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Degradative acetolactate synthase of Bacillus subtilis: purification and properties

W. David Holtzclaw、Linda F. Chapman1975-03-01Journal of Bacteriology

A degradative acetolactate synthase (acetolactate pyruvate-lyase [carboxylating], EC 4.1.3.18) from Bacillus subtilis has been partially purified and characterized. The synthesis of the enzyme was induced by growth of cells in minimal medium plus isobutyrate or acetate. The enzyme was partially purified by ammonium su…

Enzyme Structure and FunctionProtein Structure and DynamicsBiochemical and Molecular Research

Localisation and characterisation of egg shell porphyrins in several avian species

T. Baird、S. E. Solomon、D. R. Tedstone1975-03-01British Poultry Science

1. Electron microscopy, infra-red analysis and histochemical techniques have been used to determine the site of pigment deposition, the cellular localisation of pigment and the type of pigment precipitated in the egg shells of quail, White Leghorn, Brown Ranger and Black-Headed gull. 2. Transfer of pigment occurs via…

Porphyrin and Phthalocyanine ChemistryPorphyrin Metabolism and DisordersPhotosynthetic Processes and Mechanisms

Geometrical and structural relations in the rhombohedral perovskites

H. D. Megaw、C. N. W. Darlington1975-03-01OpenAlex

The rhombohedral perovskites are of interest in lattice dynamics (e.g. LaAlO3, PrAlO3) and for their ferroelectric properties (e.g. LiNbO3, PbZr/TiO3). In this paper, data scattered through the literature are correlated, with correction of some misleading mistakes of calculation. Geometrical descriptions are put in a…

Acoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics SynthesisFerroelectric and Piezoelectric Materials

Thermally Induced Phase Separation Behavior of Compatible Polymer Mixtures

Toshio Nishi、Tai-Yue Wang、T. K. Kwei1975-03-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermally Induced Phase Separation Behavior of Compatible Polymer MixturesT. Nishi, T. T. Wang, and T. K. KweiCite this: Macromolecules 1975, 8, 2, 227–234Publication Date (Print):March 1, 1975Publication History Published online1 May 2002Published inissue 1 March 1975https:…

Polymer crystallization and properties

Statistical mechanics of dense ionized matter. III. Dynamical properties of the classical one-component plasma

J. P. Hansen、Ian R. McDonald、E. L. Pollock1975-03-01OpenAlex

We present extensive molecular-dynamics (MD) computations of the time-dependent correlation functions of the classical one-component plasma over a wide range of thermodynamic states characterized by the dimensionless parameter $\ensuremath{\Gamma}=\frac{{e}^{2}}{a{k}_{B}T}$, where $a$ is the ion-sphere radius. The com…

Material Dynamics and PropertiesSpectroscopy and Quantum Chemical StudiesPhase Equilibria and Thermodynamics

Molecular Vibrations of Three Crystal Forms of Poly(vinylidene fluoride)

Masamichi Kobayashi、Kohji Tashiro、Hiroyuki Tadokoro1975-03-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMolecular Vibrations of Three Crystal Forms of Poly(vinylidene fluoride)Masamichi Kobayashi, Kohji Tashiro, and Hiroyuki TadokoroCite this: Macromolecules 1975, 8, 2, 158–171Publication Date (Print):March 1, 1975Publication History Published online1 May 2002Published inissue…

Synthesis and properties of polymersSilicone and Siloxane ChemistryConducting polymers and applications

The quantitative analysis of thin specimens

G. Cliff、G. W. Lorimer1975-03-01OpenAlex

SUMMARY Results are reported concerning the use of an energy dispersive X‐ray detector to carry out the analysis of thin foils in the electron microscope. The combination of a thin specimen and the extreme stability of the energy dispersive X‐ray detector enables the experimental determination of a calibration curve o…

Nuclear Physics and ApplicationsAdvanced X-ray and CT ImagingElectron and X-Ray Spectroscopy Techniques

Charge-density waves and superlattices in the metallic layered transition metal dichalcogenides

J. A. Wilson、F. J. Di Salvo、Shivam Mahajan1975-03-01OpenAlex

The d1 layer metals TaS2, TaSe2, NbSe2, in all their various polytypic modifications, acquire, below some appropriate temperature, phase conditions that their electromagnetic properties have previously revealed as ‘anomalous’. Our present electron-microscope studies indicate that this anomalous behaviour usually inclu…

2D Materials and ApplicationsIron-based superconductors researchOrganic and Molecular Conductors Research

Extreme Toxicity from Combustion Products of a Fire-Retarded Polyurethane Foam

J. H. Petajan、Kent J. Voorhees、S.C. Packham 等 8 位作者1975-02-28Science

The products from nonflaming combustion of wood and a trimethylol-propane-based rigid-urethane foam that was not fire-retarded produced elevated carboxyhemoglobin levels but no abnormal neurological effects. However, when this type of foam contained a reactive phosphate fire retardant, the combustion products caused g…

Flame retardant materials and propertiesFire dynamics and safety researchEnvironmental and Industrial Safety

