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Novel peri-condensed Weitz-type donors: synthesis, physical properties, and crystal structures of 3,10-dithiaperylene (DTPR), 1,6-dithiapyrene (DTPY), and some of their CT complexes

Kazuhiro Nakasuji、Hirohisa. Kubota、Tomoyuki Kotani 等 10 位作者1986-06-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNovel peri-condensed Weitz-type donors: synthesis, physical properties, and crystal structures of 3,10-dithiaperylene (DTPR), 1,6-dithiapyrene (DTPY), and some of their CT complexesKazuhiro. Nakasuji, Hirohisa. Kubota, Tomoyuki. Kotani, Ichiro. Murata, Gunzi. Saito, Toshiaki…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesOrganic and Molecular Conductors Research

Isolation and Preliminary Taxonomic Studies of Thermus Strains Isolated from Yellowstone National Park, USA

Michael J. Munster、Ann P. Munster、John Woodrow 等 4 位作者1986-06-01Microbiology

Forty-eight strains of Thermus isolated from hot springs in Yellowstone National Park, Wyoming, USA, and eight reference strains were subjected to a numerical taxonomic analysis using Gower's coefficient (SG) with single and average linkage clustering. Two major groups were distinguished, which could be differentiated…

Genomics and Phylogenetic StudiesMicrobial Community Ecology and PhysiologyDiatoms and Algae Research

Behavior of Large Pores During Sintering and Hot Isostatic Pressing

A.G. Evans、Chun‐Hway Hsueh1986-06-01Journal of the American Ceramic Society

A viscoelastic model that describes the shrinkage rate of large pores within a fine‐grained body has been developed. The concept is based on a shrinkage potential derived from the surface and grain‐boundary tensions and viscous response determined by the creep characteristics of the polycrystal. Pore removal rates are…

Advanced ceramic materials synthesisAdvanced materials and compositesPowder Metallurgy Techniques and Materials

Deactivation of a vanadia-alumina catalyst for nitric oxide reduction by ammonia

In Sik Nam、J. W. Eldridge、J. R. Kittrell1986-06-01Industrial & Engineering Chemistry Product Research and Development

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDeactivation of a vanadia-alumina catalyst for nitric oxide reduction by ammoniaIn Sik Nam, John W. Eldridge, and J. R. KittrellCite this: Ind. Eng. Chem. Prod. Res. Dev. 1986, 25, 2, 192–197Publication Date (Print):June 1, 1986Publication History Published online1 May 2002P…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceAmmonia Synthesis and Nitrogen Reduction

Surface chemistry of MoO3γ‐Al2O3 catalysts studied by laser Raman spectroscopy: Hydration and dehydration reactions and generalization to other supported systems

E. Payen、S. Kasztelan、J. Grimblot 等 4 位作者1986-06-01Journal of Raman Spectroscopy

Abstract The Raman spectra of supported molybdena‐alumina catalysts are reversibly modified by changing the laser power falling on the sample, which was examined in air. O 2 calcination or evacuation at 500–700°C produces the same modification if in situ characterization is performed. Subsequent contact with the ambie…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

A quantitative electron microscopic study of the crystalline structure of ethylene copolymers

I. G. Voigt‐Martin、Rufina G. Alamo、L. Mandelkern1986-06-01Journal of Polymer Science Part B Polymer Physics

Abstract Quantitative thin‐section electron microscope studies were made on compositional fractions of ethylene copolymers crystallized under several extreme conditions. The co‐units chosen were such that the chains contained either ethyl, hexyl, or acetate side groups. Certain general features are independent of the…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesPolymer Nanocomposites and Properties

Thermodynamic Mixing Properties of Muscovite-Paragonite Crystalline Solutions at High Temperatures and Pressures, and their Geological Applications

Nilanjan Chatterjee、S. FLUX1986-06-01Journal of Petrology

Reversed Na-K exchange data between mica and a 2 molal aqueous (Na,K)Cl fluid (Flux & Chatterjee, 1986) have been employed to model the thermodynamic mixing behaviour of muscovite-paragonite crystalline solutions on the basis of the Redlich-Kister equation. For these binary micas, Gexm may be expressed as where A=1122…

