Materials Literature
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In prior studies, aqueous Hf sulfate-peroxide solutions were spin-coated, dehydrated, patterned by electron-beam lithography, ion-exchanged (OH(-) for SO4(2-)), and finally converted to HfO2 hard masks via annealing. The atomic-level details of the underlying aqueous chemistries of these processes are complex and yet…
Growth conditions, structural, and optical properties of MgO nanostructure have been investigated. Surface composition and shift in binding energy of Mg at 50.8 eV due to oxidation were examined by core‐level spectroscopy. The SEM showed that the film is dense, and grain growth and crystallinity are enhanced by post‐d…
The design of structurally well-defined anionic molecular metal-oxygen clusters, polyoxometalates (POMs), leads to inorganic receptors with unique and tunable properties. Herein, an α-Dawson-type silicotungstate, TBA8[α-Si2W18O62]⋅3 H2O (II) that possesses a -8 charge was successfully synthesized by dimerization of a…
Abstract Wavelength‐tunable light‐emitting diodes (LEDs) of Ga x Zn 1–x O nanowire arrays are demonstrated by a simple modified chemical vapor deposition heteroepitaxial growth on p‐GaN substrate. As a gallium atom has similar electronegativity and ion radius to a zinc atom, high‐level Ga‐doped Ga x Zn 1–x O nanowire…
Mixtures of block copolymers and lithium salts are promising candidates for lithium battery electrolytes. Structural changes that occur during the order-to-disorder transition (ODT) in a diblock copolymer/salt mixture were characterized by small-angle X-ray scattering (SAXS). In salt-free block copolymers, the ODT is…
In this work, we compared two methods (incipient wetness and melting) for the encapsulation of ibuprofen in the pores of Mobil Crystalline Material 41 (MCM-41) through NMR (nuclear magnetic resonance) spectroscopy. (1)H NMR spectra were recorded under very fast MAS (sample spinning 60 kHz) conditions in both 1D and 2D…
Abstract Large‐area α‐MnO 2 nanoflower arrays are synthesized by using a facile and template‐free electrochemical deposition on flexible graphite paper. These nanoflower arrays exhibit a high specific capacitance of 314 F g −1 at a current density of 1 A g −1 with remarkable rate capability (61.1 % retention at 40 A g…
Addressing the multitude of electronic phenomena theoretically predicted for confined graphene structures requires appropriate in situ fabrication procedures yielding graphene nanoflakes (GNFs) with well-defined geometries and accessible electronic properties. Here, we present a simple strategy to fabricate quasi-free…
High Resolution Image Download MS PowerPoint Slide The surface reactivity of Y 2 O 3, YSZ, and ZrO 2 polycrystalline powder samples toward H 2 has been comparatively studied by a pool of complementary experimental techniques, comprising volumetric methods (temperature-programmed volumetric adsorption/oxidation and the…
In scarcity of light and primary producers, subterranean ecosystems are generally extremely oligotrophic habitats, receiving poor supplies of degradable organic matter from the surface. Human direct impacts on cave ecosystems mainly derive from intensive tourism and recreational caving, causing important alterations t…
The phase behavior of colloids that interact via competing interactions - short-range attraction and long-range repulsion - is studied by computer simulation. In particular, for a fixed strength and range of repulsion, the effect of the strength of an attractive interaction (ε) on the phase behavior is investigated at…
Abstract In this research, the suitability of almond shell and coconut fiber as a renewable agricultural residue for the manufacturing of biocomposite to be used as a replacement of wood was investigated. The use of agriculture waste as a reinforcement in composite may result in several environmental and socioeconomic…
The salient feature of a supercapacitor is its ability to deliver much higher power density than a battery. A hierarchical design and a cost‐effective approach to fabricate high performance supercapacitors using functional carbon nano‐particles is reported. A special arc synthesis method is used to produce amorphous/c…
We have analyzed by density functional theory calculations the structural and magnetic properties of Fe-Co alloys doped by carbon. In analogy with the formation of martensite in steels we predict that such a structure also forms for Fe-Co alloys in a wide range of concentrations. These alloys are predicted to have a s…
Cellulose crystals (CC) were chemically derived from jute by alkali treatment, bleaching and subsequent hydrolysis with 40 % sulfuric acid. Infrared spectroscopy (FT-IR) suggested sufficient removal of lignin and hemicellulose from the raw jute and scanning electron microscopy (SEM), and X-ray diffraction (XRD) studie…
Their intrinsic properties render single quantum systems as ideal tools for quantum enhanced sensing and microscopy. As an additional benefit, their size is typically on an atomic scale that enables sensing with very high spatial resolution. Here, we report on utilizing a single nitrogen vacancy center in nanodiamond…
An amphiphilic composite with magnetic Fe3O4 core and dodecylamine-modified polyoxometalate-paired poly(ionic liquid) shell was synthesized and characterized by (1)H NMR, thermogravimetric analysis (TGA), vibrating sample magnetometry (VSM), transmission electron microscopy (TEM), scanning electron microscopy (SEM), F…
A facile method was developed for fabrication of a robust shape memory polymer by swelling cross-linked natural rubber with stearic acid. Commercial rubber bands were swollen in molten stearic acid at 75 °C (35 wt % stearic acid loading). When cooled the crystallization of the stearic acid formed a percolated network…
We report a new magic-sized gold nanocluster of atomic precision formulated as Au 64 (S- c -C 6 H 11 ) 32 . The Au 64 nanocluster was obtained in relatively high yield (∼15%, Au atom basis) by a two-step size-focusing methodology. Obtaining this new magic size through the previously established “size focusing” method…
Over the last ten years, the nematic phases of liquid crystals formed from bent-core structures have provoked considerable research because of their remarkable properties. This Minireview summarises some recent measurements of the physical properties of these systems, as well as describing some new data. We concentrat…