Peierls structure transition in quasi-one-dimensional crystals

L. N. Bulaevskiǐ1975-02-28Soviet Physics Uspekhi

This review is concerned with the structure, electrical, and optical properties of mixed-valence platinum complexes of the K2 Pt(CN)1, Br0.303H2O type and of TTF-TCNQ salts. Special attention is paid to the experimental results on the anisotropy of electron motion in these quasi-one-dimensional crystals. The theory of…

Organic and Molecular Conductors ResearchPhysics of Superconductivity and MagnetismMagnetism in coordination complexes

Flow induced polymer chain extension and its relation to fibrous crystallization

M. R. Mackley、Andrew Keller1975-02-27Philosophical Transactions of the Royal Society of London Series A Mathematical and Physical Sciences

Abstract This work examines the effect that appreciable molecular extension has on the crystallization of long chain molecules. Elementary theoretical considerations presented indicate that to achieve high molecular extensions in solution a longitudinal velocity gradient of strain rate about 103s-1 is required. A meth…

Carbon Nanotubes in CompositesPolymer Foaming and CompositesPolymer crystallization and properties

Environmental crack and craze growth phenomena in polymers

J. G. Williams、G. P. Marshall1975-02-25Proceedings of the Royal Society of London A Mathematical and Physical Sciences

Abstract The nature of slow crack and craze propagation in polymers and crack propagation in inorganic glass has been considered in terms of time dependent processes. By using a fracture mechanics analysis together with time dependent material parameters, equations have been derived to describe crack and craze propaga…

Rheology and Fluid Dynamics StudiesInjection Molding Process and PropertiesPolymer crystallization and properties

Pendular rings between solids: meniscus properties and capillary force

Franklin M. Orr、L. E. Scriven、Ayala Rivas1975-02-25OpenAlex

The Laplace–Young equation is solved for axisymmetric menisci, analytically in terms of elliptic integrals for all possible types of pendular rings and liquid bridges when the effect of gravity is negligible, numerically for selected other cases in order to assess gravity's effect. Meniscus shapes, mean curvatures, ar…

Surface Modification and SuperhydrophobicitySpacecraft and Cryogenic TechnologiesPlanetary Science and Exploration

The metal-non-metal transition in VO2: X-ray photoemission and resistivity measurements

C. Blaauw、F. Leenhouts、F. van der Woude 等 4 位作者1975-02-21Journal of Physics C Solid State Physics

The semiconductor-metal transition in VO 2 has been investigated by means of XPS measurements. The band gap in the semiconducting region is found to be temperature-dependent with a room temperature value of E g =0.3 eV, in agreement with resistivity measurements. The core lines, which are asymmetric below T nu broaden…

Gas Sensing Nanomaterials and SensorsTransition Metal Oxide NanomaterialsGa2O3 and related materials

Photoemission Partial State Densities of OverlappingpanddStates for NiO, CoO, FeO, MnO, andCr2O3

D. E. East̀man、J. L. Freeouf1975-02-17Physical Review Letters

We report partial densities of states of overlapping bandlike $p$ states and localized $d$ states in several insulating transition-metal oxides which have been determined from frequency-dependent photoemission spectra taken in the range 5-90 eV. We observe that $p$-band features become weak relative to $d$-state and s…

Transition Metal Oxide NanomaterialsElectronic and Structural Properties of OxidesGa2O3 and related materials

Local Inhomogeneity of Garnet Crystals Doped with Rare-Earth Ions

Yu. K. Voron’ko、A. A. Sobol1975-02-16physica status solidi (a)

Some defects of the host lattice of crystals of the T3Al5O12 series (where T is Tb, Dy, Y, Ho, Er, Tu, Yb, Lu) doped with rare-earth ions (TR3+), are investigated by means of an analysis of the inhomogeneous splitting of the spectral lines of the TR3+ impurity ions. The connection of the concentration of some defect t…

Glass properties and applicationsOptical and Acousto-Optic TechnologiesSolid-state spectroscopy and crystallography

The DO22 Intermediate Phase in the Ni-Mo System

Gustaaf Van Tendeloo、R. de Ridder、S. Amelinckx1975-02-16physica status solidi (a)

A study of Ni3Mo by electron microscopy and electron diffraction reveals the presence of a new metastable intermediate phase during the early stages of ordering. This phase having the DO22 structure is only observed under well specified experimental conditions; it is generated immediately from the short range ordered…

Advanced Materials Characterization TechniquesMetallurgical and Alloy ProcessesIntermetallics and Advanced Alloy Properties

Luminescence of Lead Molybdate and Lead Tungstate. I. Experimental

W. Van Loo1975-02-16physica status solidi (a)

Optical properties of single crystals of lead molybdate and lead tungstate (scheelite structure) have been investigated in order to identify the nature of the luminescent centres. Absorption, emission, and excitation spectra at different temperatures (1.5 to 300 K) and photoconductivity and quantum efficiency measurem…

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Optical aging characteristics of borosilicate clad fused silica core fiber optical waveguides

I. Camlibel、D. A. Pinnow、F. W. Dabby1975-02-15Applied Physics Letters

Very low transmission loss fiber optical waveguides have been developed during the past two years which have pure fused silica cores surrounded by borosilicate glass claddings. A recent study of the binary borosilicate glass system revealed that the low refractive index values which can be achieved with this glass and…

Advanced Fiber Optic SensorsPhotonic and Optical DevicesGlass properties and applications