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Energy-Saving Synthesis of MOF-Derived Hierarchical and Hollow Co(VO3)2-Co(OH)2 Composite Leaf Arrays for Supercapacitor Electrode Materials

Yingxi Zhang、Hao Chen、Cao Guan 等 7 位作者2018-05-23ACS Applied Materials & Interfaces

A one-step and energy-saving method was proposed to synthesize hierarchical and hollow Co(VO 3 ) 2 -Co(OH) 2 composite leaf arrays on carbon cloth, which expressed high capacitance (522 mF cm –2 or 803 F g –1 at the current density of 0.5 mA cm –2 ), good rate capability (79.5% capacitance retention after a 30-fold in…

Supercapacitor Materials and FabricationConducting polymers and applicationsAdvanced battery technologies research

Modeling of hot deformation behavior and prediction of flow stress in a magnesium alloy using constitutive equation and artificial neural network (ANN) model

Saeed Aliakbari Sani、G.R. Ebrahimi、H. Vafaeenezhad 等 4 位作者2018-05-23Journal of Magnesium and Alloys

The aim of the present study was to investigate the modeling and prediction of the high temperature flow characteristics of a cast magnesium (Mg–Al–Ca) alloy by both constitutive equation and ANN model. Toward this end, hot compression experiments were performed in 250–450 °C and in strain rates of 0.001–1 s−1. The tr…

Microstructure and mechanical propertiesMagnesium Alloys: Properties and ApplicationsMetallurgy and Material Forming

Formation of Deep Electron Traps by Yb3+ Codoping Leads to Super-Long Persistent Luminescence in Ce3+-Doped Yttrium Aluminum Gallium Garnet Phosphors

Jumpei Ueda、Shun Miyano、Setsuhisa Tanabe2018-05-23ACS Applied Materials & Interfaces

The Y 3 Al 2 Ga 3 O 12:Ce 3+ –Cr 3+ compound is one of the brightest persistent phosphors, but its persistent luminescence duration is not so long because of the relatively shallow Cr 3+ electron trap. To compare the vacuum referred binding energy of the electron trapping state by Cr 3+ and lanthanide ions, we selecte…

Luminescence Properties of Advanced MaterialsTerahertz technology and applicationsRadiation Detection and Scintillator Technologies

Collective variable discovery and enhanced sampling using autoencoders: Innovations in network architecture and error function design

Wei Chen、Aik Rui Tan、Andrew L. Ferguson2018-05-23The Journal of Chemical Physics

Auto-associative neural networks ("autoencoders") present a powerful nonlinear dimensionality reduction technique to mine data-driven collective variables from molecular simulation trajectories. This technique furnishes explicit and differentiable expressions for the nonlinear collective variables, making it ideally s…

Protein Structure and DynamicsSpectroscopy and Quantum Chemical StudiesMachine Learning in Materials Science

Optically Active CdSe-Dot/CdS-Rod Nanocrystals with Induced Chirality and Circularly Polarized Luminescence

Jiaji Cheng、Junjie Hao、Haochen Liu 等 9 位作者2018-05-23ACS Nano

Ligand-induced chirality in semiconductor nanocrystals (NCs) has attracted attention because of the tunable optical properties of the NCs. Induced circular dichroism (CD) has been observed in CdX (X = S, Se, Te) NCs and their hybrids, but circularly polarized luminescence (CPL) in these fluorescent nanomaterials has b…

Quantum Dots Synthesis And PropertiesSynthesis and Properties of Aromatic CompoundsNanocluster Synthesis and Applications

Highly Oriented Monolayer Graphene Grown on a Cu/Ni(111) Alloy Foil

Ming Huang、Mandakini Biswal、Hyo Ju Park 等 19 位作者2018-05-23ACS Nano

Fast-growth of single crystal monolayer graphene by CVD using methane and hydrogen has been achieved on “homemade” single crystal Cu/Ni(111) alloy foils over large area. Full coverage was achieved in 5 min or less for a particular range of composition (1.3 at.% to 8.6 at.% Ni), as compared to 60 min for a pure Cu(111)…

Advancements in Battery MaterialsGraphene research and applications2D Materials and Applications

