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The mechanism of formation of composite microarc coatings on aluminum alloys

A. G. Rakoch、A. A. Gladkova、В.Л. Ковалев 等 4 位作者2013-11-06Protection of Metals and Physical Chemistry of Surfaces

It is shown that heating of an internal layer of microarc coating up to temperatures at which insignificant rates of heat removal from microdischarges that possess a temperature of no less than 1200°C are ensured leads to realization of a sufficient time interval for the occurrence of almost 100% transformation of low…

Aluminum Alloys Composites PropertiesMaterial Properties and ApplicationsSurface Treatment and Coatings

Adsorption of dioctyl phosphate and inhibition of dissolution of low-carbon steel in neutral solution

A. A. Chirkunov、A. S. Gorbachev、Yu. I. Kuznetsov 等 4 位作者2013-11-06Protection of Metals and Physical Chemistry of Surfaces

The effects of temperature, exposure, and agitation of the solution on the passivating properties of sodium dioctyl phosphate are studied. It is found that passivation of steel in the presence of the salt can proceed without the formation of surface oxide.

Corrosion Behavior and InhibitionMetal Alloys Wear and PropertiesMaterial Properties and Failure Mechanisms

Preparation and properties of waterborne polyurethane/antimony doped tin oxide nanocomposite coatings via sol–gel reactions

Haifeng Zhou、Hua Wang、Xingyou Tian 等 5 位作者2013-11-06Polymer Composites

Various amounts of antimony doped tin oxide (ATO) nanoparticles were incorporated into waterborne polyurethane (WPU) dispersions by sol–gel reactions. The dispersion state and morphology investigated by transmission electron microscopy (TEM) and scanning electron microscopy (SEM) showed that the nanoparticles can disp…

Polymer composites and self-healingMarine Biology and Environmental ChemistrySilicone and Siloxane Chemistry

SAXS characterization of polymer-embedded hollow nanoparticles and of their shell porosity

Zhi Hong Chen、Sun Hye Hwang、Xiangbing Zeng 等 6 位作者2013-11-06Journal of Applied Crystallography

Size parameters of SiO 2 /TiO 2 hollow nanoparticles (HNPs) of 25–100 nm in diameter were characterized by small-angle X-ray scattering (SAXS). On the basis of the decoupling and the Percus–Yevick approximations, and using a hollow sphere model, size information on HNPs was extracted, including average outer diameter,…

Nanoparticle-Based Drug DeliveryMesoporous Materials and CatalysisX-ray Diffraction in Crystallography

Screening of the Relaxivity of Gadolinium‐Loaded Periodic Mesoporous Silica Functionalized by Means of Soft Metalorganic Silylamide Grafting

Hjørdis Skår、John Georg Seland、Yucang Liang 等 6 位作者2013-11-06European Journal of Inorganic Chemistry

Abstract Soft metalorganic grafting of periodic mesoporous silica (PMS) materials is introduced as a method for obtaining nanostructured Gd III ‐loaded silica particles with relatively high 1 H relaxivity. The silylamide complex Gd[N(SiHMe 2 ) 2 ] 3 (THF) 2 was grafted onto MCM‐41, SBA‐15, and SBA‐1, thereby providing…

Magnetism in coordination complexesMesoporous Materials and CatalysisLanthanide and Transition Metal Complexes

Thermal stability and flammability performance of polypropylene composites with silica pillared montmorillonites

Fei Zhu、Liu Deng、Guipeng Cai 等 7 位作者2013-11-06Polymers for Advanced Technologies

In present work, silica pillared montmorillonite material (C-SiO2-OMT) was prepared via the sol–gel method, and the influence of the powder on thermal stability and flammability performance of polypropylene (PP) composites was investigated. Characterization of C-SiO2-OMT, elucidated with X-ray diffraction, transmissio…

Polymer Nanocomposites and PropertiesFlame retardant materials and propertiesSynthesis and properties of polymers

Enzymatic formation of a novel cell-adhesive hydrogel based on small peptides with a laterally grafted l -3,4-dihydroxyphenylalanine group

