Materials Literature
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The apparent particle size of distorted crystallites varies from independence of θ and λ (particle-size broadening) to proportionality with λ cosec θ (distortion broadening) as the parameter Eη sin θ/λ increases, where E is a particle size and η is an average strain. For a bent `orthorhombic' lamella of thickness T wi…
Warren's calculation of the line profile for diffraction from random layers depends on the use of an approximation function. This can be. avoided, and expressions found for (a) the ideal line profile for slow variation of the structure amplitude, and (b) the variation of the intensity of diffraction as a function of p…
A comprehensive X-ray investigation of the crystal structure of naphthalene is described, in which all the reflexions that lie within the reach of Cu Kα radiation have been examined. Moving-film photographic methods and visual estimates of intensities by independent observers were employed. From the results a total of…
This paper contains a calculation of the X-ray diffraction pattern to be expected from a randomly oriented assemblage of line gratings. A line grating is defined as a periodic linear structure, most generally represented by a chain of similarly oriented and uniformly separated unit cells arranged along a straight line…
The general theory is developed of X-ray scattering by crystals showing order in two translation directions but disorder in the third direction, the treatments previously published having proved inadequate for the interpretation of some single-crystal observations of the author. The solution of the problem is affected…
Progress of Theoretical Physics Vol. 3 No. 1 (1948) pp. 26–37 On Wentzel's Method in the Meson Theory Tatuoki Miyazima, Takao Tati and Sin-itiro Tomonaga Progress of Theoretical Physics Vol. 6 No. 5 (1951) pp. 815–828 On the Adiabatic Nuclear Potential, I Kazuhiko Nishijima Progress of Theoretical Physics Vol. 10 No.…
The decay rates of three doubly activated phosphors, namely, calcium halophosphate (Mn, Sb), calcium silicate (Mn, Pb), and zinc fluoride (Mn, Ti, or W) have been investigated under λ2537 excitation. The halophosphates studied all show initially a very rapid and abrupt decay, followed by a second stage of decay having…
Calcium silicate phosphors activated with varying amounts of manganese luminesce yellow to orange under cathode-ray excitation, but are not excited by ultraviolet λ2537. If a small amount of lead is added with the manganese, the resulting material responds to λ2537 to give the same color as that produced by cathode ra…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Mutual Habit Modification of Sodium Chloride and Dipolar IonsCharles P. Fenimore and Arthur. ThrailkillCite this: J. Am. Chem. Soc. 1949, 71, 8, 2714–2717Publication Date (Print):August 1, 1949Publication History Published online1 May 2002Published inissue 1 August 1949h…
Methods are described for preparing Ta–H and Zr–H targets for economic use of tritium. Ratios of hydrogen isotope to metals of about 1.0 were obtained. The use of these targets under deuteron bombardment is discussed.
Debye's theory of dielectric relaxation has been extended to molecules consisting of two similar polar groups, which cannot rotate freely relatively to one another owing to their mutual potential energy. As a result, the mean dipole moment of the molecule in the field F0 exp(iωt) can be expressed by a sum of terms of…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDegradation and Stabilization of Polyvinyl ChlorideV. Warren Fox, J. G. Hendricks, and H. J. RattiCite this: Ind. Eng. Chem. 1949, 41, 8, 1774–1779Publication Date (Print):August 1, 1949Publication History Published online1 May 2002Published inissue 1 August 1949https://pubs…
Abstract Die additive Berechnung der Verbrennungswärme organischer Verbindungen wurde weitgehend verbessert und erreicht nunmehr bei aliphatischen und einfachen alicyclischen Kohlenwasserstoffen eine Genauigkeit von ± 0.5 (z. Tl. sogar ± 0.2)/100 der Gesamtverbrennungswärme. Die neuen Verbrennungswerte der verschieden…
Abstract Tensile strengths of natural rubber samples quantitatively crosslinked with decamethylene dis‐methyl azodicarboxylate have been determined. The proportion of the azo vulcanizing agent was varied 80‐fold, the fraction p of cross‐linked units in the products ranging from 0.10x 10 −2 to 8.0 x 10 −2 . In spite of…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Heats of Formation of Sodium Borohydride, Lithium Borohydride and Lithium Aluminum HydrideWilliam D. Davis, L. S. Mason, and G. StegemanCite this: J. Am. Chem. Soc. 1949, 71, 8, 2775–2781Publication Date (Print):August 1, 1949Publication History Published online1 May 200…
A bstract A discussion of hypotheses concerning the development of gold ruby, silver yellow, and copper ruby colors in silicate glass is presented. Experiments are described which were designed to determine whether gold dissolves in molten silicate glasses in an oxidized (ionic) state or as uncombined metal. Results a…
It is suggested that the tendency to make use of all low energy orbitals is the underlying principle of electron-deficient bonding. Simple theoretical arguments, limited to the special case of two electrons and three orbitals, are given to show that this principle is a direct consequence of quantum-mechanical theories…
In order to gain additional information about the origin of preferred orientation of recrystallized grains, the influence of a magnetic field on recrystallization of iron-cobalt alloys is being studied. Preliminary results indicate a change of the texture which can be qualitatively accounted for by considering the mag…
An expanded part of a thesis on The properties of clays submitted ... for the degree of master of science in the ... University of Illinois.
Abstract The residual lattice strain observed by X-ray diffraction methods in plastically extended polycrystalline aggregates has been investigated. It is shown that, if several diffraction lines are examined, the residual lattice strains vary both in magnitude and in sign. It is known that one of the causes of intern…