Recent Progresses of High-Temperature Microwave-Absorbing Materials

Zirui Jia、Kejun Lin、Guanglei Wu 等 5 位作者2018-05-23NANO

Generally, certain parts of aircraft and weapons, for example, head cone, engine inlet and nozzle, need to be resistant to high-temperature and high-speed heat flow. In order to meet the requirement of stealth of these special parts, the high-temperature structural absorbing materials, for example, ceramic fibers, cer…

Metamaterials and Metasurfaces ApplicationsElectromagnetic wave absorption materialsAdvanced Antenna and Metasurface Technologies

Tailoring the mechanical properties of 2D materials and heterostructures

Charalampos Androulidakis、Kaihao Zhang、Matthew Robertson 等 4 位作者2018-05-232D Materials

Abstract The mechanical behavior of high quality two-dimensional (2D) crystals offers exciting opportunities for new material design, such as the combination of extremely high in-plane stiffness and bending flexibility, compared to existing three-dimensional (3D) material forms. By combining different 2D crystals vert…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Recent Advances and Progress on Melanin-like Materials and Their Biomedical Applications

Long Huang、Meiying Liu、Hongye Huang 等 6 位作者2018-05-23Biomacromolecules

Melanins are well-known biopolymers that are ubiquitous in nature, distributed widely in microorganisms, plants, and animals, and play significant physiological roles. They are mostly biopolymers formed from phenolic compounds by polymerization via quinones. Poly(dopamine) (PDA), a melanin-like material, is similar in…

Gold and Silver Nanoparticles Synthesis and Applicationsmelanin and skin pigmentationPhotochromic and Fluorescence Chemistry

Quenching of the red Mn4+ luminescence in Mn4+-doped fluoride LED phosphors

Tim Senden、Relinde J. A. van Dijk‐Moes、Andries Meijerink2018-05-23OpenAlex

Abstract Red-emitting Mn 4+ -doped fluorides are a promising class of materials to improve the color rendering and luminous efficacy of white light-emitting diodes (w-LEDs). For w-LEDs, the luminescence quenching temperature is very important, but surprisingly no systematic research has been conducted to understand th…

Luminescence Properties of Advanced MaterialsSolid State Laser TechnologiesInorganic Fluorides and Related Compounds

Development and In Vitro Characterization of Paclitaxel Loaded Solid Lipid Nanoparticles

Radhakrishnan Nithya、Karthik Siram、R. Hariprasad 等 4 位作者2018-05-22Current Nanomedicine

Background: Paclitaxel (PTX) is a potent anticancer drug which is highly effective against several cancers. Solid lipid nanoparticles (SLNs) loaded with anticancer drugs can enhance its toxicity against tumor cells at low concentrations. Objective: To develop and characterize SLNs of PTX (PSLN) to enhance its toxicity…

Nanoparticle-Based Drug DeliveryLipid Membrane Structure and BehaviorAdvancements in Transdermal Drug Delivery

Molecular symmetry effects on the stability of highly ordered smectic phases

David Ester、Vance E. Williams2018-05-22Liquid Crystals

David F. Estera & Vance E. Williams*aa Department of Chemistry, Simon Fraser University, Burnaby, CanadaCONTACT Vance E. Williams vancew@sfu.caABSTRACTIn an effort to control the phase ranges of highly ordered smectic phases, we examined the impact of molecular symmetry on phase behaviour of a series of 12 symmetrical…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Carbon nanofiber reinforced thermoplastic elastomer based on polypropylene/polybutadiene blend: theoretical modeling of Young’s modulus of the nanocomposites with respect to the orientation and agglomeration of carbon nanofiber

P. Sreedevi、M. A. Shadiya、Joseph Rani2018-05-22Journal of Polymer Engineering

Abstract The effect of the concentration of carbon nanofibers (CNFs) on thermoplastic elastomer based on polypropylene/polybutadiene (PP/BR) blend (80/20) prepared by melt blending process was investigated. The morphological properties are reported in combination with the mechanical and rheological properties of the n…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced CompositesDielectric materials and actuators

Stable iodide doping induced by photonic curing for carbon nanotube transparent conductive films

Atsushi Wachi、Hiroyuki Nishikawa、Ying Zhou 等 4 位作者2018-05-22Japanese Journal of Applied Physics

