Materials Literature
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Thin films of amorphous (stoichiometric) GeTe have been examined by direct recording of electron diffraction, and intensity profiles across the diffuse diffraction pattern have been recorded with electrostatic rejection of inelastically scattered electrons. Radial distribution analysis of these curves shows that the l…
Abstract Isotactic polypropylene hot‐pressed film was subjected to uniaxial and biaxial stretching. The orientation behavior was investigated by means of x‐ray pole figure technique, birefringence, electron microscope, and tensile tester. From the x‐ray pole figure results it was confirmed that three kinds of crystal…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTExcimer fluorescence and dimer phosphorescence from a naphthalene sandwich pairEdwin A. Chandross and Carol J. DempsterCite this: J. Am. Chem. Soc. 1970, 92, 3, 704–706Publication Date (Print):February 1, 1970Publication History Published online1 May 2002Published inissue 1…
Abstract Differential thermal analysis of mixtures of poly(vinyl chloride) and dioctyl phthalate shows a compound endothermic peak due to decomposition of both polymer and plasticizer. The thermal behavior of other plasticizers is similarly affected in the presence of poly(vinyl chloride). The addition of zinc oxide o…
When uranium metal is nitrified in 1 atm N 2 , the well‐known uranium sesquinitride with the bcc structure is obtained as a single phase at 1150° to 1175°C and below. A single phase of another sesquinitride with the hep structure is formed at 1330° to 1350°C. Between these temperatures, a kinetically stable mixture of…
Fine‐particle beta sodium ferrite (β‐NaFeO 2 ), rather than α‐Fe 2 O 3 , may be responsible for superparamagnetic behavior in a glass of composition (in mole fractions) 0.37Na 2 O‐0.26Fe 2 O 3 ‐0.37SiO 2 . The 700°C isothermal section of the phase diagram of the Na 2 O‐Fe 2 O 3 ‐SiO 2 system is given, showing a three‐…
The effects of capillary grooves on surface wetting and evaporation have been analysed. An attempt has been made to obtain expressions which approximately describe the increase in heat transfer in order to select for given properties and temperature differences a groove of optimum design. For this purpose, it is assum…
Investigations with the electron microscope on γ-irradiated single crystals of LiH have revealed the presence of cubic voids, or bubbles. These bubbles are crystallographically oriented, principally with their sides parallel to the (100) planes of the LiH crystals. Bubbles range in size from ∼ 75 Å to ∼ 1500 Å. Averag…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCyclization reactions of ninhydrin with aromatic amines and ureasRobert Shapiro and Nithiananda ChatterjieCite this: J. Org. Chem. 1970, 35, 2, 447–450Publication Date (Print):February 1, 1970Publication History Published online1 May 2002Published inissue 1 February 1970http…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermal conductivity of binary mixtures of alkali nitratesJohn McDonald and Howard Ted DavisCite this: J. Phys. Chem. 1970, 74, 4, 725–730Publication Date (Print):February 1, 1970Publication History Published online1 May 2002Published inissue 1 February 1970https://pubs.acs.…
Contact angles, surface free energies, and work of adhesion were determined by a sessile drop technique for the wetting of MgO, Al 2 O 3 , and SiO 2 by In, Ga, and Sn at 10 ‐10 torr. The surface free energies of In, Ga, and Sn were 540, 632, and 573 ergs/cm 2 (±5%), respectively, at their melting points. Works of adhe…
Abstract Der bei Kaltverformung entstehende Martensit ist bei ebenmäßiger Korrosion nur dann schädlich, wenn sich die Probe im jeweiligen Angriffsmittel im Zustand befindet; die Korrosionsstromdichte steigt dann mit dem Verformungsgrad, Der Verformungsmartensit verringert andererseits die Anfälligkeit für die interkri…
Numerical curve fitting of glow peaks, using a computer, is shown to be more objective and accurate than the existing graphical curve fitting method in evaluating trap activation energies. Besides using the numerical curve fitting method for glow peaks of first-order kinetics, the method is extended to the case of sec…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCrystal and molecular structure of tris(tetra-n-butylammonium) octacyanomolybdate(V)Brian J. Corden, James A. Cunningham, and Richard EisenbergCite this: Inorg. Chem. 1970, 9, 2, 356–362Publication Date (Print):February 1, 1970Publication History Published online1 May 2002Pu…
Abstract The self-diffusion coefficient (D) of silver ions in silver iodide has been measured between 200 °C and 500 °C. The results can be described by the Arrhenius equation D = 16.62 x 10 -5 exp (-2190/RT), where R is the gas constant in cal/mode, °K and T the temperature in °K. The standard deviation was 0.12 cm 2…
High‐purity strontium, zirconium, and titanium alkoxides were synthesized and characterized as precursors for complex oxides. Simultaneous hydrolytic decomposition either of strontium and zirconium alkoxides or of strontium and titanium alkoxides was used to obtain nearly stoichiometric, ideally mixed SrZrO 3 or SrTiO…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and characterization of tris(maleonitriledithiolato)metalatesE. I. Stiefel, Larry Everett Bennett, Z. Dori, T. H. Crawford, C. Simo, and Harry B. GrayCite this: Inorg. Chem. 1970, 9, 2, 281–286Publication Date (Print):February 1, 1970Publication History Published o…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInfrared matrix isolation spectrum of the methyl radical produced by pyrolysis of methyl iodide and dimethyl mercuryAlan SnelsonCite this: J. Phys. Chem. 1970, 74, 3, 537–544Publication Date (Print):February 1, 1970Publication History Published online1 May 2002Published inis…
Abstract The preparation of a particulate sialyl transferase from rat liver and its properties are described. The enzyme was used, in the presence of cytidine monophosphate-N-acetylneuraminic acid-1-14C and asialoceruloplasmin, to prepare substantive quantities of radioactive ceruloplasmin. With a completely desialyla…
Article Alloy Chemistry of σ (β-U)-Related Phases III. σ-Phases with Non-Transition Elements was published on February 1, 1970 in the journal International Journal of Materials Research (volume 61, issue 2).