Soil and Unsaturated FlowCO2 Sequestration and Geologic InteractionsClay minerals and soil interactions

Opposite regioselectivity in the epoxidation of geraniol and linalool with molybdenum and tungsten peroxo complexes

Antonio Arcoria、Francesco P. Ballistreri、Gaetano A. Tomaselli 等 5 位作者1986-06-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOpposite regioselectivity in the epoxidation of geraniol and linalool with molybdenum and tungsten peroxo complexesAntonio Arcoria, Francesco Paolo Ballistreri, Gaetano Andrea Tomaselli, Fulvio Di Furia, and Giorgio ModenaCite this: J. Org. Chem. 1986, 51, 12, 2374–2376Publi…

Polyoxometalates: Synthesis and ApplicationsInorganic and Organometallic ChemistryCatalysis and Oxidation Reactions

Reduction of nitric oxide with ammonia on alumina- and titania-supported metal oxide catalysts

Wing C. Wong、Ken Nobe1986-06-01Industrial & Engineering Chemistry Product Research and Development

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReduction of nitric oxide with ammonia on alumina- and titania-supported metal oxide catalystsWing C. Wong and Ken NobeCite this: Ind. Eng. Chem. Prod. Res. Dev. 1986, 25, 2, 179–186Publication Date (Print):June 1, 1986Publication History Published online1 May 2002Published…

Catalytic Processes in Materials ScienceAmmonia Synthesis and Nitrogen ReductionNanomaterials for catalytic reactions

Poly(vinyl ether)s and poly(propenyl ether)s containing mesogenic groups: A new class of side‐chain liquid‐crystalline polymers

José M. Rodriguez‐Parada、Virgil Percec1986-06-01Journal of Polymer Science Part A Polymer Chemistry

Abstract A new series of thermotropic liquid‐crystalline polymers, poly(vinyl ether)s and poly(propenyl ether)s, containing the mesogen 4‐methoxy‐4′‐hydroxybiphenyl in the side chain and different spacers between the mesogens and the backbone were synthesized and characterized by DSC and optical microscopy. Their meso…

Liquid Crystal Research AdvancementsPolymer Nanocomposites and PropertiesAdvanced Materials and Mechanics

Free radical polymerization models for simulating reactive processing

James K. Stevenson1986-06-01Polymer Engineering and Science

Abstract The generally accepted kinetic mechanism for free radical copolymerization was simplified by various assumptions and restrictions to give several realistic and easily evaluated models for the simulation of industrial molding. Six assumptions, including conversion‐dependent rate coefficients and constant comon…

Epoxy Resin Curing ProcessesInjection Molding Process and PropertiesThermal and Kinetic Analysis

Flexural Waves in Beam of Elastic Nonlocal Material

Jerzy Nowiński1986-06-01Journal of Engineering Mechanics

The elastic nonlocal moduli are first determined from an auxiliary problem involving longitudinal waves in an infinite nonlocal medium. A comparison of the dispersion equation obtained with that derived in the lattice dynamics of Born and von Kármán is made. Constitutive equations of Kroener and Eringen are introduced…

Numerical methods in engineeringThermoelastic and Magnetoelastic PhenomenaNonlocal and gradient elasticity in micro/nano structures

Open-Circuit TSD Method and Anomalous Air Gap Current in Teflon® FEP

J.A. Giacometti、José Antônio Malmonge、João Mariz Guimarães Neto1986-06-01IEEE Transactions on Electrical Insulation

The paper shows an extension of the technique of open-circuit thermally stimulated discharge (TSD), consisting of simultaneously measuring the current and its charge on the external circuit as a function of temperature. The current is measured with a strongly damped meter which fails to give a time-resolved record of…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationElectrostatic Discharge in Electronics

Herstellung, struktur und mechanische eigenschaften von strahlenchemisch mit styrol gepfropftem polyethylen