Abstract Doping has become crucial for achieving stable and high-performance conductive transparent carbon nanotube (CNT) films. In this study, we systematically investigate the doping effects of a few materials including alkali metal iodides, nonmetal iodide, and metals. We demonstrate that photonic curing can enhanc…

Carbon Nanotubes in CompositesThin-Film Transistor TechnologiesPhotonic Crystals and Applications

Associative Polymer‐grafted Magnetic Nanoparticles for Stabilization and Recovery of Pickering Emulsions

Sang Koo Choi、Han Am Son、Dae-Hwan Park 等 4 位作者2018-05-22Bulletin of the Korean Chemical Society

Herein we introduce a smart Pickering emulsion fluid system, in which associative magnetic nanoparticles (AMNPs) are assembled at the oil–water interface to give magnetic‐responsiveness to the emulsion drops. AMNPs are synthesized by grafting hydrophobically modified water‐soluble poly(2‐methacryloyloxyethylphosphoryl…

Surface Modification and SuperhydrophobicityMicro and Nano RoboticsPickering emulsions and particle stabilization

Comparison of two substrate materials used as negative control in endothelialization studies: Glass versus polymeric tissue culture plate

Anne Krüger‐Genge、Christian Schulz、Karl Kratz 等 5 位作者2018-05-22Clinical Hemorheology and Microcirculation

The endothelialization of synthetic surfaces applied as cardiovascular implant materials is an important issue to ensure the anti-thrombotic quality of a biomaterial. However, the rapid and constant development of a functionally-confluent endothelial cell monolayer is challenging. In order to investigate the compatibi…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Fabrication of hollow boron-doped diamond nanostructure via electrochemical corrosion of a tungsten oxide template

Young-Kyun Lim、Eung-Seok Lee、Choong-Hyun Lee 等 4 位作者2018-05-22Nanotechnology

Abstract In the study, a hollow boron-doped diamond (BDD) nanostructure electrode is fabricated to increase the reactive surface area for electrochemical applications. Tungsten oxide nanorods are deposited on the silicon substrate as a template by the hot filament chemical vapor deposition (HFCVD) method. The template…

Electrocatalysts for Energy ConversionDiamond and Carbon-based Materials ResearchElectrochemical Analysis and Applications

Ursache der Photolumineszenzverstärkung in Gold‐dotierten Silber‐Nanoclustern: Beiträge relativistischer Effekte und heteronuklearer Gold‐Silber‐Bindungen

Xiaoying Xie、Pin Xiao、Xiaoyan Cao 等 6 位作者2018-05-22Angewandte Chemie

Abstract Die schwache Photolumineszenz von Silber‐Nanoclustern verhindert ihre breite Anwendung als lumineszenter Nanowerkstoff. In jüngerer Zeit haben Experimente jedoch gezeigt, dass eine Au‐Dotierung die Intensität der Photolumineszenz von Ag 29 ‐Nanoclustern signifikant verstärken kann, wobei die molekularen und p…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Gold surface plasmon crystal structure based‐on polystyrene template for biosensor application

Min‐Zhuo Cheng、Jing Zhang、Dequan Bao 等 4 位作者2018-05-22Electrophoresis

In this communication, we assembled ordered polystyrene (PS) microsphere array as a template with the drop-coating method, and the oxygen plasma was used to etch the template to adjust the spacing between the PS microspheres. Nano-triangular gold array and silver nano-pyramid array were obtained by ion beam sputtering…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNanofabrication and Lithography Techniques

Effects of Milling Time on the Hydrogen Storage Properties of Mg-based Transition Metals-added Alloys

Hye Ryoung Park、Sung Nam Kwon、Myoung Youp Song2018-05-22Materials Science

In this work, Mg was employed as a starting material. Ni, Fe and Ti were selected as additives to improve hydriding and dehydriding rates of Mg. A 90 wt.% Mg + 5 wt.% Ni + 2.5 wt.% Fe + 2.5 wt.% Ti sample [named 90Mg-Ni-Fe-Ti (8 h)] was prepared by mechanical grinding under H2 atmosphere (reactive mechanical grinding)…

Hydrogen Storage and MaterialsHybrid Renewable Energy SystemsAmmonia Synthesis and Nitrogen Reduction