolution electron‐microscopic study of sodium β′″‐alumina, a polytype of the more‐widely‐studied sodium β‐ and β″‐alumina, has been undertaken using the 600 kV instrument at Cambridge University. Images revealed the loss of sodium‐containing planes, which had caused crystals to collapse and shear into…

Advanced ceramic materials synthesisAnodic Oxide Films and NanostructuresThermal Expansion and Ionic Conductivity

Dielectricc Strength of Gas Mixtures Comprising SF6, CO, c-C4-F8 and SF6, N2, c-C4F8

Y. Qiu、E. Kuffel1983-05-01IEEE Transactions on Power Apparatus and Systems

In a previous paper[8] breakdown strengths of c-C4F8/SF6/CO gas mixtures in various proportions were reported for a 30mm rod-sphere gap under ac and impulse voltages. A mixture of 1% c-C4F8 + 59% SF6 + 40% CO exhibited higher dielectric strength than pure SF6 in the pressure range between 350 and 400 kPa. The present…

High voltage insulation and dielectric phenomenaInorganic Fluorides and Related CompoundsSpacecraft and Cryogenic Technologies

Perhydroazulenes. 4. 6-tert-Butyl-4-oxoperhydroazulene system

Herbert O. House、Peter C. Gaa、Joseph H. C. Lee 等 4 位作者1983-05-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPerhydroazulenes. 4. 6-tert-Butyl-4-oxoperhydroazulene systemHerbert O. House, Peter C. Gaa, Joseph H. C. Lee, and Don VanDerveerCite this: J. Org. Chem. 1983, 48, 10, 1670–1678Publication Date (Print):May 1, 1983Publication History Published online1 May 2002Published inissu…

Porphyrin and Phthalocyanine ChemistryInorganic and Organometallic ChemistryOrganic Chemistry Cycloaddition Reactions

Gamma Radiation Effects on the Strength of a Borosilicate Glass

Wieslaw A. Zdaniewski、T.E. Easler、R. C. Bradt1983-05-01Journal of the American Ceramic Society

The effects of 60 Co gamma radiation on the strength‐related mechanical properties of a borosilicate glass were examined. Although the glass darkened considerably, only a very slight densification was observed after irradiation to levels of 10 8 rads. The strength distributions were not appreciably changed by the irra…

Concrete and Cement Materials ResearchAdvanced ceramic materials synthesisGlass properties and applications

Magnetic and Electrical Properties of CrGe and Cr11Ge8

Tetsuya Sato、Makoto Sakata1983-05-01Journal of the Physical Society of Japan

The magnetic susceptibility χ and the electrical resistivity ρ of CrGe and Cr 11 Ge 8 are investigated at temperatures above 4.2 K. The magnetic susceptibility of CrGe exhibits a cusp at about 45 K and shows the T 2 dependence with positive coefficient at low temperatures. This behavior of CrGe, together with the beha…

Rare-earth and actinide compoundsIron-based superconductors researchHeusler alloys: electronic and magnetic properties

Thermal Conductivity of Silicate and Borate Glasses

M. M. Ammar、S. Gharib、M.M. Halawa 等 5 位作者1983-05-01Journal of the American Ceramic Society

Thermal conductivities of silicate and borate glasses were determined at 30°C by steady‐state methods. From the experimental data, factors representing the contribution of individual oxides (on a weight‐percent basis) were calculated by the least‐squares method. The experimental thermal conductivities and those calcul…

Glass properties and applicationsRecycling and utilization of industrial and municipal waste in materials production

Infrared absorption and resonance Raman scattering of photochromic triphenylformazans

James W. Lewis、C. Sándorfy1983-05-01Canadian Journal of Chemistry

The infrared and resonance Raman spectra of the two long-lived forms of triphenylformazan and several of its derivatives have been examined. The spectra of unsymmetrically 15 N-labelled derivatives suggest that two tautomers exist for each of the two forms. This observation is confirmed by the spectra of 1-(p-halophen…

Luminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistrybioluminescence and chemiluminescence research

Reflectance and thermoreflectance spectra and energy band structure of GeSe crystals

G. Valiukonis、F. M. Gashimzade、D. A. Guseinova 等 7 位作者1983-05-01physica status solidi (b)

Abstract The reflectance spectra of orthorhombic GeSe crystals are studied in the region 0.5 to 12 eV in polarized light with E ∥ a and E ∥ b at 290 K and a Kramers‐Kronig analysis is performed. The thermoreflectance spectra are investigated in the region 1 to 5 eV for E ∥ a and E ∥ b at 300 and 90 K. The energy band…

Nonlinear Optical Materials ResearchPhase-change materials and chalcogenidesOptical and Acousto-Optic Technologies

Intumescent flame retardants for polymers. I. The poly(acrylonitrile)–ammonium polyphosphate–hexabromocyclododecane system