Jiaxing Xu、Zhi Zhou、Bin Wu 等 4 位作者2013-11-06Nanoscale

We rationally designed a bioadhesive supramolecular hydrogel by introducing L-3,4-dihydroxylphenylalanine (DOPA) groups while properly integrating the enzymatic reactions and self-assembly processes. The effective presence of the catechol groups successfully promoted the adhesion and proliferation of human fibroblast…

Chemical Synthesis and AnalysisSupramolecular Self-Assembly in MaterialsSilk-based biomaterials and applications

Microsegregation effects on the thermal conductivity of silicon-germanium alloys

Yongjin Lee、Gyeong S. Hwang2013-11-06Journal of Applied Physics

A silicon-germanium (SiGe) alloy is a promising candidate for thermoelectric materials; while it shows a significantly reduced thermal conductivity (κ) as compared to pure Si and Ge, the κ values obtained from previous experiments and computations tend to be widely scattered. We present here a computational analysis o…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Fast quantitative analysis of strong uniaxial texture using a March–Dollase approach

E. Zolotoyabko2013-11-06Journal of Applied Crystallography

Interrelations between the degree of uniaxial preferred orientation and the intensities and widths of selected X-ray diffraction peaks are analyzed within the March–Dollase approach. Simple analytical expressions are developed which relate the degree of preferred orientation to the rocking curve width of the strongest…

Iron oxide chemistry and applicationsX-ray Diffraction in CrystallographyCrystallography and Radiation Phenomena

Analyzing diffuse scattering with supercomputers

Tara Michels-Clark、V. E. Lynch、Christina Hoffmann 等 7 位作者2013-11-06Journal of Applied Crystallography

Two new approaches to quantitatively analyze diffuse diffraction intensities from faulted layer stacking are reported. The parameters of a probability-based growth model are determined with two iterative global optimization methods: a genetic algorithm (GA) and particle swarm optimization (PSO). The results are compar…

Crystallography and molecular interactionsCrystallization and Solubility StudiesX-ray Diffraction in Crystallography

Resonant excited state absorption and relaxation mechanisms in Tb^3+-doped calcium aluminosilicate glasses: an investigation by thermal mirror spectroscopy

G. Bianchi、Vitor Santaella Zanuto、F. B. G. Astrath 等 12 位作者2013-11-06Optics Letters

Resonant excited state absorption (ESA) and relaxation processes in Tb(3+)-doped aluminosilicate glasses are quantitatively evaluated. A model describing the excitation steps and upconversion emission is developed and applied to interpret the results from laser-induced surface deformation using thermal mirror spectros…

Glass properties and applicationsPhotorefractive and Nonlinear OpticsSolid State Laser Technologies

Natural weathering studies of oil palm trunk lumber (OPTL) green polymer composites enhanced with oil palm shell (OPS) nanoparticles

Nazrul Islam、Rudi Dungani、H. P. S. Abdul Khalil 等 6 位作者2013-11-06SpringerPlus

In this study, a green composite was produced from Oil Palm Trunk Lumber (OPTL) by impregnating oil palm shell (OPS) nanoparticles with formaldehyde resin. The changes of physical, mechanical and morphological properties of the OPS nanoparticles impregnated OPTL as a result of natural weathering was investigated. The…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Influence of surface anchoring conditions on the dielectric and electro-optical properties of nematic droplets dispersed in a polymer network

Mourad Boussoualem、M. Ismaïli、Frédérick Roussel2013-11-06Soft Matter

Dielectric and electro-optical properties of liquid crystal (LC) dispersions exhibiting two different surface anchoring conditions at the polymer-LC interface are investigated. The confining surface was tuned by changing the side chains of the polymeric matrix in order to get either planar or homeotropic anchoring con…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsNonlinear Dynamics and Pattern Formation

Enhancing Proteasome-Inhibitor Effect by Functionalized Gold Nanoparticles

Sílvia Castro Coelho、Sandra Rocha、Maria do Carmo Pereira 等 5 位作者2013-11-06Journal of Biomedical Nanotechnology

