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Synthesis of polymers containing pseudohalide groups by cationic polymerization, 1. Homopolymerization of 3,3‐bis(azidomethyl)oxetane and its copolymerization with 3‐chloromethyl‐3‐(2,5,8‐trioxadecyl)oxetane

Hervé Cheradame、Jean‐Pierre Andreolety、Eliane Rousset1991-04-01Die Makromolekulare Chemie

Abstract The cationic polymerization of 3,3‐bis(azidomethyl)oxetane (BAMO) was compared with the polymerization of 3,3‐bis(chloromethyl)oxetane (BCMO). The initiating system, boron trifluoride diethyl etherate/diethylene glycol (system. name: 2,2′‐oxydiethanol) was used and it was shown that unusually high concentrati…

Lanthanide and Transition Metal ComplexesThermal and Kinetic AnalysisChemical Reactions and Mechanisms

Grating coupling to surface plasma waves I First-order coupling

Saleem H. Zaidi、M. Yousaf、S. R. J. Brueck1991-04-01Journal of the Optical Society of America B

A systematic experimental and theoretical study of first-order grating coupling to surface plasma waves existing at an air–Ag interface is presented. The experiment extends beyond previous work to grating depths comparable with the grating period. The grating profiles range from sinusoidal to rectangular. For TM-polar…

Plasma Diagnostics and ApplicationsOptical Coatings and GratingsMagneto-Optical Properties and Applications

Durability of Zirconium‐Containing Ceramic Waste Forms in Water

Hiroshi Kamizono、I. Hayakawa、S. Muraoka1991-04-01Journal of the American Ceramic Society

The durability of three ceramic waste forms containing Zr as a constituent is examined at 90° and 150°C in HCl or deionized water. The three ceramic waste forms examined are: (A) 10‐mol%‐Y 2 O 3 ‐stabilized ZrO 2 , (B) La 2 Zr 2 O 7 with a pyrochlore structure, and (C) CaZrO 3 with a perovskite structure. Each form co…

Radioactive element chemistry and processingNuclear Materials and PropertiesNuclear materials and radiation effects

REDUCTION IN THREAD STRENGTH AS A CAUSE OF LOADING IN THE SEWING PROCESS

Jelka Geršak、Blaž Knez1991-04-01International Journal of Clothing Science and Technology

Discusses reduction of thread strength as a cause of loading in sewing. Investigates measurements of dynamic loads of the thread during seam formation and reduction of thread strength after loading in sewing. Analysis of results shows that the reduction in thread strength after loading in sewing is a function of dynam…

Textile materials and evaluations

Sequence distribution and its effect on glass transition temperatures of poly(anhydride-co-imides) containing asymmetric monomers

Andrea Staubli、Edith Mathiowitz、Robert Langer1991-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSequence distribution and its effect on glass transition temperatures of poly(anhydride-co-imides) containing asymmetric monomersAndrea Staubli, Edith Mathiowitz, and Robert LangerCite this: Macromolecules 1991, 24, 9, 2291–2298Publication Date (Print):April 29, 1991Publicat…

Flame retardant materials and propertiesSynthesis and properties of polymersMaterial Properties and Applications

Is Au6 a circular ring?

K. Balasubramanian、Dai‐Wei Liao1991-04-01The Journal of Chemical Physics

Complete active space multiconfiguration self-consistent field followed by higher-order configuration interaction calculations reveal that the ground state of Au6 is of 1A1 symmetry with a capped pentagonal structure. Similar calculations on Au−6 are also made. The 1A1g state of the neutral Au6 with a ring structure (…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceNanocluster Synthesis and Applications

Syntheses, characterization, and reactivity of manganese and rhenium dioxime complexes. X-ray crystal structure of MnII(CDO)(CDOH)2(BPh(OCH3))2, an unusual pseudoclathrochelate complex, and ReIIICl(CDO)(CDOH)2BPh

Silvia S. Jurisson、Lynn C. Francesconi、Karen E. Linder 等 7 位作者1991-04-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSyntheses, characterization, and reactivity of manganese and rhenium dioxime complexes. X-ray crystal structure of MnII(CDO)(CDOH)2(BPh(OCH3))2, an unusual pseudoclathrochelate complex, and ReIIICl(CDO)(CDOH)2BPhS. Jurisson, L. Francesconi, K. E. Linder, E. Treher, M. F. Mal…

