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Ultrastable and polyamorphic states of vapor-deposited 2-methyltetrahydrofuran

Birte Riechers、Anthony Guiseppi‐Elie、M. D. Ediger 等 4 位作者2019-06-03The Journal of Chemical Physics

This work reports results gained from dielectric spectroscopy on the organic molecular glass-former 2-methyltetrahydrofuran (MTHF), which was deposited onto an interdigitated electrode device by physical vapor deposition. By a suitable selection of preparation parameters (deposition temperature, deposition rate, and a…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesPhotochemistry and Electron Transfer Studies

Polarization-insensitive tunable terahertz polarization rotator

Shaoxian Li、Minggui Wei、Xi Feng 等 13 位作者2019-06-03Optics Express

A rotation-angle variable polarization rotator is proposed and demonstrated using an all-dielectric metasurface doublet. Such a transmissive device can conveniently rotate the polarization of incident light by any desired angles by mechanically changing the relative angle of the double metasurface layers regardless of…

Metamaterials and Metasurfaces ApplicationsOrbital Angular Momentum in OpticsAdvanced Antenna and Metasurface Technologies

Preparation of activated carbon from kenaf by activation with H3PO4. Kinetic study of the adsorption/electroadsorption using a system of supports designed in 3D, for environmental applications

Antonio Macı́as-Garcı́a、Juan Pablo Carrasco-Amador、V. Encinas-Sánchez 等 5 位作者2019-06-03Journal of environmental chemical engineering

Activated carbons were prepared from kenaf by chemical activation with phosphoric acid in different concentrations. Its electrical conductivity was also determined. From the series of prepared activated carbons, those with better textural properties, chemistry and high electrical conductivity were selected for their u…

Adsorption and biosorption for pollutant removalConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Investigation of Carmine Dye Removal by Green Chitin Nanowhiskers Adsorbent

Seyyed Salar Meshkat、Mojtaba Nasirinezhad、Mohammad Reza Bazmi2019-06-03Emerging Science Journal

A green adsorbent was evaluated to remove the carmine dye. Chitin nanowhiskers were synthesized via acid hydrolyzed method. The diameter of the synthesized chitin whiskers was about 20 nm and had 200 to 400 nm length. The morphology and chemical structure of the synthesized adsorbent were investigated by Field Emissio…

Adsorption and biosorption for pollutant removalConducting polymers and applicationsSupramolecular Self-Assembly in Materials

Effect of Sputtering Temperature on Fluorocarbon Films: Surface Nanostructure and Fluorine/Carbon Ratio

Qi Zhao、Feipeng Wang、Kaizheng Wang 等 6 位作者2019-06-03Nanomaterials

In this work, fluorocarbon film was deposited on silicon (P/100) substrate using polytetrafluoroethylene (PTFE) as target material at elevated sputtering temperature. Field emission scanning electron microscopy (FESEM), atomic force microscopy (AFM), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS) were e…

Surface Modification and SuperhydrophobicityMetal and Thin Film MechanicsDiamond and Carbon-based Materials Research

Putative mechanism for anticancer properties of Ag–PP (NPs) extract

Masoud Homayouni Tabrizi、Mozhgan Soltani、Ehsan Karimi 等 6 位作者2019-06-03IET Nanobiotechnology

One of the most important challenges in treating cancer is the invasion and the angiogenesis of cancer cells. The synthesis of green nanoparticles (NPs) and their use in therapeutic fields is one of the most effective methods with minimal side effects in cancer treatment. In this study, cytotoxic and anti-angiogenic e…

Nanoparticle-Based Drug DeliveryNanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and Applications

Effect of carbon nanotube addition on structure and properties for extrudates of high‐density polyethylene

Riho Nishikawa、Masayuki Yamaguchi2019-06-03Journal of Applied Polymer Science

ABSTRACT We investigated the structure and properties of strands of high‐density polyethylene (HDPE), containing multi‐walled carbon nanotubes (MWCNTs) extruded from a capillary rheometer. Surprisingly, we found that the MWCNTs enhanced the chain orientation of HDPE, and that in the absence of MWCNTs, orientation rela…

