Materials Literature
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Post-translational maturation of cytochromes c involves the covalent attachment of heme to the Cys-Xxx-Xxx-Cys-His motif of the apo-cytochrome. For this process, the two cysteines of the motif must be in the reduced state. In bacteria, this is achieved by dedicated, membrane-bound thiol-disulfide oxidoreductases with…
Abstract Stress-induced crystallization and melting of natural and synthetic cis-isoprene are compared by simultaneous Wide Angles X-ray Scattering ( WAXS ) and mechanical measurements. Natural (NR) and synthetic polyisoprene (SR) rubbers have the same composition and sulfur crosslink density. At fixed elongation and…
Surface-enhanced Raman scattering (SERS) spectra of methionine (Met) containing dipeptides: Met-X and X-Met, where X is: L-glycine (Gly), L-leucine (Leu), L-proline (Pro), and L-phenylalanine (Phe) are reported. Using pre-aggregated Ag colloid we obtained high-quality SERS spectra of these compounds spontaneously adso…
The electrooptic characteristics of a twisted nematic (TN) liquid crystal display (LCD) fabricated by doping Ag nanoparticles protected with NLC, 5CB (K-15, Merck) molecules have been investigated, and it is shown that the device exhibits a unique electrooptic response characteristic that is sensitive to the high-freq…
Reaction of [Bu(4)N](4)[H(3)PW(11)O(39)] with [Re(NPh)Cl(3)(PPh(3))(2)], in acetonitrile and in the presence of NEt(3), provided the first Keggin-type organoimido derivative [Bu(4)N](4)[PW(11)O(39)(ReNPh)] (Ph = C(6)H(5)) (1). The functionalization was clearly demonstrated by various techniques including (1)H and (14)…
The flash-cooling of crystals in macromolecular crystallography has become commonplace. The procedure makes it possible to collect data from much smaller specimens than was the case in the past Also, flash-cooled crystals are much less prone to radiation damage than their room-temperature counterparts, allowing data t…
Fabric hand is commonly adopted for assessing fabric quality and prospective perfor mance in a particular end use. In general, fabric hand is primarily assessed subjectively. Subjective assessments treat fabric hand as a psychological reaction obtained from the sense of touch, based on the experience and sensitivity o…
Sensitivity to crack propagation in flax fiber-reinforced polypropylene (PP) composites has been examined on SEN-T specimens. The sound waves that arise due to loading have been investigated with the acoustic emission method. Linear functional relationship has been revealed between the number of acoustic events that o…
Silicate glasses remain the most investigated systems for optical planar waveguides, since they offer a reasonable solubility for rare-earth ions, they are transparent in the near-infrared–visible region and they are compatible with integrated optics (IO) technology. In the last decade, various technologies have been…
Galactose mutarotase catalyzes the conversion of beta-d-galactose to alpha-d-galactose during normal galactose metabolism. The enzyme has been isolated from bacteria, plants, and animals and is present in the cytoplasm of most cells. Here we report the x-ray crystallographic analysis of human galactose mutarotase both…
Yttria-alumina-silica (YAS) glasses doped with Er/sup 3+/ and Tm/sup 3+/ have been examined spectroscopically for their potential as fiber amplifier gain media for optical telecommunication systems. Absorption and emission spectra as well as emission lifetime measurements and Judd-Ofelt calculations are reported. Tm/s…
Abstract Summary: Mimetics of eggshell membrane protein fibers have been obtained with an electrospinning technique based on soluble eggshell membrane protein (SEP) prepared previously. Poly(ethylene oxide), a biocompatible and water soluble polymer, is used to improve the processability of SEP. Blends of SEP/PEO aque…
Abstract Concern about the release of eco-toxic zinc species from rubbers into the environment leads to an increasing interest in potential substitutes. Although alternative metal oxides and zinc compounds as activators for sulfur vulcanization have been studied thoroughly, at present no viable alternative has been fo…
To investigate the relationship between the size and structure of TiO(2) nanoparticles, three size-selected samples of TiO(2) nanoparticles were prepared via a hydrolysis method that uses Ti[OCH(CH(3))(2)](4) as the starting material. The structures of the nanoparticles were characterized using powder X-ray diffractio…
Colloid transport studies were conducted in water-saturated physically heterogeneous systems to gain insight into the processes controlling transport in natural aquifer and vadose zone (variably saturated) systems. Stable monodispersed colloids (carboxyl latex microspheres) and porous media (Ottawa quartz sands) that…
The regional flux density in laminations of soft magnetic materials is usually determined by means of a single-winding coil inserted through drilled holes. An alternative method is to use needle contacts arranged at lamination surface points through the surface coating. This method is simple and nondestructive. Howeve…
Abstract Enhancement of the solubility of valdecoxib was examined using a series of hydrophilic carriers (mannitol, polyethylene glycol (PEG) 4000, PEG 6000, PEG 8000, and urea), surfactants (Tween‐20, Tween‐80, and sodium lauryl sulfate [SLS]) and cosolvents (ethanol, methanol, and glycerol) at 37°C. The solubility o…
Plasma damage to methylsilsequioxane (MSQ) based low-k dielectrics degrades the material’s resistance to subsequent wet etch processes. In addition, the loss of methyl species during plasma exposure increases their susceptibility to water absorption leading to increased dielectric permittivities. In this article, we i…
Different methods and conditions for ATP incorporation into PEGylated liposomes were compared in order to obtain a preparation with a maximized ATP content. Such a preparation may find the application for the in vivo treatment of ischemic tissues suffering from an insufficient ATP supply. Several different methods of…
Structure–property relationships were investigated to reveal the generic influence of various substituents on ferroelectric BaTiO 3 . Compositional modifications of ferroelectric BaTiO 3 were systematically investigated for La 3+ and Nb 5+ substituents. A generic influence of charged point defects in breaking down the…