Metal-Organic Frameworks: Synthesis and ApplicationsCorrosion Behavior and InhibitionExtraction and Separation Processes

Organometallic oxides: preparation and properties of the tetrahedral (Td) chromium cubane [(.eta.-C5(CH3)5)Cr(.mu.3-O)]4 and comparison with the D2 [(.eta.-C5H5)Cr(.mu.3-O)]4 and D2d [(.eta.-C5H4CH3)Cr(.mu.3-O)]4

Frank Bottomley、Jinhua Chen、Sarajane M. MacIntosh 等 4 位作者1991-04-01Organometallics

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOrganometallic oxides: preparation and properties of the tetrahedral (Td) chromium cubane [(.eta.-C5(CH3)5)Cr(.mu.3-O)]4 and comparison with the D2 [(.eta.-C5H5)Cr(.mu.3-O)]4 and D2d [(.eta.-C5H4CH3)Cr(.mu.3-O)]4Frank Bottomley, Jinhua Chen, Sarajane M. MacIntosh, and Robert…

Organometallic Complex Synthesis and CatalysisMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexes

Characterization of adsorbed 2-vinylpyridine/styrene diblock copolymers on silver surfaces using surface-enhanced Raman scattering

W. H. Tsai、F. J. Boerio、S J Clarson 等 5 位作者1991-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCharacterization of adsorbed 2-vinylpyridine/styrene diblock copolymers on silver surfaces using surface-enhanced Raman scatteringW. H. Tsai, F. J. Boerio, S. J. Clarson, E. E. Parsonage, and M. TirrellCite this: Macromolecules 1991, 24, 9, 2538–2545Publication Date (Print):…

Gold and Silver Nanoparticles Synthesis and Applications

N-Alkylation and Hofmann elimination from thermal decomposition of R4N+ salts of aromatic polyamide polyanions: synthesis and stereochemistry of N-alkylated aromatic polyamides

Robert R. Burch、Lewis E. Manring1991-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTN-Alkylation and Hofmann elimination from thermal decomposition of R4N+ salts of aromatic polyamide polyanions: synthesis and stereochemistry of N-alkylated aromatic polyamidesRobert R. Burch and Lewis E. ManringCite this: Macromolecules 1991, 24, 8, 1731–1735Publication Dat…

Fiber-reinforced polymer compositesSynthesis and properties of polymersThermal and Kinetic Analysis

Intergranular corrosion of copper and α-Cu-Al alloy bicrystals

Masato Yamashita、T. Mimaki、Satoshi Hashimoto 等 4 位作者1991-04-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

Intergranular corrosion in copper bicrystals with symmetrical [110] tilt boundaries and in Cu-9 at.% Al alloy bicrystals with symmetrical [110] and [100] tilt boundaries was investigated by examining the depths of corrosion grooves developed at the boundaries after an immersion test in acid solutions (modified Livings…

Microstructure and mechanical propertiesCorrosion Behavior and InhibitionAluminum Alloy Microstructure Properties

Pulse sharpening in a uniform LC ladder network containing nonlinear ferroelectric capacitors

C.R. Wilson、M. M. Turner、Paul W. Smith1991-04-01IEEE Transactions on Electron Devices

A new method of pulse sharpening is described in which the risetime of a high-voltage pulse is progressively reduced as it propagates along a uniform lumped-element delay line containing nonlinear ferroelectric capacitors. The capacitors are made from a barium-titanate-based ceramic dielectric whose relative permittiv…

High voltage insulation and dielectric phenomenaPulsed Power Technology ApplicationsElectrostatic Discharge in Electronics

High‐Temperature Toughness and Tensile Strength of Whisker‐Reinforced Silicon Nitride

Tatsuki Ohji、Yasuhiro Gotô、Akihiko Tsuge1991-04-01Journal of the American Ceramic Society

The R ‐curve behavior of hot‐pressed silicon nitride reinforced with silicon carbide whiskers is investigated from room temperature to 1300°C using the chevron‐notch bend test. The bridging stress, estimated from increment of fracture resistance in the rising R ‐curve, is discussed in relation to tensile strength meas…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsAdvanced Surface Polishing Techniques

Thiol protease‐like active site found in the enzyme dienelactone hydrolase: Localization using biochemical, genetic, and structural tools

