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Effect of deuteration, oxidation, and hydrogen-bonding on the infrared spectrum of cellulose

John W. Rowen、Earle K. Plyler1950-03-01Journal of research of the National Bureau of Standards

Regenerated cellulose film s were immersed in heavy water (99 .58 % D 20 ) at temperatures up t o 52 C for a s long as 100 hours in an attempt to effect a substitution of D for the H in the OH groups of the ccllulose. The intensity of the OH vibration in t he 3-micron region of the spectrum of t he films decreased ver…

Advanced Cellulose Research StudiesBiofuel production and bioconversion

Über das Schmelz‐ und Erstarrungsbild des doppelt‐ternären Systemes (K2 · Na2 · Mg)(Cl2 · SO4)

Ernst Jänecke1950-03-01Zeitschrift für anorganische Chemie

Abstract Das System der doppelt‐ternären Salzgemische (K 2 · Na 2 · Mg) (Cl 2 · SO 4 ) im Gleichgewicht der möglichen Salze mit Schmelze stellt das Grenzsystem der wässerigen Salzlösung dar, wobei also Schmelze ohne Wasser an dem Auftreten von Flüssigem beteiligt ist. Das Zustandsbild ist, wie vom Verfasser vor Jahren…

Chemical Synthesis and CharacterizationSolid-state spectroscopy and crystallography

TNT INTO PHLOROGLUCINOL

M. L. Kastens、Julius F. Kaplan1950-03-01Industrial & Engineering Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTNT INTO PHLOROGLUCINOLM. L. Kastens and Julius F. KaplanCite this: Ind. Eng. Chem. 1950, 42, 3, 402–413Publication Date (Print):March 1, 1950Publication History Published online1 May 2002Published inissue 1 March 1950https://pubs.acs.org/doi/10.1021/ie50483a009https://doi.o…

Lanthanide and Transition Metal Complexes

The Vibrational Spectra of Molecules and Complex Ions in Crystals IV. Ammonium Bromide and Deutero-Ammonium Bromide

E. L. Wagner、D. F. Hornig1950-03-01The Journal of Chemical Physics

The infra-red spectra of thin non-scattering films of NH4Br and ND4Br were obtained at 28°C, −78°C and −190°C. The spectra of both compounds in Phase III are in agreement with the x-ray symmetry, D4h7. The torsional oscillation frequencies occur at 319 cm−1 and 230 cm−1 in NH4Br and ND4Br, respectively. The spectra of…

Solid-state spectroscopy and crystallographyLanthanide and Transition Metal ComplexesChemical Thermodynamics and Molecular Structure

The Vibrational Spectra of Molecules and Complex Ions in Crystals III. Ammonium Chloride and Deutero-Ammonium Chloride

E. L. Wagner、D. F. Hornig1950-03-01The Journal of Chemical Physics

The infra-red spectra of thin non-scattering films of NH4Cl and ND4Cl were obtained at 28°, −78° and −190°C. A convenient low temperature transmission type cell usable for such films is described. No indication of fine structure due to free rotation of the NH4+ ions was found. Instead, evidence is presented for the ex…

Molecular Spectroscopy and StructureMolecular spectroscopy and chiralitySolid-state spectroscopy and crystallography

Observations on the Thermal Expansion of Crystalline and Glassy Substances

F. A. Hummel1950-03-01Journal of the American Ceramic Society

The importance of the reversible thermal expansion of inorganic substances is recognized by metallurgists, glass technologists, and ceramists who deal with manufactured products that are subjected to temperature cycles in service. The temperature interval involved may be small, as in dental porcelain, or large, as in…

Nuclear materials and radiation effectsRecycling and utilization of industrial and municipal waste in materials productionGlass properties and applications

The Inhibition of Foaming. II. A Mechanism for the Rupture of Liquid Films by Anti-foaming Agents.

Sydney Ross1950-03-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Inhibition of Foaming. II. A Mechanism for the Rupture of Liquid Films by Anti-foaming Agents.Sydney. RossCite this: J. Phys. Chem. 1950, 54, 3, 429–436Publication Date (Print):March 1, 1950Publication History Published online1 May 2002Published inissue 1 March 1950https…

Pickering emulsions and particle stabilization