The magnetic properties of transition metal ions in asymmetric ligand fields. Part 3.—The behaviour of some t52g complexes
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602. The magnetic properties of some d 3-complexes
B. N. Figgis, J. Lewis and F. E. Mabbs, J. Chem. Soc., 1961, 3138 DOI: 10.1039/JR9610003138
REACTION BETWEEN SILICA AND CALCIUM HYDROXIDE SOLUTIONS. I. KINETICS IN THE TEMPERATURE RANGE 30 TO 85°1
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTREACTION BETWEEN SILICA AND CALCIUM HYDROXIDE SOLUTIONS. I. KINETICS IN THE TEMPERATURE RANGE 30 TO 85°1S. A. GreenbergCite this: J. Phys. Chem. 1961, 65, 1, 12–16Publication Date (Print):January 1, 1961Publication History Published online1 May 2002Published inissue 1 Januar…
Thermoelectric Properties of Ag2Te
The Seebeck coefficient α, electrical conductivity σ, and thermal conductivity K data are given for a number of Ag2Te specimens measured at room temperature. The maximum value observed for the figure of merit α2σ/K was 1.3×10−3°C−1. The relationship between K and σ was linear, and Kel could be expressed approximately…
Electrochemical Behavior of the Magnesium Anode
The anodic transient behavior of magnesium in aqueous environments is studied under controlled conditions. The steady‐state behavior as reported by other investigators is reviewed, and pertinent additional observations are reported. A unified explanation of the aqueous electrochemical behavior of magnesium based on th…
601. The magnetic properties of some d 4-complexes
The first page of this article is displayed as the abstract.
726. Phosphine oxide complexes. Part V. Tetrahedral complexes of manganese(II) containing triphenylphosphine oxide, and triphenylarsine oxide as ligands
D. M. L. Goodgame and F. A. Cotton, J. Chem. Soc., 1961, 3735 DOI: 10.1039/JR9610003735
51. Alkyls and aryls of transition metals. Part IV. Cobalt(II) and iron(II) derivatives
J. Chatt and B. L. Shaw, J. Chem. Soc., 1961, 285 DOI: 10.1039/JR9610000285
Thermal Stability as a Function of Chemical Structure.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermal Stability as a Function of Chemical Structure.E.S. Blake, W.C. Hammann, James W. Edwards, T.E. Reichard, and M. R. OrtCite this: J. Chem. Eng. Data 1961, 6, 1, 87–98Publication Date (Print):January 1, 1961Publication History Published online1 May 2002Published inissu…
CHARACTERISTIC VIBRATIONS OF THE SULPHURYL GROUP
A compilation of the S—O symmetric and asymmetric stretching frequencies is given for a large number of compounds containing an —SO 2 — group. It is shown that a linear relationship between [Formula: see text] is valid for a large number of sulphuryl and polysulphuryl compounds and that the actual frequencies depend i…
X-Ray Studies on Solid Solutions of Oxygen in a-Zirconium.
ABS>The solubility of oxygen in alpha -zirconium in the temperature region, 400-800 deg C, was investigated by x-ray methods. The solubility, which is independent of temperature, is 28.6 at.% (ZrO/sub 0.4//sub 0/). With increasing oxygen content, the length of the c axis increases over the entire solubility range whil…
Instability Constants of Complex Compounds.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInstability Constants of Complex Compounds.F. BasoloCite this: J. Am. Chem. Soc. 1961, 83, 2, 507Publication Date (Print):January 1, 1961Publication History Published online1 May 2002Published inissue 1 January 1961https://pubs.acs.org/doi/10.1021/ja01463a075https://doi.org/…
Diffusion Coefficients of Helium in Fused Quartz
The diffusion of helium through the walls of high-purity fused quartz hollow cylinders was studied using a mass spectrometer as a detecting device. By surrounding the outside of the hollow cylinder with helium and observing it diffuse through into the mass spectrometer, permeation rates and diffusion coefficients were…
874. High-temperature studies of the system calcium oxide–phosphorus pentoxide
J. H. Welch and W. Gutt, J. Chem. Soc., 1961, 4442 DOI: 10.1039/JR9610004442
ESTERIFICATION OF THE SURFACE OF AMORPHOUS SILICA
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTESTERIFICATION OF THE SURFACE OF AMORPHOUS SILICAC. C. Ballard, E. C. Broge, R. K. Iler, D. S. St. John, and J. R. McWhorterCite this: J. Phys. Chem. 1961, 65, 1, 20–25Publication Date (Print):January 1, 1961Publication History Published online1 May 2002Published inissue 1 J…
Devitrification of Natural Glass
Many aspects of the history of natural glasses are related to the physicochemical properties of silicate melts. Glasses are thermodynamically unstable; with time and under a variety of conditions, they become crystalline. When little water is present, devitrification may be described in much the same terms as those wh…
Chemical reactivity of polyethylene terephthalate. Hydrolysis and esterification reactions in the solid phase
D. A. S. Ravens and I. M. Ward, Trans. Faraday Soc., 1961, 57, 150 DOI: 10.1039/TF9615700150
Passivity and Corrosion Resistance of Titanium and Its Alloys
A brief review is given of possible ways to increase corrosion resistance of titanium in acids proceeding from analysis of its electrochemical characteristics and passive state stability. Rational ways of alloying titanium for acid resistance are indicated. Experiments include titanium alloys with palladium, chromium,…
Soviet Electrochemistry
Abstract not Available.
Note on a Phase Transition in VO2.
The powder diffractogram of vanadium dioxide crystals was found to change, rapidly and reversibly, at about 70 deg C, the most obvious feature being the disappearance of all reflections hkl with h odd. At 180 deg C the effect was even greater and the crystal structure was derived and found to be essentially of the rut…