Dushyant Pathak、Gary W. Ashley、David L. Ollis1991-04-01Proteins Structure Function and Bioinformatics

The active site of dienelactone hydrolase (DLH), a microbial enzyme of the beta-ketoadipate pathway, has been conclusively located using a combination of crystallographic, biochemical, and genetic techniques. DLH hydrolyzes a dienelactone to maleylacetate and has esterase activity on p-nitrophenyl acetate and trans-ci…

Enzyme Catalysis and ImmobilizationEnzyme Structure and FunctionVitamin K Research Studies

ESR and Magnetic Susceptibility Studies on High-Spin Tetrahedral Cobalt(II)–Thiolate Complexes: An Approach to Rubredoxin-Type Active Sites

Kouichi Fukui、Hiroaki Ohya‐Nishiguchi、Noboru Hirota1991-04-01Bulletin of the Chemical Society of Japan

Abstract Magnetic susceptibility and ESR studies on high-spin (S=3⁄2) tetrahedral cobalt(II)–thiolate complexes were performed for A2[Co(SPh)4]; A=Me4N (1a), Et4N (1b), Ph4P (1c) and (Et4N)2[Co(SR)4]; R=C6H4-p-Me (2), C6H4-p-Cl (3), C6F5 (4). It was found that the magnitude of zero-field splitting and the anisotropy o…

Metal complexes synthesis and propertiesMagnetism in coordination complexesOrganic and Molecular Conductors Research

Study of oxidation-state contrast in gallium dichloride by synchrotron X-ray anomalous scattering

Angus P. Wilkinson、Anthony K. Cheetham、D. E. Cox1991-04-01Acta Crystallographica Section B Structural Science

Demonstration de la possibilite d'observer une difference dans les courbes f'(E) pour deux etats d'oxydation differents d'un element dans un compose de valence mixte, a proximite d'un seuil d'absorption approprie. Cette methode a l'avantage de fournir des informations, en etant selective sur le site

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesX-ray Diffraction in Crystallography

Dielectric nonlinearity and spontaneous polarization ofKTa1−xNbxO3in the diffuse transition range

J. Toulouse、X. M. Wang、L.A. Knauss 等 4 位作者1991-04-01Physical review. B, Condensed matter

${\mathrm{KTa}}_{1\mathrm{\ensuremath{-}}\mathit{x}}$${\mathrm{Nb}}_{\mathit{x}}$${\mathrm{O}}_{3}$ (KTN) in an intermediate-concentration range (x=15.7%) has been studied using dielectric-constant and spontaneous-polarization measurements. A large peak in the dielectric constant (${\mathrm{\ensuremath{\epsilon}}}_{\m…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Experimental and theoretical study of near-infrared absorbing naphthoquinone methide dyes with a nonplanar geometry

Yuji Kubo、Katsuhira Yoshida、Masafumi Adachi 等 5 位作者1991-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTExperimental and theoretical study of near-infrared absorbing naphthoquinone methide dyes with a nonplanar geometryYuji Kubo, Katsuhira Yoshida, Masafumi Adachi, Shinichiro Nakamura, and Shuichi MaedaCite this: J. Am. Chem. Soc. 1991, 113, 8, 2868–2873Publication Date (Print…

Dyeing and Modifying Textile FibersPhotochromic and Fluorescence ChemistrySynthesis of Indole Derivatives

PALATAL PRESSURE PATTERNS OF GELATIN GELS IN THE MOUTH

Junko Takahashi、Fumiko Nakazawa1991-04-01Journal of Texture Studies

ABSTRACT Palatal pressures of gelatin gel at various concentrations were detected by pressure transducers set at three locations in the palate. The following parameters were derived from the palatal pressure patterns: P, mean of palatal pressure from the beginning of eating to the end of swallowing; S, the last pulse…

Meat and Animal Product QualityLaser Applications in Dentistry and MedicineCollagen: Extraction and Characterization

Evaluation of Milkweed Floss as an Insulative Fill Material

Patricia Cox Crews、Shiela A. Sievert、Lisa T. Woeppel 等 4 位作者1991-04-01Textile Research Journal

Milkweed, a perennial plant that can adapt to adverse soil conditions, is being developed as an alternative crop. Fiber characterization and potential market iden tification are critical to its development. The most promising commercial use for milkweed floss is as a loose fill for jackets and comforters. The purpose…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesInnovations in Concrete and Construction Materials