Materials Literature
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A model for the doped rare-earth manganites such as ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Sr}}_{x}{\mathrm{MnO}}_{3}$ incorporating the physics of dynamic Jahn-Teller and double-exchange effects is presented and solved via a dynamical mean field approximation. The interplay of these two effects as the electron pho…
Polycrystalline bulk samples of Ti 3 SiC 2 were fabricated by reactively hot‐pressing Ti, graphite, and SiC powders at 40 MPa and 1600°C for 4 h. This compound has remarkable properties. Its compressive strength, measured at room temperature, was 600 MPa, and dropped to 260 MPa at 1300°C in air. Although the room‐temp…
Se analiza la influencia de los tratamientos termomecánicos, en primer lugar, llevados a cabo en laboratorio y, posteriormente, en un proceso industrial, sobre las propiedades mecánicas de aceros microaleados de forja. Se han variado las temperaturas de forja y las velocidades de enfriamiento tras la misma y se ha est…
Department of Chemistry, University of Rajasthan, Jaipur-302 004 <em>Manuscript received 19 November 1993, revised 21 October 1994, accepted 4 November 1994</em> Spectroscopic, Antifungal and Antibacterial Studies of some Manganese Heterochelates.
Experimental and theoretical work on the magnetoacoustics of rare-earth orthoferrites near reorientation phase transitions (RPTs) is reviewed. The temperature and field dependence of magnetoresonant soft-mode frequencies and of the sound velocity and attenuation near various RPTs, as obtained by RF and ultrasonic spec…
Measurements on the anomalous temperature behaviour of the spontaneous magnetisation in various ferrimagnets (N-, M-, and P-type Neel curves) are analysed and summarised. The concept of a 'weak' magnetic sublattice is applied to explain the anomalies as well as manifestations of the 'low-temperature point' TB and the…
We describe a recently discovered stable planar surface of silicon, Si(114). This high-index surface, oriented 19.5 degrees away from (001) toward (111), undergoes a 2x1 reconstruction. We propose a complete model for the reconstructed surface based on scanning tunneling microscopy images and first-principles total-en…
Semiconductor heterostructures with prescribed energy dependence of the transmittance can be designed by combining: {\em a)} Padé approximant reconstruction of the S-matrix; {\em b)} inverse scattering theory for Schrodinger's equation; {\em c)} a unitary transformation which takes into account the variable mass effec…
The shapes and sizes of platinum nanoparticles were controlled by changes in the ratio of the concentration of the capping polymer material to the concentration of the platinum cations used in the reductive synthesis of colloidal particles in solution at room temperature. Tetrahedral, cubic, irregular-prismatic, icosa…
VIII. Applications and Illustrations 490 A. ADSA-P 490 B. ADSA-D 502 References 505 I. INTRODUCTION Numerous methodologies have been developed for the measurement of contact angles and surface tensions as outlined in Chapter 8 and Refs. 1-4. Liquid surface tension measurements commonly involve the determination of the…
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The effect of ozone gas treatment on the adhesion between low-density polyethylene (LDPE) and cellulose was investigated. The ozone treatment of LDPE resulted in a significant increase in the interfacial shear strength as measured by the single fiber fragmentation test, whereas the ozone treatment of cellulose was not…
The effects of temperatures, styrene concentration, and molecular composition of unsat-urated polyester (UP) prepolymers on the viscosity of UP-styrene systems are studied. The viscosity of UP resins follows the Arrhenius-type expression with resin temperature as well as with the styrene molar fraction of the resin. T…
Sorption of distilled water in a cellulose-based hydrogel is presented. The examined system is based on a mixture of sodium salt of carboxymethylcellulose and hydroxyethylcellulose, crosslinked with divinilsulphone. The effect of chemical composition, manufacturing procedures, as well as desiccation protocols on equil…
Effects of the mixing ratio of poly(DL-lactide) (PDLLA) and poly (ε-caprolactone) (PCL) on the thermal and mechanical properties and morphologies of the solution-cast blends were investigated by differential scanning calorimetry (DSC), polarizing microscopy, tensile tests, and dynamic mechanical analysis. The presence…
A large family of isoquinoline sulfonamide compounds inhibits protein kinases by competing with adenosine triphosphates(ATP), yet interferes little with the activity of other ATP-using enzymes such as ATPases and adenylate cyclases. One such compound, N-(2-aminoethyl)-5-chloroisoquinoline-8-sulfonamide (CK17), is sele…
The phonon dispersion and the electron-phonon interaction for the $β$-Po and the bcc high pressure phases of tellurium are computed with density-functional perturbation theory. Our calculations reproduce and explain the experimentally observed pressure dependence of the superconducting critical temperature (T$_{\rm c}…
Gadolinium(III) texaphyrin (Gd-tex2+) is representative of a new class of radiation sensitizers detectable by magnetic resonance imaging (MRI). This porphyrin-like complex has a high electron affinity [E1/2 (red.) approximately = -0.08 V versus normal hydrogen electrode] and forms a long-lived pi-radical cation upon e…
The rate of the latent heat transfer at first-order phase transitions is calculated. A dynamic criterion to determine the dominating process in kinetics of phase transitions is obtained. It is shown that in ferroelectric perovskites of the -type the relaxation of the order parameter governs the phase transition kineti…
Thin films of MnTe having zinc-blende structure were grown on BaF2(111) substrates under various growth conditions by molecular beam epitaxy. The structural properties of the deposited films were characterized by x-ray diffraction which evidenced sometimes the presence of other crystallographic phases apart from a dom…