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Molecular structure of gold 2,3,7,8,12,13,17,18-octabromo-5,10,15-tris(4′-pentafluorosulfanylphenyl)corrole: Potential insights into the insolubility of gold octabromocorroles

Kolle E. Thomas、Kevin J. Gagnon、Laura J. MCormick 等 4 位作者2018-06-11Journal of Porphyrins and Phthalocyanines

X-ray structures of gold corroles, which are still rather uncommon, afford significant insights into intermolecular interactions involving Au(III), a subject that has been much less studied than aurophilic and metallophilic interactions involving Au(I). The X-ray structure of gold [Formula: see text]-octabromo-meso-tr…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresSurface Chemistry and Catalysis

Trap-Door-Like Irreversible Photoinduced Charge Transfer in a Donor–Acceptor Complex

Carlos R. Lien-Medrano、Cristián G. Sánchez2018-06-11The Journal of Physical Chemistry Letters

For efficient conversion of light into useful energy sources, it is very important to study and describe the first steps of primary charge-transfer process in natural structures and artificial devices. The time scale of these processes in artificial photosynthetic and photovoltaic devices is on the order of femto- to…

Diamond and Carbon-based Materials ResearchPorphyrin and Phthalocyanine ChemistryMolecular Junctions and Nanostructures

Efficient Removal of Cadmium Using Edible Fungus and Its Quantitative Fluorimetric Estimation Using ( Z )‑2-(4 H ‑1,2,4-Triazol-4-yl)iminomethylphenol

Abhijit Manna、Ellairaja Sundaram、Chinnaiah Amutha 等 4 位作者2018-06-11ACS Omega

Abstract Microbes accumulate heavy metals after adsorption or absorption. This study exhibited that Trametes versicolor can tolerate up to 5 mg/g concentration of cadmium. Change in fungus morphology due to cadmium along with its absorption were analyzed using SEM, XRD, and EDAX. Cadmium absorption usually increased w…

Nanoparticles: synthesis and applicationsHeavy metals in environmentHeavy Metal Exposure and Toxicity

Tailored Mesoporous Silica Nanoparticles for Controlled Drug Delivery: Platform Fabrication, Targeted Delivery, and Computational Design and Analysis

Xiaodong She、Lijue Chen、Zhifeng Yi 等 10 位作者2018-06-11Mini-Reviews in Medicinal Chemistry

Mesoporous silica nanoparticles (MSNs) are exceptionally promising drug carriers for controlled drug delivery systems because their morphology, pore structure, pore volume and pore size can be well tailored to obtain certain drug release profiles. Moreover, they possess the ability to specifically transport and delive…

Nanoparticle-Based Drug DeliveryMesoporous Materials and Catalysis

Probing flexoelectricity via a split Hopkinson pressure bar experiment

Taotao Hu、Qian Deng、Shengping Shen2018-06-11Applied Physics Letters

Flexoelectricity is thought of as a universal property of all dielectric materials that couples polarization with the inhomogeneous deformation. However, at the macroscale, this coupling is usually very weak and the direct observation of flexoelectricity always suffers from a low signal-to-noise ratio (SNR). At the mi…

Force Microscopy Techniques and ApplicationsMechanical and Optical ResonatorsNonlocal and gradient elasticity in micro/nano structures

Electrical properties of ZnO:H films fabricated by RF sputtering deposition and fabrication of p-NiO/n-ZnO heterojunction devices

Yusuke Ohteki、Mutsumi Sugiyama2018-06-11Japanese Journal of Applied Physics

Abstract A high-transparency ZnO thin film of high carrier concentration was grown by conventional RF sputtering, where the carrier concentration was continuously varied from 10 16 to 10 19 cm −3 by controlling the amounts of O 2 and H 2 sputtering gases. To prevent the formation of a Schottky junction at the contact…

ZnO doping and propertiesTransition Metal Oxide NanomaterialsCopper-based nanomaterials and applications

Theoretical description of quantum mechanical permeation of graphene membranes by charged hydrogen isotopes

James W. Mazzuca、Nathaniel Haut2018-06-11The Journal of Chemical Physics

It has been recently shown that in the presence of an applied voltage, hydrogen and deuterium nuclei can be separated from one another using graphene membranes as a nuclear sieve, resulting in a 10-fold enhancement in the concentration of the lighter isotope. While previous studies, both experimental and theoretical,…

