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X-Ray Photoelectron Spectroscopic Studies of Carbon Fiber Surfaces. Part XVI: Core-Level and Valence-Band Studies of Pitch-Based Fibers Electrochemically Treated in Ammonium Carbonate Solution

Yaoming Xie、Tie-Jun Wang、O. M. Franklin 等 4 位作者1992-04-01Applied Spectroscopy

DuPont E-120 high-modulus pitch-based carbon fibers were treated electrochemically in 0.5 M (NH 4 ) 2 CO 3 solution under both potentiostatic and galvanostatic modes. X-ray photoelectron spectroscopy (XPS) was used to monitor the chemical changes on the carbon fiber surfaces. Both core-level and valence-band spectra s…

Advancements in Battery MaterialsFiber-reinforced polymer compositesElectron and X-Ray Spectroscopy Techniques

Effects of regeneration conditions on the characteristics of water vapor adsorption on silica gel

Rong Luan Yeh、Tushar K. Ghosh、Anthony L. Hines1992-04-01Journal of Chemical & Engineering Data

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEffects of regeneration conditions on the characteristics of water vapor adsorption on silica gelRong Luan Yeh, Tushar K. Ghosh, and Anthony L. HinesCite this: J. Chem. Eng. Data 1992, 37, 2, 259–261Publication Date (Print):April 1, 1992Publication History Published online1…

Mesoporous Materials and CatalysisCarbon Dioxide Capture Technologies

Photoelectrochemical Measurements of Thin Oxide Films: Multiple Internal Reflection Effects

J.P.H. Sukamto、William H. Smyrl、Christopher S. McMillan 等 4 位作者1992-04-01Journal of The Electrochemical Society

Previous studies have shown that photoelectrochemical methods used to study the semiconducting properties of oxides may be extended to in situ investigations of thin oxide films. A new expression relating the photocurrent to the film thickness has been derived by combining a simplified Gärtner/Butler model and an opti…

Transition Metal Oxide NanomaterialsAnodic Oxide Films and NanostructuresElectronic and Structural Properties of Oxides

Error Estimates with Smooth and Nonsmooth Data for a Finite Element Method for the Cahn-Hilliard Equation

Charles M. Elliott、Stig Larsson1992-04-01Mathematics of Computation

A finite element method for the Cahn-Hilliard equation (a semilinear parabolic equation of fourth order) is analyzed, both in a spatially semidiscrete case and in a completely discrete case based on the backward Euler method. Error bounds of optimal order over a finite time interval are obtained for solutions with smo…

Advanced Numerical Methods in Computational MathematicsSolidification and crystal growth phenomenaAdvanced Mathematical Modeling in Engineering

Synthesis and preliminary characterization of a new fully aromatic mesogenic polyester containing a 2-phenylbenzoxazole group

Ugo Caruso、Roberto Centore、Antonio Roviello 等 4 位作者1992-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and preliminary characterization of a new fully aromatic mesogenic polyester containing a 2-phenylbenzoxazole groupU. Caruso, R. Centore, A. Roviello, and A. SiriguCite this: Macromolecules 1992, 25, 9, 2290–2293Publication Date (Print):April 27, 1992Publication Hi…

Liquid Crystal Research AdvancementsEpoxy Resin Curing ProcessesSynthesis and properties of polymers

Simulations of phase transitions in Rb2ZnCl4

Haidong Lu、John Hardy1992-04-01Physical review. B, Condensed matter

Structural relaxations, molecular-dynamics simulations, and lattice-dynamics calculations were performed to study the phase transitions in ${\mathrm{Rb}}_{2}$${\mathrm{ZnCl}}_{4}$, using intermolecular and intramolecular potentials generated from ab initio quantum-chemistry calculations for the whole molecular ion ${\…

Crystal Structures and PropertiesPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography

Metal-thiolate bonding properties: single-crystal ESR, susceptibility, and polarized absorption evidence for a strong .pi. interaction in tetrakis(thiophenolato)cobaltate(II)

