S. Martin Nelson、C. Victor Knox1983-01-01Journal of the Chemical Society Dalton Transactions
The syntheses, via metal-ion (Mg2+, Ca2+, or Ba2+) template methods followed by transmetallation, of the complexes [ML1]X2(M = MnII, FeII, CoII, NiII, CuII, or ZnII; X = ClO4– or BPh4–) of the potentially septidentate ligand L1 formed by condensation of 1 mol of 2,6-diacetylpyridine with 2 mol of 3-oxapentane-1,5-diam…
Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes
B. Guillaume、R. L. Hahn、A. H. Narten1983-01-01Inorganic Chemistry
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInvestigations of "cation-cation" complexes of neptunyl ion (NpO2+) solutions by large-angle x-ray scatteringB. Guillaume, R. L. Hahn, and A. H. NartenCite this: Inorg. Chem. 1983, 22, 1, 109–111Publication Date (Print):January 1, 1983Publication History Published online1 Ma…
Analytical Chemistry and ChromatographyRadioactive element chemistry and processingLanthanide and Transition Metal Complexes
J. A. McKeague、Douglas Grant、H. Kodama 等 5 位作者1983-01-01Canadian Journal of Earth Sciences
Brownish yellow saprolite derived from granite gneiss is exposed beneath 1–2 m of reddish brown till along a roadcut in the Cape Breton Highlands. The strongly acid soil is similar to other Podzolic soils of the region except for the presence of gibbsite in the silt and clay fractions. In the saprolite, feldspar and b…
Geology and Paleoclimatology ResearchClay minerals and soil interactionsTherapeutic Uses of Natural Elements
Hiroshi Nagai、Takeshi Fujikawa、Keiichirô Shôji1983-01-01Transactions of the Japan Institute of Metals
In order to obtain a better fundamental understanding of factors responsible for an excellent improving effect of rare earths addition on the high temperature oxidation resistance of Ni–Cr alloys, the electrical conductivities of sintered Cr2O3 doped with various amounts of La2O3, Y2O3 and NiO were measured in the tem…
Advancements in Solid Oxide Fuel CellsTransition Metal Oxide NanomaterialsThermal Expansion and Ionic Conductivity
Suresh C. Tyagi、Brian J. Hathaway1983-01-01Journal of the Chemical Society Dalton Transactions
The crystal structure of the title compound [Cu(bipy)2(CN)][NO3]·2H2O has been determined by X-ray analysis. It crystallises in the monoclinic space group, P21/n with a= 9.263(3), b= 24.678(4), c= 10.123(3)Å, β= 109.83(8)°, and Z= 4. The five-co-ordinate CuN2N2C chromophore has a distorted trigonal-bipyramidal stereoc…
Metal complexes synthesis and propertiesCrystal structures of chemical compoundsMagnetism in coordination complexes
C. Chen、James L. White、Joseph E. Spruiell 等 4 位作者1983-01-01Textile Research Journal
A laboratory apparatus for investigating the spunbonding process is described. Filaments emerging from a spinneret are drawn by high velocity air moving through an aspirator. The dynamics of the process are specified and the air drag is experi mentally determined. Friction factor/Reynolds number relationships are deve…
Mechanical Behavior of CompositesTextile materials and evaluationsMaterial Properties and Processing
Leonhard Walz、H. Paulus、W. Haase 等 5 位作者1983-01-01Journal of the Chemical Society Dalton Transactions
The crystal and the molecular structure of the title compound has been determined using three-dimensional X-ray diffractometer data involving 7 045 independent reflections. The compound crystallizes in the monoclinic space group I2/c with eight formula units [(CuL2)4]·9CH3OH in a unit cell with dimensions a= 27.062(5)…
Metal complexes synthesis and propertiesCrystal structures of chemical compoundsMagnetism in coordination complexes
Tetsuo Asaji、Hideki Sakai、Daiyû Nakamura1983-01-01Inorganic Chemistry
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMagnetic phase transitions in dibromo(4H-1,2,4-triazole)copper(II) and related copper(II) complexes as studied by nitrogen-14 nuclear quadrupole resonance and magnetic susceptibility measurementsTetsuo Asaji, Hideki Sakai, and Daiyu NakamuraCite this: Inorg. Chem. 1983, 22,…
Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes
Lydie Valade、Mich�le Bousseau、Alain Gleizes 等 4 位作者1983-01-01Journal of the Chemical Society Chemical Communications
The highly conducting electrocrystallized mixed valence [Ni(dmit)2](NBu4)0.29 complex (H2dmit = 4,5-dimercapto-1,3-dithiole-2-thione) shows an unususl two-dimensional structure as shown by X-ray diffraction methods and anisotropic conductivity measurements.
Metal-Organic Frameworks: Synthesis and ApplicationsCrystallography and molecular interactionsOrganic and Molecular Conductors Research
Shigeyoshi Sakaki、Kazuo Kitaura、Keiji Morokuma 等 4 位作者1983-01-01Inorganic Chemistry
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAb initio MO study of nickel(0) complexes: stereochemistry of Ni(PH3)2L (L = H2CO or (CO)2) and comparison of coordinate bonds of various ligandsShigeyoshi Sakaki, Kazuo Kitaura, Keiji Morokuma, and Katsutoshi OhkuboCite this: Inorg. Chem. 1983, 22, 1, 104–108Publication Dat…
Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes
K. Hiraga、Tokujiro Yamamoto、Makoto Hirabayashi1983-01-01Transactions of the Japan Institute of Metals
The tetrahedrally close-packed structure of the μ-phase of Co7Mo6 has been investigated by the many-beam imaging with [110] axial illumination. Twinnings, stacking faults and other structure defects have been revealed in terms of characteristic coordination polyhedrons with the aid of multislice computations. Occurren…
Advanced Chemical Physics StudiesRare-earth and actinide compoundsX-ray Diffraction in Crystallography
I. Odler、S. Abdul-Maula1983-01-01Journal of the American Ceramic Society
Up to 4.7% ZnO can be incorporated into the crystalline lattice of C 3 S. Five allotropic forms (i.e. T I , T II , M I , M II , and R) can be stabilized at room temperature, depending on the amount of ZnO. When heated to high temperature, the C 3 S‐ZnO solid solution decomposes and ZnO escapes from the crystalline lat…
Advanced ceramic materials synthesisCalcium Carbonate Crystallization and InhibitionLayered Double Hydroxides Synthesis and Applications
Eberhard W. Neuse、Mohamed S. Loonat1983-01-01Macromolecules
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTwo-stage polybenzimidazole synthesis via poly(azomethine) intermediatesEberhard W. Neuse and Mohamed S. LoonatCite this: Macromolecules 1983, 16, 1, 128–136Publication Date (Print):January 1, 1983Publication History Published online1 May 2002Published inissue 1 January 1983…
Synthesis and properties of polymersMicrowave-Assisted Synthesis and ApplicationsSynthesis of Tetrazole Derivatives
Bruce W. Dockum、Glenn A. Eisman、Edward Witten 等 4 位作者1983-01-01Inorganic Chemistry
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThiocyanate-bridged transition-metal polymers. 4. A study of the structural, electronic, and magnetic properties of some mono(2,2'-bipyridyl) transition-metal thiocyanates: zigzag polymeric chains based on Mn(bpy)(NCS)2 and Co(bpy)(NCS)2Bruce W. Dockum, Glenn A. Eisman, E. H…
Metal complexes synthesis and propertiesMagnetism in coordination complexesSynthesis and Characterization of Heterocyclic Compounds
Rudolf Klein、W. Heß1983-01-01Faraday Discussions of the Chemical Society
Using the Fokker–Planck equation as the basic description, various collective and single-particle properties of highly charged spherical macroparticles in solution are derived. The dynamic structure factor S(k,t) for finite k is found to be non-exponential in t due to the viscoelastic properties of the liquid of inter…
Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesElectrostatics and Colloid Interactions
Hiroshi Uetsuka、Teruo FURUTA、Satoru Kawasaki1983-01-01Journal of Nuclear Science and Technology
With a view to examining the failure-bearing capability of Zircaloy-4 cladding under postulated Loss-of-Coolant Accident condition in LWRs, integral tests of rod-burst, oxidation and thermal-shock were performed using simulated fuel containing A1203 pellets sheathed in Zircaloy-4 specimen cladding, filled with He gas,…
Nuclear reactor physics and engineeringNuclear Materials and PropertiesNuclear Engineering Thermal-Hydraulics
Shinzo Ashida、Takayuki Shimazaki、Kazuyoshi Kitano 等 4 位作者1983-01-01Agricultural and Biological Chemistry
Killer yeast strains of Saccharomyces cerevisiae were firstly described by Bevan and Makower1} in 1963. Killer yeasts of the Saccharomyces and of other genera secrete
Catalytic Processes in Materials Science
G. Wendt、Dietmar Hentschel、J. Finster 等 6 位作者1983-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases
NiO/Al2O3–SiO2 catalysts containing 5 mol% NiO and various amounts of alumina have been prepared by precipitation. Nitrogen adsorption–desorption isotherms on both the calcined samples and the corresponding Al2O3–SiO2 precursors have been measured. Surface areas SB.E.T. and St have been calculated and the pore structu…
Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions
Ingemar Lundström1983-01-01Physica Scripta
Connections between surface physics and biology are discussed. Special attention is paid to protein adsorption on solid surfaces, with relevance to biocompatibility and surface oriented diagnostic methods. Simple models for denaturation of proteins and interaction between antigens and antibodies on surfaces are develo…
Advanced biosensing and bioanalysis techniquesPolymer Surface Interaction StudiesAdvanced Biosensing Techniques and Applications
John Lewis Weaver、Jack Winnick1983-01-01Journal of The Electrochemical Society
Representative cathode half‐cell polarization data at low inlet cathode concentrations are presented for the MCCDC operated in the fuel‐cell mode. A mathematical model is used to correlate the cathode data and to explain the observed behavior, especially at high utilization. Also presented are representative cathode r…
Advancements in Solid Oxide Fuel CellsMolten salt chemistry and electrochemical processesElectronic and Structural Properties of Oxides