Graphene research and applicationsNanopore and Nanochannel Transport StudiesMuon and positron interactions and applications

Antibacterial Evaluation of Cuprous Oxide Nanoparticles Synthesized Using Leaf Extract of Callistemon viminalis

Deepika Sharma、N. Thakur、Jitendraa Vashistt 等 4 位作者2018-06-11Indian Journal of Pharmaceutical Education and Research

Abstract: Objectives: Nanoparticles synthesis via green approach is a scorching theme of research nowadays as it minimizes the use of harmful chemicals. Not much work has been done on bio reduction of copper salts; therefore our present work was focused on green synthesis of copper oxide nanoparticles using leaf extra…

Nanoparticles: synthesis and applications

Waste heat recovery in an oscillating heat pipe using interfacial electrical double layers

Qingchen Shen、Chao Chang、Peng Tao 等 10 位作者2018-06-11Applied Physics Letters

This work presents the recovery of thermal energy through the oscillation of liquid plugs induced by phase transition within the oscillating heat pipe (OHP) during the quick heat-transfer process of the OHP. Using the electrical double layer at the liquid-solid interface in the OHP, this study demonstrated that the wa…

Advanced Thermoelectric Materials and DevicesSolar-Powered Water Purification MethodsThermal Radiation and Cooling Technologies

Synthesis of Poly(3,4-ethylenedioxythiophene)–Platinum and Poly(3,4-ethylenedioxythiophene)–Poly(styrenesulfonate) Hybrid Fibers by Alternating Current Bipolar Electropolymerization

Yuki Koizumi、Masato Ohira、Tempei Watanabe 等 6 位作者2018-06-11Langmuir

Alternating current (ac) bipolar electropolymerization of 3,4-ethylenedioxythiophene (EDOT) was performed in the presence of hexachloroplatinate ([PtCl 6 ] 2– ) or poly(styrenesulfonate) (PSS). We demonstrated that both [PtCl 6 ] 2– and PSS were successfully incorporated into electrogenerated poly(3,4-ethylenedioxythi…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Synthesis, densification, and microstructure of TaC‐TaB 2 ‐SiC ceramics

Junfeng Gu、Mingyu Xiang、Wei Ji 等 6 位作者2018-06-11Journal of the American Ceramic Society

Abstract The usual way to prepare TaC‐TaB 2 ceramics by adding B 4 C to TaC leads to formation of residual C, which degrades samples’ mechanical properties. To eliminate the residual C, we suggest incorporating Si together with B 4 C into TaC ceramics, resulting in new ultrahigh‐temperature ceramics (TaC‐TaB 2 ‐SiC).…

Advanced ceramic materials synthesisMXene and MAX Phase MaterialsAdvanced materials and composites

Size-selective breaking of the core–shell structure of gallium nanoparticles

Sergio Catalán‐Gómez、A. Redondo‐Cubero、F. J. Palomares 等 9 位作者2018-06-11Nanotechnology

Core-shell gallium nanoparticles (Ga NPs) have recently been proposed as an ultraviolet plasmonic material for different applications but only at room temperature. Here, the thermal stability as a function of the size of the NPs is reported over a wide range of temperatures. We analyze the chemical and structural prop…

ZnO doping and propertiesGold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And Properties

Inverse surface‐enhanced spatially offset Raman spectroscopy (SESORS) through a monkey skull

Ren Odion、Pietro Strobbia、Bridget M. Crawford 等 4 位作者2018-06-11Journal of Raman Spectroscopy

Abstract The use of nanoparticles in nanomedicine has received increasing interest. However, in vivo detection of nanoparticles using optical techniques is still a formidable challenge. Detecting surface‐enhanced Raman scattering (SERS)‐labeled nanoparticles through thick tissue is crucial due to its large number of p…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy Techniques in Biomedical and Chemical ResearchPhotoacoustic and Ultrasonic Imaging

Electron Delocalization of Mixed‐Valence Diiron Sites Mediated by Group 10 Metal Ions in Heterotrimetallic Fe‐M‐Fe (M=Ni, Pd, and Pt) Chain Complexes

