Multiphonon Orbit-Lattice Relaxation in La Br 3 , La Cl 3 , and La F 3
Received 2 October 1967DOI:https://doi.org/10.1103/PhysRevLett.19.1423©1967 American Physical Society
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Hypersensitivity of the 5D—7F2 Transition of Trivalent Europium in the Garnet Structure
Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation G. Blasse, A. Bril; Hypersensitivity of the 5D—7F2 Transition of Trivalent Europium in the Garnet…
Far-Infrared Spectra of Ring Compounds. II. The Spectrum and Ring-Puckering Potential Function of Cyclopentene
The infrared spectrum of cyclopentene has been recorded in the range 18–300 cm−1. Two series of thirteen and nine Q branches, respectively, were observed, both of which arise from the strongly anharmonic energy levels of the B1 ring-puckering vibration. The longer, more intense series is assigned to molecules in the g…
Investigation of Some Ce3+-Activated Phosphors
The fluorescence of a number of new Ce3+-activated phosphors is described and discussed. Only host lattices with a sublattice consisting of trivalent lanthanide ions are used to avoid charge compensation of the Ce3+ ion. Usually the Ce3+ emission is in the near-ultraviolet region. Y3Al5O12–Ce and SrY2O4–Ce, however, s…
Auger Electron Emission from Clean and Carbon-Contaminated Mo
Measurements have been made of the Auger electron yield from polycrystalline Mo targets bombarded by mass-selected beams of ${\mathrm{Ar}}^{+}$ and ${\mathrm{He}}^{+}$ ions at normal incidence. The yields were measured for incident-ion kinetic energies of 50-400 eV. The experiments were conducted in ultrahigh vacuum t…
Lattice-Vibration Effects in the Spectra of ZnO:Ni and ZnO:Co
The optical absorption spectra of ZnO:${\mathrm{Ni}}^{2+}$ and ZnO:${\mathrm{Co}}^{2+}$ have been studied in the visible region, at temperatures from 7\ifmmode^\circ\else\textdegree\fi{}K up. From correlation with lattice phonon energies, evidence has been found for the assignment of much of the band structure to vibr…
Magnetic Resonance and Susceptibility of Several Ilmenite Powders
Magnetic susceptibility, paramagnetic resonance, and antiferromagnetic resonance have been measured in MnTi${\mathrm{O}}_{3}$, FeTi${\mathrm{O}}_{3}$, CoTi${\mathrm{O}}_{3}$, and NiTi${\mathrm{O}}_{3}$. N\'eel temperatures ${T}_{N}$ of 65, 56, 37, and 23\ifmmode\pm\else\textpm\fi{}2\ifmmode^\circ\else\textdegree\fi{}K…
Optical Absorption in Single-Domain Ferroelectric Barium Titanate
The optical-absorption coefficients for polarized light have been measured for single-domain crystals of $n$-type BaTi${\mathrm{O}}_{3}$. The measurements were made over a wavelength range from approximately 0.4 to 12 \ensuremath{\mu}, and over a temperature range from 26 to 130\ifmmode^\circ\else\textdegree\fi{}C. Th…
Localized versus CollectivedElectrons and Néel Temperatures in Perovskite and Perovskite-Related Structures
It is pointed out that a simple, localized-electron antiferromagnet having one electron per localized orbital interacting via 180\ifmmode^\circ\else\textdegree\fi{} superexchange with similar orbitals on $z$ near-neighbor cations via an overlap integral $\ensuremath{\Delta}$ has a N\'eel temperature $k{T}_{n}\ensurema…
Magnetic Study of the Manganate Phases: CaMnO3,Ca4Mn3O10,Ca3Mn2O7,Ca2MnO4
Two series of manganate phases have been prepared and their magnetic properties measured. The first series consists, in addition to CaMn${\mathrm{O}}_{3}$, of three phases having layered structures. In these, tetravalent magnanese ions are contained in single or multiple perovskite layers which are separated from each…
Critical size of magnetic particles with high uniaxial anisotropy