Kouichi Fukui、Norimichi Kojima、Hiroaki Ohya‐Nishiguchi 等 4 位作者1992-04-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMetal-thiolate bonding properties: single-crystal ESR, susceptibility, and polarized absorption evidence for a strong .pi. interaction in tetrakis(thiophenolato)cobaltate(II)Kouichi Fukui, Norimichi Kojima, Hiroaki Ohya-Nishiguchi, and Noboru HirotaCite this: Inorg. Chem. 19…

Organic and Molecular Conductors ResearchSolid-state spectroscopy and crystallographyOrganometallic Compounds Synthesis and Characterization

In vivo Fate of Repeat-Unit-Radiolabelled Poly(β-malic acid), a Potential Drug Carrier

Philippe Fournié、Dominique Domurado、Philippe Guérin 等 6 位作者1992-04-01Journal of Bioactive and Compatible Polymers

In order to compare the fates of end-chain-radiolabelled and repeat-unit-radiolabelled poly(β-malic acid)s after intravenous injection in mice, repeat-unit 14 C-radiolabelling of this biodegradable water-soluble poly carboxylic acid polymer was achieved starting from 14 C-aspartic acid. The ac tivity of the resulting…

Nanoparticle-Based Drug DeliveryAdvanced Polymer Synthesis and CharacterizationLanthanide and Transition Metal Complexes

Accelerated aging of extruded dielectric power cables. II. Life testing of 15 kV XLPE-insulated cables

Bruce Bernstein、William A. Thue、M.D. Walton 等 4 位作者1992-04-01IEEE Transactions on Power Delivery

For pt.I see ibid., vol.7, no.2, p.596-602 (1992). Preliminary results are described in which 15 kV XLPE cables were subjected to accelerated aging tests under a variety of controlled voltage stress and thermal load cycle conditions, with loss of life being calculated for each set of conditions in terms of the geometr…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationElectrostatic Discharge in Electronics

A Practical Method for Characterizing Poured Beer Foam Quality

Marc Constant1992-04-01Journal of the American Society of Brewing Chemists

Many of the methods for measuring beer foam are based on measurements of the weight or volume of beer collapsed from foam rather than on measurements of the foam itself. However, these drainage methods may not reflect the consumer's perception of foam collapse. Therefore, a method to characterize numerous properties o…

Hydrology and Sediment Transport ProcessesHorticultural and Viticultural ResearchPickering emulsions and particle stabilization

Control of Grain‐Boundary Pinning in Al 2 O 3 /ZrO 2 Composites with Ce 3+ /Ce 4+ Doping

Liang Xue、Karsten Meyer、I‐Wei Chen1992-04-01Journal of the American Ceramic Society

The control of the microstructure of Ce‐doped Al 2 O 3 /ZrO 2 componsites by the valence change of cerium ion has been demonstrated. Two distinctively different types of microstructure, large Al 2 O 3 grains with intragranular ZrO 2 particles and small Al 2 O 3 grains with intergranular ZrO 2 particles, can be obtaine…

Advanced ceramic materials synthesisAdvanced materials and compositesNuclear materials and radiation effects

Exciplex formation between pyrene derivatives and N,N-dimethylaniline in Aerosol OT reversed micelles

Claudio D. Borsarelli、Juan J. Cosa、Carlos M. Previtali1992-04-01Langmuir

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTExciplex formation between pyrene derivatives and N,N-dimethylaniline in Aerosol OT reversed micellesClaudio D. Borsarelli, Juan J. Cosa, and Carlos M. PrevitaliCite this: Langmuir 1992, 8, 4, 1070–1075Publication Date (Print):April 1, 1992Publication History Published onlin…

Surfactants and Colloidal SystemsPorphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer Studies

Lithium-transition metal complexes derived from meso-octaethylporphyrinogen which display .sigma.- and .pi.-bonding modes

Jayne Jubb、Denis Jacoby、Carlo Floriani 等 5 位作者1992-04-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTLithium-transition metal complexes derived from meso-octaethylporphyrinogen which display .sigma.- and .pi.-bonding modesJayne Jubb, Denis Jacoby, Carlo Floriani, Angiola Chiesi-Villa, and Corrado RizzoliCite this: Inorg. Chem. 1992, 31, 7, 1306–1308Publication Date (Print):…

DNA and Nucleic Acid ChemistryMolecular Sensors and Ion DetectionPorphyrin and Phthalocyanine Chemistry

