Materials Literature
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The fundamental principles of the electrochemical determination of the surface area of metals are discussed. Conditions of determination and methods of calculation are analysed for smooth and powdered metals of the platinum group, nickel, the copper subgroup, and carbonaceous materials. A list of 108 references is inc…
Using pulsed nuclear magnetic resonance methods the central component magnetisation recovery curves have been measured for 59 Co in a single crystal of K 3 Co(CN) 6 at 295K. By using two different sets of initial conditions it has been possible to measure the parameters W 1 and W 2 which are related to the transition…
The 1.945 eV optical centre is produced in type Ib diamond by radiation damage and annealing at approximately 800 degrees C. The author reports that H3 (2.463 eV) centres, characteristic of irradiated and annealed type Ia diamond, have been created by heating an irradiated type Ib diamond to temperatures where nitroge…
Material dispersion measurements are reported on six characteristic lightguide glass compositions. The measurements were made on bulk specimens and cover the wavelength range from 0.8 to 1.5 μm. It is observed that in these silicate glasses the wavelength at which material dispersion is zero is in all cases greater th…
Fatigue failure in marine propeller blades of Ni-Al-bronze was investigated. Calculations of alternating stress imposed on the propeller blades were carried out by unsteady lifting surface theory and the results were applied to the analysis of fatigue failure of blades. Fatigue tests in seawater were carried out by us…
The present work consists of an analytical investigation of the effective thermal conductivity of microsphere and fi- brous insulation media. Because of the statistical nature of random packing patterns of microspheres and fibers, there ex- ists a range of effective thermal conductivities for any given solid fraction…
An increasing body of research indicates that carbon can exist in a number of polymorphic "carbyne" forms. It is proposed that these forms occur because of a shift to triple bonding in the carbon system as temperature increases above 2600 K. It is also proposed that graphite can dissociate into triple-bonded molecules…
The perovskite-type layer compound NH3(CH2)3NH3MnCl4 undergoes two discontinuous structural phase transitions at 336 and 305 K, respectively. Optical, dielectric, and 35Cl NQR measurements in all three phases as well as differential thermal analysis of the phase transitions are performed. The partially deuterated comp…
Barium titanate doped with donors is a good n-type semiconductor, the conductivity of which, however, is considerably influenced by intrinsic defects always present in these materials. Therefore not only the equilibrium behaviour of these defects but also the defect formation and the defect diffusion play an important…
Data are presented for the refractive index of Irtran 2, a hot-pressed microcrystalline compact of ZnS, made by the Eastman Kodak Company, from 1 microm to 15 microm and from 93 K to 283 K. The values range from 2.35 at both high temperatures and short wavelengths to 2.12 at the opposite extremes. The average value of…
The controlled potential electrolysis of Ni(II) meso-tetraphenylporphyrin (Ni(II)TPP) gives at room temperature the corresponding metalloporphyrin π-cation radical [Ni(II)TPP] + • . Upon freezing a solution of the π-cation radical to 77 K an internal electron transfer occurs to give [Ni(III)TPP] + . A discussion of th…
Crystals of varying compensation mechanism (extra oxygen bridges or ${\mathrm{Co}}^{2+}$ substitution) and phase ($\ensuremath{\beta}$ or ${\ensuremath{\beta}}^{\ensuremath{'}\ensuremath{'}}$) have been grown by adding cobalt oxide to a melt containing NaC${\mathrm{O}}_{3}$, ${\mathrm{Al}}_{2}$${\mathrm{O}}_{3}$, and…
The far-infrared conductivity of Na, Ag, Rb, and K $\ensuremath{\beta}$-alumina is measured from 10 to 200 ${\mathrm{cm}}^{\ensuremath{-}1}$. A broad band of absorption is observed whose detailed structure depends on growth conditions. The frequencies observed agree quantitatively with model calculations by Wang, Gaff…
An attempt has been made to understand the detailed form and phasing taken by the periodic-structural distortions (PSD) as developed in the various ${d}^{1}\ensuremath{-}{d}^{0}$ charge-density-wave (CDW) bearing materials. The diagrammatic mode of presentation which is used facilitates insight into the forces at work…
The transport properties of semimetallic Ti${\mathrm{Se}}_{2}$ are reexamined, and the limits of a two-band model are discussed. We conclude that the density of electrons and holes is 5 \ifmmode\times\else\texttimes\fi{} ${10}^{20}$/${\mathrm{cm}}^{3}$ to 10 \ifmmode\times\else\texttimes\fi{} ${10}^{20}$/${\mathrm{cm}…
A linear $\ensuremath{\gamma}T$ term is observed in the low-temperature specific-heat behavior of the nonmetallic vanadiumoxide bronzes of sodium and copper. The low-temperature magnetic susceptibility is equally anomalous and points to a singlet or diamagnetic ground state. It is postulated that the ${\mathrm{V}}^{4+…
Resonant Raman scattering of multiphonon modes has been studied in ${\mathrm{Cu}}_{2}$O in the region of its yellow and green excitonic series. Resonant enhancements of a large number of Raman modes have been observed. The experimental results have been interpreted quantitatively in terms of three kinds of exciton-pho…
Energy-loss spectra were measured by backscattering 500-eV electrons from films of W${\mathrm{O}}_{3}$ grown on single-crystal W(100), and from single crystals of ${\mathrm{Na}}_{x}$ W${\mathrm{O}}_{3}$ ($0.35<x<0.86$) and Re${\mathrm{O}}_{3}$ which were cleaved in ultrahigh vacuum. The spectrum of a crystal wit…
M2[Pt(CN)4]3⋅nH2O compounds (with M3+=Sm3+, Eu3+, Tb3+,...) represent a new solid state class for investigations of nonradiative excitation energy transfer. The donors are linear stacks (columns) of square planar [Pt(CN)4]2− complexes and the acceptors are rare earth ions which are located between the stacks. Radiatio…
An efficient and accurate numerical procedure is used to solve the HNC and RHNC integral equations for charged hard spheres, the so-called restricted primitive model (RPM) for electrolyte solutions and molten salts. The computed thermodynamic quantities and correlation functions are found to be in good but not excelle…