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The infrared spectra of the anhydrous rare-earth nitrates are presented in the region 4000–100 cm−1. Strong coordination of the nitrate groups to the metal atom occurs. Possible different types of metal—oxygen bonding in these compounds is discussed.
Infrared-active lattice vibrational spectra of α-Al2O3 and Cr2O3 have been investigated by reflection and transmission measurements on single crystal samples and also by transmission on Nujol mulled Cr2O3. Single-crystal transmission data above 700 cm−1 have been assigned to combinations and overtones.
Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation E. H. Nicollian, A. Goetzberger; MOS CONDUCTANCE TECHNIQUE FOR MEASURING SURFACE STATE PARAMETERS…
Received 16 September 1965DOI:https://doi.org/10.1103/PhysRevLett.15.621©1965 American Physical Society
The transport properties of electrons in CdS grown with Group I impurities which show the phenomenon of "storage" have been studied to determine the mechanism of conduction. The mobility parallel to the $c$ axis at low temperature is of the order of 1 to 10 ${\mathrm{cm}}^{2}$/ volt sec and is very anisotropic, the mo…
Nuclear magnetic double-resonance experiments were performed on a gaseous sample containing a mixture of HD and C${\mathrm{O}}_{2}$ at high pressure by observing the spin-spin multiplet in the proton-resonance spectrum and irradiating either the deuteron transitions or some of the proton transitions. The spectra show…
The Hall coefficient and electrical resistivity have been measured on single-crystal specimens of $n$-type Sn${\mathrm{O}}_{2}$ between 80 and 900\ifmmode^\circ\else\textdegree\fi{}K. Data were obtained on samples in the "as grown" state, as well as on crystals which were thermally equilibrated in oxygen. A single-don…
Using symmetry arguments, the effective-mass Hamiltonian including spin-orbit interaction is derived for energy bands with extrema near the vertical edge of the hexagonal prism which represents the Brillouin zone of graphite. The energy bands in the plane normal to the vertical edge are described by k\ifmmode\cdot\els…
The edge-recombination-radiation spectrum from natural semiconducting diamond has been re-examined and compared with spectra obtained for the first time from aluminum and nominally boron-doped General Electric synthetic diamond. The intrinsic components are due to the phonon-assisted decay of free indirect excitons of…
Optical absorption and photoconductivity have been observed in the ultraviolet in single crystals of nominally pure $\ensuremath{\beta}\ensuremath{-}{\mathrm{Ga}}_{2}{\mathrm{O}}_{3}$. At room temperature a steep absorption edge, characteristic of a band-to-band transition, is observed at 2700 \AA{}. The edge is shift…
Experience with stainless-steel-clad fuel rods irradiated in the Vallecitos Boiling Water Reactor (VBWR) has shown that Type-304 stainless steel is susceptible to stress-assisted intergranular corrosion attack. Failure of over 40 fuel rods clad with this material occurred during irradiation of 950 fuel rods of several…
The relation between the grain size, the density and the sintering conditions for polycrystalline nickel ferrite has been studied for specimens prepared by a conventional ceramic technique. The contribution to the ferrimagnetic resonance linewidth due to the pores within the ferrite is considered and it is shown that…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Heats of Formation and Polymerization of Carbon SuboxideB. D. Kybett, G. K. Johnson, C. K. Barker, and J. L. MargraveCite this: J. Phys. Chem. 1965, 69, 10, 3603–3606Publication Date (Print):October 1, 1965Publication History Published online1 May 2002Published inissue 1…
Abstract The effect of various environmental conditions, other than chemical, on the mechanical properties of amorphous polymers is considered. The response of such polymers to an applied stress or strain depends on the mobility of polymeric chains which in turn is largely a function of free volume. The free volume va…
In current technology, the edge definition that can be achieved by the photoresist process is approximately ten times sharper than the registration accuracy that can be maintained over a workpiece of any reasonable size. A description is presented of an attempt to improve registration through feedback from the workpie…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTVapor-Liquid Equilibria of the System Acrylonitrile-Acetonitrile-Water.D. S. Blackford and Robert YorkCite this: J. Chem. Eng. Data 1965, 10, 4, 313–318Publication Date (Print):October 1, 1965Publication History Published online1 May 2002Published inissue 1 October 1965https…
Stress relaxation in rubber stocks containing various fillers was measured at room temperature, and an empirical equation found for relating decrease in tension, ft, over a period of time from 0.1 sec. to 6 months, namely: where f1.0 is force after 1 min. of relaxation, n is the relaxation rate of material (by definit…
Uniaxial tensile data from tests at different rates of extension over a wide temperature range are considered for butyl, silicone, Viton B, SBR, and natural rubber vulcanizates (series A) and for six Viton A-HV vulcanizates (series B) of differing crosslink densities. For series A and for A-6 in series B, equilibrium…
Measurements of the thermal conductivity of plastically deformed CaF2 and LiF between 1.3° and 80°K indicate the presence of a phonon scattering mechanism which does not display the frequency dependence normally associated with dislocations. Instead of a reciprocal relaxation time τ−1∝ω, which is characteristic of sca…
It is generally assumed, that in solids the diffusion of gas is modified through traps, which capture the gas atoms for a certain length of time. Taking into account this trapping with constant absorption- and emission-probability the diffusion from a sphere was calculated numerically by HURST. In the present paper th…