Materials Literature
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A study was made to determine whether a magnetic field, such as that associated with a thermonuclear reactor, might adversely affect the corrosion behavior of metallic surfaces in contact with a flowing electrolyte. In metal/ flowing‐electrolyte systems, electrochemical reactions dependent on the metal/ electrolyte in…
Abstract Chemical and physical properties of the clay mineral nontronite were studied as the oxidation state of structural iron was altered. Magnesium exchange capacities (CEC) were determined for different nontronite samples that were unaltered, dithionite‐reduced, and reduced‐reoxidized, and were compared to predict…
The L-(+)-lactate dehydrogenase (L-lactate:NAD+ oxidoreductase, EC 1.1.1.27) of Streptococcus lactis C10, like that of other streptococci, was activated by fructose 1,6-diphosphate (FDP). The enzyme showed some activity in the absence of FDP, with a pH optimum of 8.2; FDP decreased the Km for both pyruvate and reduced…
Specific-heat data (at zero field and 15.6 kV/cm), dielectric data, and electrocaloric data measured on a KTa${\mathrm{O}}_{3}$ crystal between 2 and 25 K are reported. The zero-field specific heat is about 30 times larger than the Debye prediction (${\ensuremath{\Theta}}_{D}=580$ K) at these temperatures but shows no…
The effect of pH changes and the presence of ligands on the uptake of lead and cadmium ions by three types of clay mineral (kaolinite, illite and montmorillonite) has been investigated.     In the absence of ligands, metal ion adsorption increases gradually with increasing pH until a thresho…
The melting, eutectic, peritectic, solidus, and liquidus temperatures in the system Zr‐O have been measured directly by a simple optical pyrometric technique requiring only a few hundred milligrams of sample. The saturation solubility of oxygen in α‐Zr( s ) between 1270° and 1980°C and the lower phase boundary of the…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEquilibrium Cyclic Oligomer Formation in the Anionic Polymerization of iε-CaprolactoneKoichi Ito, Yutaka Hashizuka, and Yuya YamashitaCite this: Macromolecules 1977, 10, 4, 821–824Publication Date (Print):July 1, 1977Publication History Published online1 May 2002Published in…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis of Poly[(amino acid alkyl ester)phosphazenes]H. R. Allcock, T. J. Fuller, D. P. Mack, K. Matsumura, and Karen M. SmeltzCite this: Macromolecules 1977, 10, 4, 824–830Publication Date (Print):July 1, 1977Publication History Published online1 May 2002Published inissue…
For pt.I see ibid., vol.6, p.180 (1976). The resonant model potential theory of a d band metal discussed by the author previously is used to calculate the total energy and its structural dependence. Only completely full or empty d band metals are considered; for these metals, the Harrison Gamma / mod E d -E F mod expa…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTX-ray photoelectron/Auger electron spectroscopic studies of tin and indium metal foils and oxidesAlbert W. C. Lin, Neal R. Armstrong, and Theodore. KuwanaCite this: Anal. Chem. 1977, 49, 8, 1228–1235Publication Date (Print):July 1, 1977Publication History Published online1 M…
Statistical variation of pitting potential and induction time for pit generation has been studied based on a stochastic theory which had been developed for the fracture of solid materials caused by applied stress. In order to obtain a large number of data, a multichannel pitting corrosion testing apparatus was develop…
Nonradiative decay of excited rare-earth ions by multiphonon emission has been investigated in a series of oxide glasses. Various rare-earth electronic levels were selectively excited by short-duration laser pulses and multiphonon relaxation rates were determined from measurements of fluorescence rise and decay times.…
This article reviews the fundamental experimental and theoretical results on the nature of radiation defects and the mechanism of their production in ionic (mainly alkali-halide) crystals. We show that one can produce high concentrations of radiation defects in these crystals by irradiating with photons and particles…
American Institute of Mining, Metallurgical, and Petroleum Engineers, Inc. Abstract Corrosion data were obtained in a well in the Salton Sea Geothermal Field. These data were obtained from inspection of steel tubing removed from the 4200-foot well and from specimens of various alloys exposed at the bottom of the well.…
A method was developed for predicting oxidation distribution through the thickness of reinforced carbon-carbon material in an earth atmospheric entry environment. A mathematical model was developed which describes oxygen diffusion and reaction rates within material pores. Pertinent rate constants were derived, and mat…
Desert varnish has been characterized by infrared spectroscopy, x-ray diffraction, and electron microscopy. It is a distinct morphological entity having an abrupt boundary with the underlying rock. Clay minerals comprise more than 70 percent of the varnish. Iron and manganese oxides constitute the bulk of the remainde…
A total of 66 autoionising states of Rb I have been observed between 15 and 21 eV excited-state energy, excitation being by electron impact at kinetic energies of 27, 40, 100 and 400 eV. Of the observed states, 40 have been reported in ultraviolet absorption experiments. The remaining 26 states do not appear in any pr…
Lithium-sodium beta alumina having a lithium/sodium ratio greater than about I appears to be the first generally useful lithium superionic conductor that has been reported. It exhibits strikingly nonlinear ion exchange properties and may presage the discovery of similar co-ionic interactions in other superionic conduc…
Afin d'étudier la précipitation du composé Fe3Ga ordonné (structure Ll2 ou DO19) dans une matrice elle-měme ordonnée (structure DO3), nous avons été conduits à préciser le diagramme de phases du système fer–gallium dans la région 15 è 30 %at Ga. La preéipitation se produit suivant un processus continu avec germination…
The Mössbauer effect of 57Fe is used to investigate the early stage of phase separation in the Fe-33 at% Cr-21.5 at% Co alloy, a new ductile permanent magnet. After being quenched from a one-phase region, the foil samples are aged at 560 °C, and the Mössbauer spectra are taken at room temperature. The hyperfine field…