Yu‐Chiao Liu、Shao‐An Hua、Ming‐Chuan Cheng 等 10 位作者2018-06-11Chemistry - A European Journal

Abstract The heterotrimetallic complexes [FeMFe(dpa) 4 Cl 2 ] (M=Ni ( 1 ), Pd ( 2 ), and Pt ( 3 ); dpa − =dipyridylamido) featuring two high‐spin iron centers linked by Group 10 metals were synthesized and their physical properties were investigated. Oxidation of 1 – 3 with suitable oxidants in CH 2 Cl 2 solution yiel…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Copper–Nickel and Copper–Cobalt Thermoelectric Generators: Power-Generating Optimization through Structural Geometrics

Krishna Veni Selvan、Mohamed Sultan Mohamed Ali2018-06-11IEEE Transactions on Electron Devices

In this paper of thermoelectric generators, metals are used as the prospective thermoelectric materials or thermoelements on flexible copper (Cu)-clad polyimide substrate. The fabricated thick film generators have planar and lateral structures with lateral heat flow and lateral thermopile layout. Hereby, two prototype…

Advanced Thermoelectric Materials and DevicesInnovative Energy Harvesting TechnologiesThermal Radiation and Cooling Technologies

Unraveling the Water Impermeability Discrepancy in CVD‐Grown Graphene

Jinsung Kwak、Se‐Yang Kim、Yongsu Jo 等 7 位作者2018-06-11Advanced Materials

Graphene has recently attracted particular interest as a flexible barrier film preventing permeation of gases and moistures. However, it has been proved to be exceptionally challenging to develop large-scale graphene films with little oxygen and moisture permeation suitable for industrial uses, mainly due to the prese…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Synthesis of Graphene-like Films by Electrochemical Reduction of Polyhalogenated Aromatic Compounds and their Electrochemical Capacitor Applications

Züleyha Kudaş、Emre Gür、Duygu Ekinci2018-06-11Langmuir

Graphene is a promising two-dimensional nanomaterial for many applications due to its exciting properties. In the past decade, a variety of techniques-each with its own set of advantages and disadvantages-have been developed to prepare graphene, and there are ongoing efforts to improve these techniques and to reveal n…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

Oil/Water Separations from Nanosized Superhydrophobic to Microsized under-Oil Superhydrophilic Dust

Mengying Long、Shan Peng、Wanshun Deng 等 8 位作者2018-06-11ACS Applied Nano Materials

Dust, which can be seen almost everywhere in real life, often dirties the building, car, cloth, and so on. Humans have come up with many ideas to wash it out for a cleaner world. While in the point of material researchers, dust is composed of particles in different scales. In this work, for the first time, we try to m…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferAerosol Filtration and Electrostatic Precipitation

Low temperature preparation of highly fluorinated multiwalled carbon nanotubes activated by Fe 3 O 4 to enhance microwave absorbing property

Yang Liu、Yichun Zhang、Cheng Zhang 等 8 位作者2018-06-11Nanotechnology

Abstract Conventional approaches to preparing highly fluorinated multiwalled carbon nanotubes (MWCNTs) always require a high temperature. This paper presents a catalytic approach to realizing the effective fluorination of MWNCTs at room temperature (RT). Fe 3 O 4 /MWCNTs composites with Fe 3 O 4 loaded on MWCNTs were…

Electromagnetic wave absorption materialsFlame retardant materials and propertiesAdvanced Antenna and Metasurface Technologies

Iron Oxide Nanoparticles with Grafted Polymeric Analogue of Dimethyl Sulfoxide as Potential Magnetic Resonance Imaging Contrast Agents

Jiajun Yan、Sipei Li、Francis Cartieri 等 8 位作者2018-06-11ACS Applied Materials & Interfaces

Novel water-dispersible hybrid iron oxide nanoparticles grafted with a polymeric analogue of dimethyl sulfoxide (DMSO) were prepared. Superparamagnetic iron oxide nanoparticles with immobilized atom-transfer radical polymerization (ATRP) initiators were prepared via an in situ method using 12-(2-bromoisobutyramido)dod…

Nanoparticle-Based Drug DeliveryAdvanced Polymer Synthesis and CharacterizationLanthanide and Transition Metal Complexes