Abstract The critical sizes of particles of magnetic material with high uniaxial anisotropy are calculated by equating the energies in the single and multi-domain states. Exact calculations are presented of the variation of critical size with shape for a rectangular particle, and the variation of critical size in an…
Crosslinking cotton with formaldehyde in phosphoric acid
Abstract Cotton print cloth was treated with a solution of formaldehyde in concentrated orthophosphoric acid (a strong cellulose swelling agent). The treatment produces a crosslinked cotton with extremely high wet wrinkle recovery and moisture absorptivity, and very low dry wrinkle recovery. The variations in physical…
A redox‐initiated xylan–poly(sodium acrylate) graft copolymer
Abstract An aspen 4‐ O ‐methylglucuronoxylan was grafted with poly(sodium acrylate) (PSA) in 3.4 N NaOH at 25–30°C. with the use of a persulfate–thiosulfate redox initiator system. The formation of a true graft copolymer was indicated by fractional precipitation and light‐scattering studies, physical mixtures of the t…
The crystal structure and refinement of ferrimagnetic barium ferrite, BaFe12O19
Article The crystal structure and refinement of ferrimagnetic barium ferrite, BaFe12O19 was published on December 1, 1967 in the journal Zeitschrift für Kristallographie - Crystalline Materials (volume 125, issue 1-6).
Sättigungsdrucke über SbCl3, SbCl5 und das Reaktionsgleichgewicht SbCl3 + Cl2 = SbCl5
Abstract Der Dampfdruck über flüssigem SbCl 3 wurde zwischen 90 und 190°C, der über flüssigem SbCl 5 zwischen 50 und 120°C im Membrannullmanometer gemessen. Die Auswertung liefert die Verdampfungsenthalpien und Verdampfungsentropien am Siedepunkt: Die aus den Geradenneigungen berechneten Siedepunkte betragen \document…
Low-temperature magnetic properties of dysprosium single crystals
The magnetic properties of three single crystals of dysprosium have been investigated along the principal directions of the hexagonal close-packed structure, over the temperature range 4 to 300 °K and in applied fields up to 18 kOe. The measurements along the a and b directions agree in general with the previous work.…
Impact Cratering in Granular Materials
Craters produced by projectile impact in granular materials were studied for a wide range of energies and projectile types. Crater sizes were shown to depend on projectile size and shape and on the particle size of the target material. The volume of the impact crater was related to the kinetic energy of the projectile…
The Relative Reactivities of the Hydroxyl Groups of Cotton Cellulose—A Progress Report1
Major preceding studies of the distribution of substituents in cellulose have been reviewed. Over-all results indicate that the highest degree of reaction occurs at the hydroxyl group on C-2 in the case of the irreversible Williamson syntheses involving reagents of small molecular size. Pronounced preferential reactio…
Verbindungen mit Apatitstruktur. III. Apatite des Typs M(XVIO4)3F2 (MII = Sr, Pb; XVI = S, Cr; XIV = Si, Ge)
Abstract Durch Festkörperreaktionen gelang die Darstellung von 8 Verbindungen des Typs M (X VI O 4 ) 3 F 2 (M II = Sr, Pb; X VI = S, Cr; X IV = Si, Ge) mit Apatitstruktur. Die Gitterdimensionen der Verbindungen werden mitgeteilt. Zwischen Sr 10 (PO 4 ) 6 F 2 und Sr 10 (SO 4 ) 3 (SiO 4 ) 3 F 2 besteht eine vollständige…
Inelastic Scattering of Kilovolt Electrons by Solids and Liquids
Some recent measurements of the inelastic scattering of kilovolt electrons by solids and liquids are described. The determination of energy losses and cross sections is discussed as well as factors influencing the accuracy of measurement. The degree of correlation between optical and electron energy loss experiments a…