Materials Literature
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Thethermoelectric properties of mixed oxides In2O3·MOx(MOx= Cr2O3, Mn2O3, NiO, ZnO, Y2O3, Nb2O5 SnO2) are investigated in terms of the thermoelectric materials at high temperature. The Seebeck coefficients,S, of all the samples have negative values, and those of In2O3·SnO2 and In2O3·ZnO increase linearly with temperat…
The syntheses and characterization of a series of (15-crown-5)methyl 3,4,5-tris(p-alkyloxybenzyloxy)benzoatest with alkyl tails of four 25, six 26, and twelve 27 carbon atoms and of (15-crown-5)methyl 3,4,5-tris(p-dodecyloxybenzoate)28 are described. Complexation of the crown ether endo-receptor with NaCF3SO3 destabil…
The mechanism of irreversible inactivation of mandelate racemase (MR) from Pseudomonas putida by alpha-phenylglycidate (alpha PGA) has been investigated stereochemically and crystallographically. The (R) and (S) enantiomers of alpha PGA were synthesized in high enantiomeric excess (81% ee and 83% ee, respectively) usi…
ZnO and ZnS powders were prepared from aqueous solutions of zinc salts in the presence of ethylenediamine or triethanolamine. The morphology of the powders was analysed by scanning electron microscopy and infrared spectroscopy. The effect of the experimental conditions upon the size and shape of the particles is descr…
Advanced liposomal therapeutics has been attained by liposome surface modification, initially with specific glycolipids and subsequently with surface-grafted PEG, reducing in vivo rapid recognition and uptake, giving prolonged blood circulation, and providing selective localization in tumors and other pathological sit…
Several mechanism-related aspects of the corrosion of zirconium alloys have been investigated using different examination techniques. The microstructure of different types of oxide layers was analyzed by transmission electron microscopy (TEM). Uniform oxide mainly consists of m-ZrO2 and a smaller fraction of t-ZrO2 wi…
It is shown that the adsorption of water by a variety of active carbons can be described within the framework of Dubinin's theory. Owing to the low values of the characteristic energy, E(0.8–2.5 kJ mol–1), the Dubinin–Astakhov equation becomes S-shaped in the range 0.3 < p/po <0.7 and provides a good basis for the fit…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTImportance of distinct water environments in the hydrolysis of poly(DL-lactide-co-glycolide)Eric A. Schmitt, D. R. Flanagan, and Robert J. LinhardtCite this: Macromolecules 1994, 27, 3, 743–748Publication Date (Print):January 1, 1994Publication History Published online1 May…
An extension of the Judd–Ofelt technique [B. R. Judd, Phys. Rev. 127, 750 (1962)] is introduced in which measured fluorescence branching ratios are incorporated into the calculation of the Judd–Ofelt parameters. It is found that including branching ratio measurements into the analysis allows the Judd–Ofelt parameters…
Calcium carbonate precipitation by 63 strains of moderately halophilic bacteria (Vibrio spp.) isolated from water of a saltern pond has been studied, taking into account the influence of salinity and temperature on the quantity and type of crystals precipitated. The bacteria formed crystals under all the conditions te…
Novel bis(phthalocyaninato)lutetium(III) complexes substituted with long n-alkyl chains have been synthesized. These complexes, 1a–c, show three kinds of discotic mesophase (Dhd, Dob.d, and DL). Also 1a–c display the three primary colours (red, green, blue) of electrochromism in their solutions. The solutions of oxidi…
The new tripodal ligand tris-[3-(2′-pyridyl)pyrazol-1-yl]hydroborate (L–), comprising three N,N-bidentate chelating arms linked by the apical boron atom, has been synthesized; the crystal structure of [EuL(MeOH)2F][PF6] reveals the nine-coordinate metal lying within the hexadentate ligand cavity.
Tremendous efforts have been devoted to the studies of ceramic materials under transient thermal conditions over the past four decades. Such studies are becoming increasingly more important as advanced ceramic materials are demanded for applications at higher temperatures and more severe transient thermal conditions.…
All articles of this category Reproducible, high-yielding synthesis of the title compounds 2-4 , which are important precursors of highly functionalised tetrathiafulvalene derivatives and multistage redox assemblies, are described. This is demonstrated by the subsequent reactions of 3 and 4 to prepare compounds 9-16 ;…
High-resolution X-ray powder diffraction using synchrotron radiation has been used to determine the unit-cell parameters of some of the n-alkanes within the range C13H28–C60H122. These have, in general, been found to conform to the structural patterns predicted by Nyburg and Potworowski (Acta Crystallogr., Sect. B, 19…
The differential thermal analysis of a single crystal of pyridinium tetrafluoroborate was performed revealing two solid-solid phase transitions at 205 and 240 K. The real part of the dielectric permittivity was measured between 190 and 290 K. The large anomaly at the higher phase transition is interpreted as the Curie…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTConduction type of substituted tetraazaporphyrins and perylene tetracarboxylic acid diimides as detected by thermoelectric power measurementsD. Schlettwein, D. Woehrle, E. Karmann, and U. MelvilleCite this: Chem. Mater. 1994, 6, 1, 3–6Publication Date (Print):January 1, 1994…
I. Introduction Fibre Reinforced Polymers History of fibre reinforced polymer materials Resins Additives to resins Reinforcements Properties of composite materials Health and safety II. Techniques for Manufacture of Composites Manufacturing Processes Introduction Open mould processes Closed mould processes Continuous…
The fast-decay component of the retained polarization in lead zirconate titanate ferroelectric capacitors was examined as a function of write/read voltage, number of cycles (fatigue), and temperature. The percentage of polarization loss within 1 s after the write pulse was found to be independent of the write/read vol…
We review the results of electrical conduction and breakdown research reported mainly after 1980 in Japan, and comment on the present situation and future prospect of research work in this field. Effects of introduction of polar groups into polymers on electric strength F/sub b/ are summarized. Influences of copolymer…