Alberto Ballistreri、Giorgio Montaudo、Concetto Puglisi 等 5 位作者1983-05-01Journal of Applied Polymer Science

Abstract The influence of ammonium polyphosphate (APP) and hexabromocyclododecane (HBCD) as flame retardant (FR) on poly(acrylonitrile) (PAN) has been examined. The APP–HBCD system behaves as an intumescent flame retardant (IFR) formulation, APP being the char‐forming agent and HBCD the blowing agent. A negligible gas…

Flame retardant materials and propertiesThermal and Kinetic AnalysisSilicone and Siloxane Chemistry

Protein isolates from navy and pinto beans: their uses in macaroni products

Abdelmonem A. Seyam、O. J. Banasik、Merlin D. Breen1983-05-01Journal of Agricultural and Food Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTProtein isolates from navy and pinto beans: their uses in macaroni productsAbdelmonem A. Seyam, Orville J. Banasik, and Merlin D. BreenCite this: J. Agric. Food Chem. 1983, 31, 3, 499–502Publication Date (Print):May 1, 1983Publication History Published online1 May 2002Publis…

Collagen: Extraction and Characterization

Surface-Induced Helix-Unwinding Process in Thin Homogeneous Ferroelectric Smectic Cells of DOBAMBC

Katsumi Kondo、Hideo Takezoe、Atsuo Fukuda 等 6 位作者1983-05-01Japanese Journal of Applied Physics

Under conditions where molecules are forced parallel to the cell surfaces but do not orient themselves along a particular direction, we have observed the unwinding process. The cell thickness dependence of the transition temperature from Sm A to distorted Sm C * or Sm C, T c ( d ), has been obtained. The apparent tilt…

Liquid Crystal Research AdvancementsAdvanced Materials and MechanicsPlant Reproductive Biology

Electronic Properties of Vapor-Grown Heteroepitaxial ZnO Film on Sapphire

Masanobu Kasuga、Shinzi Ogawa1983-05-01Japanese Journal of Applied Physics

Hall coefficient and resistivity measurements have been made on single-crystal ZnO films prepared by chemical vapor deposition on sapphire substrates from 4.2 K to 300 K. Successive reduction of the film thickness from the surface and the rear (interface to substrate) revealed that there are two regions–a bulk region…

Physics of Superconductivity and MagnetismZnO doping and propertiesMagnetic Field Sensors Techniques

SCC of Zirconium and Its Alloys in Nitric Acid

Te‐Lin Yau1983-05-01CORROSION

Stress corrosion cracking (SCC) of zirconium Grades 702 (commercially pure zirconium), 704 (a Zr-1.5 Sn alloy), and 705 (a Zr-2.5 Nb alloy) in nitric acid has been studied by constant strain techniques, optical microscopy, scanning electron microscopy, and electrochemical techniques. Zirconium and its alloys, except w…

Hydrogen embrittlement and corrosion behaviors in metalsHigh Temperature Alloys and CreepNuclear Materials and Properties

Degree of mineralization: its significance for the stability and treatment of excavated ironwork

David Watkinson1983-05-01Studies in Conservation

The ratio weight:volume has been determined for ironwork from four archaeological sites. It is shown how this ratio can be used to determine the presence or absence of metallic iron in a corroded artifact. Experiments show that totally mineralized ironwork generally contains much less chloride than does ironwork retai…

Corrosion Behavior and InhibitionCultural Heritage Materials AnalysisMetallurgy and Cultural Artifacts

Dissolved Metal Species Mechanism for Initiation of Crevice Corrosion of Aluminum: I . Experimental Investigations in Chloride Solutions

Kurt R. Hebert、Richard C. Alkire1983-05-01Journal of The Electrochemical Society

Experiments on initiation of crevice corrosion were carried out on Al specimens in dilute aqueous solutions at ambient temperature. Transient current distributions within crevices were measured by a sectioned electrode technique, and microsampling was used to monitor dissolved aluminum, p H, and [Cl − ] composition ch…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityAnodic Oxide Films and Nanostructures

Proof of theT52term in the magnetization of Fe(BC) metallic glasses

A. K. Majumdar、V. Oestreich、D. Weschenfelder 等 4 位作者1983-05-01Physical review. B, Condensed matter

The magnetization of ${\mathrm{Fe}}_{80}{\mathrm{B}}_{20\ensuremath{-}x}{\mathrm{C}}_{x} (0\ensuremath{\le}x\ensuremath{\le}8)$ ferromagnetic metallic glasses has been measured in the temperature range $0<T\ensuremath{\lesssim}180$ K (corresponding to $0<\frac{T}{{T}_{C}}\ensuremath{\lesssim}0.3$) and in magneti…

Magnetic properties of thin filmsMetallic Glasses and Amorphous AlloysMagnetic Properties and Applications