Carbon Nanotubes in CompositesPolymer crystallization and propertiesPolymer Foaming and Composites

DeepCentering: fully automated crystal centering using deep learning for macromolecular crystallography

Shô Itô、Go Ueno、Masaki Yamamoto2019-06-03Journal of Synchrotron Radiation

High-throughput protein crystallography using a synchrotron light source is an important method used in drug discovery. Beamline components for automated experiments including automatic sample changers have been utilized to accelerate the measurement of a number of macromolecular crystals. However, unlike cryo-loop ce…

Protein Structure and DynamicsEnzyme Structure and FunctionMachine Learning in Materials Science

Machine learning guided design of single-molecule magnets for magnetocaloric applications

Ludwig Holleis、B. S. Shivaram、Prasanna V. Balachandran2019-06-03Applied Physics Letters

We present a data-driven approach to predict entropy changes (ΔS) in small magnetic fields in single-molecule magnets (SMMs) relevant to their application as magnetocaloric refrigerants. We construct a database of SMMs with a representation scheme incorporating aspects related to dimensionality, structure, local coord…

Theoretical and Computational PhysicsMagnetism in coordination complexesMachine Learning in Materials Science

Quantum Monte Carlo Studies of CO Adsorption on Transition Metal Surfaces

Cheng‐Rong Hsing、Chun-Ming Chang、Ching Cheng 等 4 位作者2019-06-03The Journal of Physical Chemistry C

The adsorptions of CO molecule on various fcc(111) surfaces (Rh, Ir, Pt, and Cu) have been studied by diffusion quantum Monte Carlo (DMC) calculations, and the results show that the top site is the most stable adsorption site on all the four surfaces, in agreement with experiments. In particular, the site preference i…

Advanced Chemical Physics StudiesCatalytic Processes in Materials Sciencenanoparticles nucleation surface interactions

Systematic study of the chiral smectic phases of a fluorinated compound

Sebastian Lalik、Aleksandra Deptuch、Patryk Fryń 等 9 位作者2019-06-03Liquid Crystals

Physical properties of the partially fluorinated compound 3F5FPhF, with hockey stick-like molecules, were studied by complementary methods. Apart from the already reported paraelectric SmA*, ferroelectric SmC* and antiferroelectric SmC*A phases, the presence of the smectic C*α subphase in the phase sequence was proved…

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchPolydiacetylene-based materials and applications

Ultra-compact, broadband Huygens’ metasurfaces based on induced magnetism

Chunhua Xue、Qun Lou、Teng Li2019-06-03Applied Physics Express

An ultra-compact, broadband Huygens’ metasurface based on induced magnetism has been proposed. The induced magnetism in the Huygens’ meta-atom originates from the circulating electric currents constituted by the antisymmetric flowing of surface currents on the both conducting elements. The Huygens’ metasurface based o…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Direct Radiation Effects on the Structure and Stability of Collagen and Other Proteins

Mathieu Lalande、Lucas Schwob、Violaine Vizcaino 等 7 位作者2019-06-03ChemBioChem

In this review, recent progress in understanding the direct effects of radiation on the structure and stability of collagen, the most abundant protein in the human body, and other proteins is surveyed. Special emphasis is placed on the triple-helical structure of collagen, as studied by means of collagen mimetic pepti…

Meat and Animal Product QualityMarine Biology and Environmental ChemistryCollagen: Extraction and Characterization

Broadband and linear polarization metasurface carpet cloak in the visible

Liyi Hsu、Abdoulaye Ndao、Boubacar Kanté2019-06-03Optics Letters

In the past few years, carpet cloaking has attracted interest because of its feasibility at optical frequencies and potential in stealth technologies. Metasurfaces have been proposed as a method to engineer ultra-thin carpet cloaking surfaces due to their abilities to manipulate wavefronts, polarization, and phase at…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchAdvanced Antenna and Metasurface Technologies

