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Molecular Orbital Calculations on Porphine and Tetrahydroporphine

H. C. Longuet–Higgins、C. W. Rector、John R. Platt1950-09-01The Journal of Chemical Physics

The first three electronic transitions of porphine and the first five electronic transitions of tetrahydroporphine are predicted as simple one-electron LCAO molecular orbital transitions (with overlap included). The electron densities and bond orders in the ground states are also computed. The observed levels are tent…

Oxidative Organic Chemistry ReactionsPorphyrin and Phthalocyanine ChemistryFluorine in Organic Chemistry

Gallium and Germanium Substitutions in Synthetic Feldspars

Julian R. Goldsmith1950-09-01The Journal of Geology

Compounds of gallium and germanium isostructural with the feldspars have been prepared, and some of their crystal-chemical properties are here described. In the Na and K feldspars, $$Al^{+++}$$ and $$Si^{++++}$$ can be completely replaced by $$Ga^{+++}$$ and $$Ge^{++++}$$; but, in pure Ca feldspar, complete substituti…

Iron oxide chemistry and applicationsSilicon Effects in AgricultureClay minerals and soil interactions

Temperature Dependence of the Emission of an Improved Manganese-Activated Magnesium Germanate Phosphor

Luke Thorington1950-09-01Journal of the Optical Society of America

A number of recent researches have been concerned with magnesium germanate phosphors. An improved such phosphor is reported here having over twice the brightness of the previous compositions as prepared in this laboratory, and which shows peak luminescence efficiency at temperatures near 350°C. Temperature dependence…

Luminescence Properties of Advanced MaterialsSolid-state spectroscopy and crystallographyRadiation Detection and Scintillator Technologies

Phase Relationships in the System Zirconia—Ceria

Pol Duwez、Francis Odell1950-09-01Journal of the American Ceramic Society

The phase relationships in the system zirconia‐ceria were investigated by X‐ray diffraction and dilatometric methods. The specimens were prepared by mixing and compacting the oxide powders and firing at 2000°C. At 2000°C. zirconia and ceria are miscible in each other from about 24 to 100 mole % ceria. The range of sol…

Thermal and Kinetic AnalysisCrystallization and Solubility StudiesCatalytic Processes in Materials Science