Materials Literature
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Abstract Interlanthanide perovskites CeTmO 3 , CeYbO 3 , CeLuO 3 , PrYbO 3 , PrLuO 3 , and Ce Ln O 3 solid solutions have been prepared by cofusion techniques. Thermal stability and the optical properties of these materials have been investigated. A very important nephelauxetic effect ( ΔE = 3600 cm −1 ) is observed.…
Extensive experimental comparisons of calorimetric and ionometric measurements have been made that cover a broader range of electron energies and depths in graphite than previously reported. Electron beams of 15, 20, 25, 30, 40, and 50 MeV were used. Calorimetric absorbed-dose measurements and ionometric specific-char…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTComplexation of tetra-.mu.-carboxylato-dirhodium(II) with imidazoleK. Das and J. L. BearCite this: Inorg. Chem. 1976, 15, 9, 2093–2095Publication Date (Print):September 1, 1976Publication History Published online1 May 2002Published inissue 1 September 1976https://pubs.acs.or…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA symmetrical diazaditwistane. 2,9-Dicyano-5,11-dimethyl-5,11-diazatetracyclo[6.2.2.02,7.04,9]dodecaneJan Ten Broeke, Alan W. Douglas, and Edward J. J. GrabowskiCite this: J. Org. Chem. 1976, 41, 19, 3159–3163Publication Date (Print):September 1, 1976Publication History Publ…
Abstract The EPR spectra of three different Cu 2+ centres and the spectrum of the radiation hole centre in single crystals of anatase are investigated. The constants of the spin‐Hamiltonians for all the spectra and the ground state wave functions are obtained. The conditions of incorporation into the crystal, the site…
Abstract The characteristic ferroelectric dispersion of the complex dielectric constant of AgNa(NO 2 ) 2 is measured in a wide temperature range enclosing the transition point. It can be well described by a Debye monodispersive process except for a small temperature intervall around T c . The relaxation strength obeys…
All single phase regions (compounds and solid solutions) in the system were activated with 0.01 mole percent (m/o) Ce 3+ (with equimolar amounts of Li + , Na + , or K + added to compensate charges) and the resulting ultraviolet excitation and emission spectra were characterized. Brightest phosphors were obtained from…
Methods are presented for facilitating the calculation of even moments 〈R2p〉 of the end to end vector R and for the inference of the probability distribution in the absence of excluded volume effects. The gain in efficiency of moment calculations is several hundredfold for the first 10 moments, 0⩽p⩽10. The proposed in…
In order to close the system of differential field equations developed in Paper I, this article proposes a rational development of the relevant macroscopic thermodynamics and of a constitutive theory. In particular, by following Coleman’s thermodynamics, exact nonlinear constitutive equations for thermoelastic antifer…
Specimens of polycrystalline UO2 were strained in compression at constant strain rate from 0.05 to 10.0/min and at temperatures ranging 900°–2,000°C. The experimental results revealed characteristic yield point, and the yield stress varied with strain rate and temperature. The present data, obtained at strain rates hi…
Abstract The thermal degradation of poly(oxycarbonylpentamethylene), (poly‐ε‐caprolactone), ( 3 ), was investigated at 220°C and 80 mm Hg under nitrogen. 3 was found to be thermally much more stable than poly(oxycarbonylethylene), (poly‐β‐propiolactone), ( 1 ), although it decomposed faster than poly(oxycarbonyl‐1,1‐d…
It has been shown that noncrystalline Ge-sputtered films prepared under a range of conditions display a wide variation in structure, composition, and film properties depending on the sputtering process parameters. Data are presented in which optical absorption edge, stress, density, argon and oxygen contents, and othe…
Bifurcation buckling of oval cylindrical shells under the interaction of uniform compressive forces and bending moments of arbitrary orientation is investigated. Buckling loads as well as the asymmetric buckling modes are determined by a matrix interative solution aided by a sequence of successive approximate solution…
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Optically anisotropic glasses were obtained by the uniaxial stretching of phase‐separated borosilicate glasses in the transformation temperature range. The sign inversion of the birefringence, induced by subsequent heat treatments, was correlated with microstructure. The positive birefringence is attributed to form bi…
Abstract We have developed an empirical correlation between the loss tangent (tan δ) and the product of the volume fraction (ϕ) of carbon black in the composite and the total filler-polymer interfacial area per unit volume of composite (ψ). This correlation was applied to vulcanizates based on SBR-1500, SBR-1712, and…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAnisotropic exchange and temperature-dependent electron paramagnetic resonance line width in one-dimensional copper(II) complexes. 2. Magnetic properties of copper(II) oxalate-1/3-waterKenneth T. McGregor and Zoltan G. SoosCite this: Inorg. Chem. 1976, 15, 9, 2159–2165Public…
Abstract not Available.
Abstract The iron chelating ability of hydroxamic acid polymers was studied as a function of the atomic chain spacing separating neighboring hydroxamic acid units. Two polymers were prepared, one having the hydroxamic acid group separated by 11 atoms and the other by three atoms. The iron binding of these polymers was…
In order to explain experimental observations on amorphous arsenic chalcogenides, it has recently been proposed that these compounds contain a high density of dangling bonds with rather special properties. However, chemical considerations raise doubts as to the plausibility of this model, which also does not readily a…