Materials Literature
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The extent of polymerization of liquid sulfur up to 731 K has been obtained using Raman scattering. The data reveal the absence of a maximum in the polymerization curve. The obtained results are discussed in the spirit of computer simulations that suggest the existence of a maximum which depends on the bond breaking e…
High temperature performance of polymers depend mainly on their glass transition temperature T g . Polymers with high T g , however, often tend to have low toughness. In this work, a model polyethylene like polymer is analysed to understand the reason for this phenomenon. To this end, molecular dynamics simulations ar…
A systematic study of the dehydrogenation process of undoped and of catalyzed NaAlH4 by means of anelastic spectroscopy is presented. Evidence is reported of the formation of a highly mobile species during decomposition, which has been identified in off-stoichiometric AlH6-x units, giving rise to fast H vacancy local…
Abstract Boron‐containing novolac resins were prepared through the modification of a commercial novolac resin with different contents of bis(benzo‐1,3,2‐dioxaborolanyl) oxide. Their thermal and flame‐retardant properties were measured. Then, they were crosslinked with hexamethylenetetramine, and their thermal, thermod…
At reduced dimensionality, Coulomb interactions play a crucial role in determining device properties. While such interactions within the same carbon nanotube have been shown to have unexpected properties, device integration and multi-nanotube devices require the consideration of inter-nanotube interactions. We present…
Polyphosphazenes with amino acid ester side groups show potential as hydrolytically degradable materials for biomedical applications. This study focuses on practical aspects of their use as biodegradable materials, such as effects of the hydrolytic environment and sample processing. Poly[di(ethyl glycinato)phosphazene…
In this paper, interatomic potential models used for atomistic simulations of insulating oxides are revisited through the example of ${\mathrm{TiO}}_{2}$ rutile. The cohesive energy of oxides comprises an electrostatic part and a short-range part whose relative importance differs with the models. The electrostatic par…
RAFT agents were attached to multi-walled carbon nanotubes (MWNTs); subsequently, different kinds of aqueous soluble ionic polymer chains, such as cationic polymer (poly(2-(dimethylamino) ethylmethacrylate)), anionic polymer (poly(acrylic acid)) and zwitterionic polymer (poly{3-[ N -(3- methacrylamidopropyl)- N , N -d…
Currently, there is great interest in the development of methods suitable for determining the stoichiometry of biomolecules attached to nanoparticles. We describe the use of the dynamic light-scattering technique (DLS) to determine the stoichiometry of the protein cytochrome P450(BSbeta) attached to CdS and CdSe quant…
The diffusion of glycerol molecules decreases with decreasing temperature as its viscosity increases in a manner simply described by the Stokes-Einstein relation. Approaching the glass transition, this relation breaks down as it does with a number of other pure liquid glass formers. We have measured the diffusion coef…
We study a model suspension of sterically stabilized colloidal particles and nonadsorbing ideal polymer coils, both in bulk and adsorbed against a planar hard wall. By integrating out the degrees of freedom of the polymer coils, we derive a formal expression for the effective one-component Hamiltonian of the colloids.…
An effective Hamiltonian approach is developed to mimic finite-temperature properties of $({\mathrm{Ba}}_{x}{\mathrm{Sr}}_{1\ensuremath{-}x})\mathrm{Ti}{\mathrm{O}}_{3}$ perovskite systems. It is found that this atomistic approach is overall quite accurate to qualitatively and quantitatively reproduce the experimental…
The effects of particle composition on heterogeneous catalysis were studied using dendrimer-encapsulated nanoparticles (DENs) as precursors to supported Pt-Cu catalysts. Bimetallic Pt-Cu DENs with varying Pt/Cu ratios were prepared in an anaerobic aqueous solution and deposited onto a high-purity commercial alumina su…
Abstract Epoxy/Al 2 O 3 nanocomposites were prepared using an epoxy resin, diglycidyl ether of bisphenol A, and cured with a polyoxypropylene diamine (Jeffamine D‐400). Transmission electron microscopy and wide angle X‐ray diffraction were employed to reveal the morphology of epoxy/Al 2 O 3 nanocomposites. Dynamic mec…
Abstract Hexagonal close‐packed (hcp) cobalt nanowires with diameters of 150–300 nm and lengths of up to several hundreds of micrometers have been synthesized by a hydrothermal reduction method. These cobalt nanowires were generated by the reduction of cobalt( II ) citrate complexes by hypophosphite (H 2 PO 2 – ) in b…
It is shown that adsorption of the [Au(en)(2)](3+) cationic complex can be successfully employed for the deposition of gold nanoparticles (1.5 to 3 nm) onto SiO(2) with high metal loading, good dispersion, and small Au particle size. When the solution pH increases (from 3.8 to 10.5), the Au loading in the Au/SiO(2) sa…
We studied the influence of the disorder introduced in polycrystalline MgB2 samples by neutron irradiation. To circumvent self shielding effects due to the strong interaction between thermal neutrons and 10B we employed isotopically enriched 11B which contains 40 times less 10B than natural B. The comparison of electr…
A model involving competing short-range isotropic Heisenberg interactions is developed to explain the "double-q" magnetic structure of CeAl$_2$. For suitably chosen interactions, terms in the Landau expansion quadratic in the order parameters explain the condensation of incommensurate order at wavevectors in the star…
We describe a technique for fabricating nanometer-scale gaps in Pt wires on insulating substrates, using individual single-walled carbon nanotubes as shadow masks during metal deposition. More than 80% of the devices display current-voltage dependencies characteristic of direct electron tunneling. Fits to the current-…
The uniaxial in-plane magnetic anisotropy (UIP-MA) constant is calculated for a single step on the (001) surface of fcc Co($N$) films. The calculations are done for both an undecorated step and the step decorated with one or more, up to 7, Cu wires. Our objective is to explain the mechanisms by which the decoration de…