Colloidal gold nanoparticles intensify the anticancer response of the drug bortezomib, a proteasome inhibitor. Polyethylene glycol-coated gold nanoparticles and the drug show a synergistic effect in reducing the cell viability of prostate cancer cell line Du145. It was observed a significant cell viability reduction w…

Nanoparticle-Based Drug Delivery

Sensitizing Cancer Cells to TRAIL-Induced Death by Micellar Delivery of Mitoxantrone

Taraka Sai Pavan Grandhi、Thrimoorthy Potta、David J. Taylor 等 7 位作者2013-11-06Nanomedicine

TNFα-related apoptosis-inducing ligand (TRAIL) induces death selectively in cancer cells. However, subpopulations of cancer cells are either resistant to or can develop resistance to TRAIL-induced death. As a result, strategies that overcome this resistance are currently under investigation. We have recently identifie…

Nanoparticle-Based Drug DeliveryCell death mechanisms and regulationRNA Interference and Gene Delivery

Improvement of toughness properties of polypropylene/wollastonite composites using an interface modifier

Homero Salas-Papayanopolos、Ana Beatriz Morales、Tomás Lozano 等 8 位作者2013-11-06Polymer Composites

The effects of type of processing of polypropylene (PP)/wollastonite composites on mechanical properties and dispersion state were investigated. The concentration in weight of the filler in the compounds was of 2.5%, 5%, and 10%, respectively. Stearic acid was used as an interface modifier for the PP–wollastonite syst…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

Systematic tuning of the conduction mechanisms in ferroelectric thin films

Delphin Levasseur、E. Bouyssou、Rosa De Paolis 等 8 位作者2013-11-06Journal of Physics Condensed Matter

We have investigated the macroscopic and microscopic properties of large sets of Ba0.7Sr0.3TiO3 thin films including several substitution rates of manganese. Thanks to a high degree of control of the processing parameters at each stage we have been able to find a link between the dc leakage current and the low and hig…

Ferroelectric and Piezoelectric MaterialsElectronic and Structural Properties of OxidesDielectric properties of ceramics

Poly(lactic acid)‐based systems filled with talc microparticles: Thermal, structural, and morphological issues

Pietro Russo、Domenico Acierno、Adriano Vignali 等 4 位作者2013-11-06Polymer Composites

Polylactic acid (PLA)‐based composites containing 1, 3, and 5% by weight of talc microparticles were prepared by extrusion and characterized in terms of thermal, structural, and morphological issues. The binary materials were then compared with ternary systems including 5% by weight of a secondary poly(ε‐caprolactone)…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionCarbon dioxide utilization in catalysis

Indigenously produced polyhydroxyalkanoate based co‐polymer as cellular supportive biomaterial

A. Shabna、V. Saranya、J. Malathi 等 5 位作者2013-11-06Journal of Biomedical Materials Research Part A

The focus of this study was to evaluate the growth of the cells on a scaffold based on novel polyhydroxyalkanoate (PHA) (Polyhydroxy propionate copoly hydroxy ocatadecanoate copolymer), derived from a mutant strain of Pseudomonas sp. Naive PHA was also blended with several biodegradable polymeric materials (PEG, PLA,…

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and propertiesGraphene and Nanomaterials Applications

A Ternary Conjugation System for the Construction of DNA Libraries forGeobacillus kaustophilusHTA426

Hirokazu Suzuki、Keisuke Wada、Megumi Furukawa 等 5 位作者2013-11-06Bioscience Biotechnology and Biochemistry

This report describes efficient plasmid uptake by the thermophile Geobacillus kaustophilus HTA426 by means of a ternary conjugation system, which was used to construct thermophile DNA libraries for G. kaustophilus and to identify the genes for orotidine-5'-phosphate decarboxylase by in vivo functional screening. The r…

Bacterial Genetics and BiotechnologyMicrobial Metabolic Engineering and BioproductionEnzyme Structure and Function