Electrostatic properties of 1-methyluracil from diffraction data

Wim T. Klooster、S. Swaminathan、Raymond G. Nanni 等 4 位作者1992-04-01Acta Crystallographica Section B Structural Science

1-Methyluracil (1-methyl-2,4-dioxopyrimidine), C5H6-N2O2, M(r) = 126.12, orthorhombic, Ibam, a = 13.188 (6), b = 13.175 (5), c = 6.214 (3) A, V = 1079.7 (8) A3, Z = 8, Dx = 1.552 g cm-3, lambda (Mo K alpha) = 0.7107 A, mu = 1.317 cm-1, F(000) = 528, T = 123 K, R(F2) = 0.068 for 2996 reflections with sin theta/lambda l…

Metal complexes synthesis and propertiesCrystal structures of chemical compoundsNonlinear Optical Materials Research

Aspects of modeling of high voltage ferroelectric nonlinear ceramic capacitors

Colin Campbell、J.D. van Wyk、M.F.K. Holm 等 4 位作者1992-04-01IEEE Transactions on Components Hybrids and Manufacturing Technology

Experimental and theoretical studies are reported on the room temperature capacitance-voltage (CV) and (tan delta )-V response of a high-voltage barium titanate ceramic disc capacitor with prescribed nonlinear CV response, as fabricated for an intended power electronics application. The CV response was modeled in term…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMagnetic Properties and Applications

Initiation of vinyl ether polymerization by trimethylsilyl triflate, dimethyl sulfide, and adventitious water

Chang Gi Cho、B. A. FEIT、Owen W. Webster1992-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInitiation of vinyl ether polymerization by trimethylsilyl triflate, dimethyl sulfide, and adventitious waterChang Gi Cho, Ben Ami Feit, and Owen W. WebsterCite this: Macromolecules 1992, 25, 8, 2081–2085Publication Date (Print):April 1, 1992Publication History Published onl…

Synthesis and properties of polymersSilicone and Siloxane ChemistryPhotopolymerization techniques and applications

Computer simulation studies of the dependence on density of the orientational order in nematic liquid crystals

J.W. Emsley、G. R. Luckhurst、William E. Palke 等 4 位作者1992-04-01Liquid Crystals

Simulations of the temperature dependence of the nematic orientational order parameter, [Pbar] 2, at different densities have been made using the Gay-Berne potential. The results are used to calculate Γ = −(∂In T/∂ IN V) [Pbar] 2, which is a measure of the relative sensitivity of [Pbar] 2 to temperature and density. P…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesNonlinear Dynamics and Pattern Formation

A Rolling Contact Fatigue Study of Hard Carbon Coated M-50 Steel

Ronghua Wei、Paul J. Wilbur、F.M. Kustas1992-04-01Journal of Tribology

Hard carbon coatings with diamond-like properties were applied on AISI M-50 steel rods which were subjected to rolling contact fatigue (RCF) testing at a cyclic Hertzian stress level of 5.5 GPa. The coatings were produced using a single, broad beam ion source that directed 450 eV ions, derived from a methane discharge…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchTribology and Wear Analysis

Modeling Boron Adsorption on Kaolinite

Shivi P. N. Singh、Shas V. Mattigod1992-04-01Clays and Clay Minerals

Abstract Boron adsorption at constant ionic strength [0.09 ± 0.01 moles/liter of KClO 4 or Ca(ClO 4 ) 2 ] on 0.2−2 μ m clay fraction of pretreated kaolinite was modeled using both phenomenological equations and surface complexation reactions. Phenomenological equations were expressed as linear relationships between th…

Radioactive element chemistry and processingClay minerals and soil interactionsIron oxide chemistry and applications

Surface Chemistry and Electrocatalytic Activity of the HER on Nickel Modified with Heteropolyacids

O. Savadogo1992-04-01Journal of The Electrochemical Society

Nickel was modified at the surface from dilute acid solution containing different concentrations of , , or . It was shown that improvement in the over potential (η)) and in the exchange current density of the hydrogen evolution reaction (HER) in 3 M on the electrode depends on the nature of the heteropolyacid of the m…

Electrocatalysts for Energy ConversionCorrosion Behavior and InhibitionGas Sensing Nanomaterials and Sensors