K. Friese、Goerg H. Michler、Helga Steinbach 等 5 位作者1986-06-01Die Angewandte Makromolekulare Chemie

Abstract Von strahlenchemisch durch Gasphasen‐Pfropfung hergestellten Pfropfprodukten aus Polyethylen und Styrol wurden die Anteile an Homopolymerem und gepfropftem Styrol, die Struktur der Pfropfprodukte (an Hand von elektronenmikroskopischen Aufnahmen) sowie einige mechanische Eigenschaften in Abhängigkeit von der P…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesFiber-reinforced polymer composites

Effects of inorganic speciation on the interpretation of copper adsorption by soils

G. S. P. Ritchie、S. C. Jarvis1986-06-01Journal of Soil Science

SUMMARY A previous study with a range of soils indicated that adsorption of copper could not be adequately described by the Freundlich equation. Adsorption curves for all but a highly calcareous soil could be divided into two straight lines with a marked increase in slope at low solution concentrations. A computer pro…

Heavy metals in environmentClay minerals and soil interactionsMine drainage and remediation techniques

Silicone fluids: Synthesis, properties and applications

Philipp Huber、Wolf-Dieter Kaiser1986-06-01Journal of Synthetic Lubrication

Abstract This paper describes the structure and derivation of ‘classical’ silicone fluids, giving the reactions for the production of dimethyl fluids by Miiller‐Rochow synthesis, polymerisation, direct synthesis, hydrosilylation, and transesterification. The properties of siloxanes are described, and the applications…

Mesoporous Materials and CatalysisSilicone and Siloxane Chemistry

Failure mechanisms for organic coatings subjected to 0.1M sulfuric acid

Malcolm L. White、Hyacinth Vedage、Richard D. Granata 等 4 位作者1986-06-01Industrial & Engineering Chemistry Product Research and Development

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFailure mechanisms for organic coatings subjected to 0.1M sulfuric acidMalcolm L. White, Hyacinth Vedage, Richard D. Granata, and Henry Leidheiser Jr.Cite this: Ind. Eng. Chem. Prod. Res. Dev. 1986, 25, 2, 129–132Publication Date (Print):June 1, 1986Publication History Publi…

Corrosion Behavior and InhibitionFuel Cells and Related MaterialsConcrete Corrosion and Durability

Carbonization in a tube bomb. 1. Carbonization of petroleum residue into a lump of needle coke

Isao Mochida、Yozo Korai、Yasuhiro Nesumi 等 4 位作者1986-06-01Industrial & Engineering Chemistry Product Research and Development

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCarbonization in a tube bomb. 1. Carbonization of petroleum residue into a lump of needle cokeIsao Mochida, Yozo Korai, Yasuhiro Nesumi, and Takashi OyamaCite this: Ind. Eng. Chem. Prod. Res. Dev. 1986, 25, 2, 198–201Publication Date (Print):June 1, 1986Publication History P…

Energetic Materials and CombustionThermal and Kinetic AnalysisGraphite, nuclear technology, radiation studies

ETHYLENE OXIDATION ON SILVER CATALYSTS: EFFECT OF ETHYLENE OXIDE AND OF EXTERNAL TRANSFER LIMITATIONS

M. Stoukides、Stavros Pavlou1986-06-01Chemical Engineering Communications

Ethylene oxidation to ethylene oxide and to carbon dioxide over silver catalysts was studied in a CSTR. The effects of two factors on the catalyst performance were examined. The first was the presence of excess ethylene oxide in the feed. A kinetic model was introduced which assumed that ethylene and ethylene oxide co…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

The electron-energy-loss spectrum of lithium metal

Dang-Rong Lru、David B. Williams1986-06-01Philosophical Magazine B

Electron-energy-loss spectra of pure Li metal from 0 to ∼ 75 eV have been obtained for the first time in an analytical electron microscope. The spectrum is compared with density-of-states calculations and results from other spectroscopic techniques as well as with energy-loss spectra of slightly oxidized Li.

Advancements in Battery MaterialsX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques