Materials Literature
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An application of a magnetostatic 3-D nonlinear finite-element code to the computation of the axial forces on the windings of a large-power autotransformer due to short-circuit currents is described. The analyzed five-limb core autotransformer has an internal tertiary delta-connected winding. A comparison between the…
Abstract There are relatively few well‐documented reports about the mineralogy of Aridisols. A Durorthid and two Haplargids were sampled in the Mojave Desert, California. The soils formed in alluvial deposits estimated to be >300 000, 200 000, and 100 000 yr old, respectively, and were examined for factors influenc…
Abstract The network structure of TBSI-accelerated vulcanization of cis -polyisoprene was studied using C-13 solid-state NMR. The initial crosslink products consisted of A1c ( cis ) and A2c ( cis ) polysulfides. As the percent cure is increased, the A1c and A2c structures reduce in rank to monosulfides, and polysulfid…
For those PTCR materials with higher Pb content, the thermodynamic derivation of increasing values for “inversion temperature” and cation vacancy diffusion rate accounts for the increases in the calculated acceptor‐state densities N s (cm −2 ). The influence of frequency‐dependent properties for the dielectric constan…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHigh-pressure studies of photoluminescence properties of ruthenium(II) polypyridyl complexesJ. M. Lang, Z. A. Dreger, and H. G. DrickamerCite this: J. Phys. Chem. 1993, 97, 10, 2289–2294Publication Date (Print):March 1, 1993Publication History Published online1 May 2002Publi…
Abstract The capture of HCl from cumyl chloride, a model compound for degrading PVC, by epoxidized soybean oil, yielding the related chlorohydrin, is relatively inefficient. The reaction is much accelerated by the presence of metal salts that are primary stabilizers, in particular by zinc carboxylates. In such instanc…
Abstract This work deals with the conductivity of polymer/filler‐mixtures, with the conductive filler particles of colloid size. For the interpretation of the conductivity course in such systems Wessling recently proposed a new thermodynamical percolation model, the so‐called “dynamic boundary model.” A consequence of…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElasticity of nematic networks and nematic effects in conventional rubbersP. Bladon and M. WarnerCite this: Macromolecules 1993, 26, 5, 1078–1085Publication Date (Print):March 1, 1993Publication History Published online1 May 2002Published inissue 1 March 1993https://doi.org/…
A systematic reexamination of the Er - Co system was carried out by differential thermal analysis, optical microscopy, X-ray diffraction and EPMA techniques. A revised Er - Co binary phase diagram is proposed. This binary system consists of four peritectic reactions, three reactions of congruent melting and a eutectoi…
Differential scanning calorimetry (DSC) has been employed to characterize the thermal denaturation of CPL1 lysozyme and its isolated fragments in the absence and presence of choline. The heat capacity function of CPL1 lysozyme shows two peaks with Tm values of 43.5 and 51.4 degrees C. At saturating concentrations of c…
The formalism of the Ammann bar grid with two spacings is systematically analyzed. Simple two-by-two matrices describe the self-similar deflation. The deflation and the inflation factors are the two eigenvalues of the matrix. The ratio of the two spacings is derived as another characteristic quantity of the matrices.…
A systematic evaluation of the electrochemical oxidation of porous graphite powder electrodes in , , and propylene carbonate (PC) electrolytes containing or is described. The graphite compounds obtained are characterized by x‐ray powder diffraction while in the electrolyte solution and following evacuation. The potent…
Abstract The effect of the composition of various wood fibers and surface‐treated mica as well as different surface treatments of cellulosic materials on the mechanical properties of PVC composites has been evaluated. Cellulosics were surface modified by prior coating with maleic andydride (MA), mixtures of MA and Na‐…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOn the structure and mechanism of formation of the Lansbury reagent, lithium tetrakis(N-dihydropyridyl)aluminateDennis D. Tanner and Chi Ming YangCite this: J. Org. Chem. 1993, 58, 7, 1840–1846Publication Date (Print):March 1, 1993Publication History Published online1 May 20…
The small magnitude of (${\mathit{T}}_{\mathit{c}}$-${\mathit{T}}^{\mathrm{*}}$)/${\mathit{T}}_{\mathit{c}}$, where ${\mathit{T}}_{\mathit{c}}$ is the nematic-isotropic phase transition temperature and ${\mathit{T}}^{\mathrm{*}}$ denotes the virtual transition temperature, has been a long-standing puzzle in the physic…
Clays, acid‐activated to an optimum level, have been pillared with alumina to give semi‐crystalline expanded materials with surface acidities, pore volumes and average pore diameters generally higher than those of the corresponding pillared materials derived from a clay matrix not previously acid‐activated. The chloro…
Low-humidity monoclinic lysozyme, resulting from a water-mediated transformation, has one of the lowest solvent contents (22% by volume) observed in a protein crystal. Its structure has been solved by the molecular replacement method and refined to an R value of 0.175 for 7684 observed reflections in the 10-1.75 A res…
The sdaB gene which codes for the second L-serine deaminase (L-SD) of Escherichia coli K-12 has been sequenced and shown to be very similar to the sdaA gene which codes for the first L-serine deaminase. sdaB is transcribed in rich medium, particularly in the absence of glucose, and is under the control of catabolite a…
Previous studies on the surface properties of Dicor castable glass-ceramic have shown the formation of a specific crystalline phase at the glass-ceramic/embedment interface. If this phase is not removed by grinding, it leads to an undesirable strength decrease. The aims of this study were: (1) to determine the nature…
An immersion grating with high refractive index n increases spectral resolution n-fold over that of a surface reflection grating of equal length.