The structure analysis and optical performance of PVA films doped with Fe3+-metal for UV- limiter, and optoelectronics

H. Elhosiny Ali、M. Abdelaziz、H. Algarni 等 4 位作者2019-06-03Materials Research Express

A conventional casting technique was utilized to prepare the PVA/ Fe 3+ composite samples with various weight levels (PVA:0.04 Fe 3+ , PVA:0.19 Fe 3+ , PVA:0.40 Fe 3+ , PVA:1.90 Fe 3+ and PVA:4.00 Fe 3+ wt%) of FeCl 3 . Based on the influence of wt%, the structure of PVA changed to semi-crystalline material with a hig…

Polymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and IrradiationLaser-Ablation Synthesis of Nanoparticles

Graphene-Wrapped MgO/Poly(vinyl alcohol) Composite Sheets: Dielectric and Electromagnetic Interference Shielding Properties at Elevated Temperatures

Sandeep Kumar Marka、Vadali V. S. S. Srikanth、Bashaiah Sindam 等 6 位作者2019-06-03ACS Applied Materials & Interfaces

Different amounts of graphene-wrapped magnesium oxide (G@MgO) powders are uniformly dispersed in poly(vinyl alcohol) (PVA) solution in different experiments to obtain solutions which are coagulated to obtain solid materials, which are then hot pressed at 413 K and 3 t of pressure to finally obtain 1 mm thick freestand…

Electromagnetic wave absorption materialsAdvanced Antenna and Metasurface TechnologiesDielectric materials and actuators

On-surface synthesis of planar dendrimers via divergent cross-coupling reaction

Deng‐Yuan Li、Shiwen Li、Yu-Li Xie 等 7 位作者2019-06-03Nature Communications

Dendrimers are homostructural and highly branched macromolecules with unique dendritic effects and extensive use in multidisciplinary fields. Although thousands of dendrimers have been synthesized in solution, the on-surface synthetic protocol for planar dendrimers has never been explored, limiting the elucidation of…

Molecular Junctions and NanostructuresDendrimers and Hyperbranched PolymersSurface Chemistry and Catalysis

Electric field control of the semiconductor-metal transition in two dimensional CuInP2S6/germanene van der Waals heterostructure

Ziye Zhu、Xiaofang Chen、Wenbin Li 等 4 位作者2019-06-03Applied Physics Letters

We propose a van der Waals heterostructure CuInP2S6/germanene by combining two dimensional ferroelectric semiconductor CuInP2S6 with germanene. By density functional theory calculations, we find that the metal-semiconductor transition can be realized in the CuInP2S6/germanene heterostructure by controlling the ferroel…

Perovskite Materials and Applications2D Materials and ApplicationsAdvanced Sensor and Energy Harvesting Materials

Oxidative Coupling of Methane over Hybrid Membrane/Catalyst Active Centers: Chemical Requirements for Prolonged Lifetime

Valentina Omoze Igenegbai、Rawan Almallahi、Randall J. Meyer 等 4 位作者2019-06-03ACS Energy Letters

Solid oxide membrane/catalyst hybrid systems have been proposed as a promising platform for selective oxidative coupling of methane to form higher value C 2+ products. In these hybrid systems, the membrane controls the local chemical potential of reacting oxygen atoms while the catalyst allows for selective reaction o…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Fullerene-Directed Synthesis of Flowerlike Cu3(PO4)2 Crystals for Efficient Photocatalytic Degradation of Dyes

Mengjun Chen、Geping Zhang、Yue Jiang 等 7 位作者2019-06-03Langmuir

Biomineralization is a typical methodology developed by nature to produce calcium-based materials. A method mimicking this process has nowadays become popular for the preparation of artificial organic–inorganic hybrids. Here, Cu 3 (PO 4 ) 2 crystals with a flowerlike morphology have been prepared using water-soluble d…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesCopper-based nanomaterials and applications