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Orientational order determination in liquid crystals by x-ray diffraction

Moshe Deutsch1991-12-01Physical Review A

The orientational distribution function f relative to the director of elongated molecules of liquid crystals and related materials can be determined, in principle, from the intensity distribution I along equatorial arcs in the x-ray-diffraction pattern. The integral equation relating these two quantities is solved her…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesMolecular spectroscopy and chirality

Phase Stability and Physical Properties of Cubic and Tetragonal ZrO 2 in the System ZrO 2 –Y 2 O 3 –Ta 2 O 5

Dae‐Joon Kim、T. Y. Tien1991-12-01Journal of the American Ceramic Society

The cubic ( c ‐ZrO 2 ) and tetragonal zirconia ( t ‐ZrO 2 ) phase stability regions in the system ZrO 2 –Y 2 O 3 –Ta 2 O 5 were delineated. The c ‐ZrO 2 solid solutions are formed with the fluorite structure. The t ‐ZrO 2 solid solutions having a c/a axial ratio (tetragonality) smaller than 1.0203 display high fractur…

Advanced ceramic materials synthesisAdvanced materials and compositesNuclear materials and radiation effects

Sevenfold diamond structure and conductivity of copper dicyanoquinonediimines Cu(DCNQI)2

Otto Ermer1991-12-01Advanced Materials

Communication: The high substituent sensitivity of the electrical conductivity of copper DCNQI radical anion salts (see figure) is atributed to the fact that the stacks of copper atoms and bridging DCNQI ligands are covalently clamped together within the frame work of a sevenfold interpenetrating super diamond archite…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchN-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Miscible blends of cellulose and poly(vinylpyrrolidone)

Jean Francois Masson、R. St. John Manley1991-12-01Macromolecules

Peer reviewed: Yes

Material Properties and ApplicationsAdvanced Theoretical and Applied Studies in Material Sciences and GeometryPolymer Science and Applications

The added mass, Basset, and viscous drag coefficients in nondilute bubbly liquids undergoing small-amplitude oscillatory motion

Ashok S. Sangani、D. Z. Zhang、Andréa Prosperetti1991-12-01Physics of Fluids A Fluid Dynamics

The motion of bubbles dispersed in a liquid when a small-amplitude oscillatory motion is imposed on the mixture is examined in the limit of small frequency and viscosity. Under these conditions, for bubbles with a stress-free surface, the motion can be described in terms of added mass and viscous force coefficients. F…

Fluid Dynamics and Heat TransferPickering emulsions and particle stabilizationParticle Dynamics in Fluid Flows

Electro-optic response of polymer dispersed liquid-crystal films

Shubham Jain、D. K. Rout1991-12-01Journal of Applied Physics

The electro-optic response of polymer dispersed liquid-crystal (PDLC) films is reported as a function of frequency and amplitude of the applied voltage and size of the LC droplets. We found that the threshold voltage is minimum and sharpest at frequencies near a few kHz. Visual and optical response studies show that t…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsNonlinear Dynamics and Pattern Formation

Mixed-Layer Clay Geothermometry in the Wairakei Geothermal Field, New Zealand

Colin C. Harvey、P. R. L. Browne1991-12-01Clays and Clay Minerals

Abstract Mixed-layer clays of variable composition and structure occur in core samples from two drillholes (WK207 and WK210) drilled into the Te Mihi sector of the Wairakei geothermal field. These were identified by X-ray diffraction analysis of glycolated and oriented sample fractions at less than 2 μ m and less than…

Geological and Geochemical AnalysisSoil and Unsaturated FlowClay minerals and soil interactions

Laminin and basement membrane-associated microfilaments in wild-type and mutant Drosophila ovarian follicles

Herwig O. Gutzeit、W. Eberhardt、Eugen K.‐M. Gratwohl1991-12-01Journal of Cell Science

The localization of the extracellular matrix glycoprotein laminin was studied using polyclonal anti-laminin antibodies. The laminin patterns of the basement membranes of the muscular epithelial sheath that envelops the ovariole were conspicuously different from those of the basement membrane of the follicular epitheli…

Cellular Mechanics and InteractionsCell Adhesion Molecules ResearchSilk-based biomaterials and applications

Template‐Controlled Formation of Cluster Shells or a Type of Molecular Recognition: Synthesis of [HV22O54(ClO4)]6− and [H2V18O44(N3)]5−

Achim Müller、Erich Krickemeyer、Michael Penk 等 6 位作者1991-12-01Angewandte Chemie International Edition in English

Anions as templates for “host” anions determine the shape of molecular cavities (cluster shells) which form from differently coupled tetragonal-pyramidal OVO4 building blocks. For example, in the case of the cluster anions [HV22O54(ClO4)]6− and [H2V18O44(N3)]5− (depicted on the right) the construction of the cluster s…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Tetrabutylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate as a noncoordinating electrolyte: reversible 1e- oxidations of ruthenocene, osmocene, and Rh2(TM4)42+ (TM4=2,5-diisocyano-2,5-dimethylhexane)

Michael G. Hill、W. M. Lamanna、Kent R. Mann1991-12-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTetrabutylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate as a noncoordinating electrolyte: reversible 1e- oxidations of ruthenocene, osmocene, and Rh2(TM4)42+ (TM4=2,5-diisocyano-2,5-dimethylhexane)Michael G. Hill, William M. Lamanna, and Kent R. MannCite this: Inor…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesElectrochemical Analysis and Applications

Mode-coupling theory of the glass transition in colloidal systems

Grzegorz Szamel、Hartmut Löwen1991-12-01Physical Review A

Within a mode-coupling approximation we investigate the influence of the short-time dynamics of colloidal fluids on the glass-transition scenario. We assume Brownian dynamics, neglect hydrodynamic interactions, and follow approximations used to construct a mode-coupling theory (MCT) for structural relaxation in dense…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesThermodynamic properties of mixtures

Mechanism of Pore Formation on n‐Type Silicon

X. G. Zhang1991-12-01Journal of The Electrochemical Society

The morphology of porous silicon formed on n‐type silicon by anodic dissolution in HF solution and its relation to the current‐potential characteristics are reported. An individual pore generally consists of three sections: a thin surface layer with pore size much smaller than in the bulk; an equidiameter main body; a…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceAnodic Oxide Films and Nanostructures

An extended equation to calculate NaCl contents from final clathrate melting temperatures in H2O-CO2-NaCl fluid inclusions: Implications for P-T isochore location

Robert S. Darling1991-12-01Geochimica et Cosmochimica Acta

This report informs fluid inclusion researchers of an extended equation to calculate wt% NaCl from final CO2-clathrate melting temperatures in H2O-CO2-NaCl fluid inclusions. This equation is valid only if melting occurs in the presence of CO2-liquid, CO2-vapor, and salt solution. Previous workers used the equation of…

Methane Hydrates and Related PhenomenaCalcium Carbonate Crystallization and InhibitionCO2 Sequestration and Geologic Interactions

Synthesis and size control of polystyrene latices via polymerization in microemulsion

Markus Antonietti、Wolfgang Bremser、Dorothea Mueschenborn 等 6 位作者1991-12-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and size control of polystyrene latices via polymerization in microemulsionMarkus Antonietti, Wolfgang Bremser, Dorothea Mueschenborn, Christine Rosenauer, Beate Schupp, and Manfred SchmidtCite this: Macromolecules 1991, 24, 25, 6636–6643Publication Date (Print):De…

Surfactants and Colloidal SystemsMesoporous Materials and CatalysisInorganic and Organometallic Chemistry

Proline residues responsible for thermostability occur with high frequency in the loop regions of an extremely thermostable oligo-1,6-glucosidase from Bacillus thermoglucosidasius KP1006.

Kunihiko Watanabe、K. Chishiro、K. Kitamura 等 4 位作者1991-12-01Journal of Biological Chemistry

The gene encoding for an extremely thermostable oligo-1,6-glucosidase from Bacillus thermoglucosidasius KP1006 (DSM2542, obligate thermophile) was sequenced. The amino acid sequence deduced from the nucleotide sequence of the gene (1686 base pairs) corresponded to a protein of 562 amino acid residues with a Mr of 66,5…

Bacterial Genetics and BiotechnologyRNA and protein synthesis mechanismsEnzyme Structure and Function

Numerical and experimental studies of bubble growth during the microcellular foaming process

N. S. Ramesh、Don H. Rasmussen、Gregory A. Campbell1991-12-01Polymer Engineering and Science

Abstract A new experimental technique for studying the dynamics of bubble growth in thermoplastics using scanning electron microscopy is developed. The influence of temperature, saturation pressure, molecular weight, and the nature of physical blowing agent are investigated. The experimental results show that, the abo…

Polymer composites and self-healingRheology and Fluid Dynamics StudiesPolymer Foaming and Composites

The effect of liquid-phase sintering on the properties of Pr6O11-based ZnO varistors

Aldo Bologna Alles、Vernon L. Burdick1991-12-01Journal of Applied Physics

Conventionally batched varistors in the ZnO–Co3O4–Pr6O11 system that were sintered at or above 1280 °C exhibited a sharp increase in the average breakdown voltage per grain boundary. In these samples, barrier heights and donor concentration values, derived from capacitance-voltage analysis, exhibited sharp changes at…

ZnO doping and propertiesSilicon and Solar Cell TechnologiesSemiconductor materials and interfaces

Silicon Nitride—From Powder Synthesis to Ceramic Materials

H. Lange、G. Wötting、Gerhard Winter1991-12-01Angewandte Chemie International Edition in English

Abstract Silicon nitride is a ceramic material of great interest to advanced engine construction and mechanical engineering owing to an outstanding combination of favorable properties like high mechanical strength at high temperatures, corrosion and wear resistance, great hardness, and low density. The material is bas…

Advanced ceramic materials synthesisMXene and MAX Phase MaterialsMuon and positron interactions and applications

Safety of gadolinium‐DTPA: Extended clinical experience

H.P. Niendorf、Jens Haustein、I. Cornelius 等 5 位作者1991-12-01Magnetic Resonance in Medicine

This review reports data on the general and renal tolerance of the paramagnetic contrast agent Gd-DTPA after intravenous administration. Gd-DTPA was administered usually at a dose level of 0.1-0.2 mmol/kg body wt (range: 0.005-0.25 mmol/kg body wt) in cranial, spinal and body MR indications. In phase I-IIIa studies a…

Advanced MRI Techniques and ApplicationsAcute Kidney Injury ResearchLanthanide and Transition Metal Complexes

Estimation of distillation compositions from multiple temperature measurements using partial-least-squares regression

Thor Mejdell、Sigurd Skogestad1991-12-01Industrial & Engineering Chemistry Research

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEstimation of distillation compositions from multiple temperature measurements using partial-least-squares regressionThor Mejdell and Sigurd SkogestadCite this: Ind. Eng. Chem. Res. 1991, 30, 12, 2543–2555Publication Date (Print):December 1, 1991Publication History Published…

Spectroscopy and Chemometric AnalysesFault Detection and Control SystemsCrystallization and Solubility Studies