Materials Literature
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We study thermal properties of SrMnO3 starting from analysis of the low-energy electronic structure of the Mn4+ ion in oxygen surroundings. As a start point of the studies, simulations of a SrMnO3 unit cell were performed with using the density functional theory (DFT). The DFT calculations have revealed ionic characte…
Two staining methods of wood flour/polypropylene composites in an attempt to improve the color stability of wood‐plastic composites (WPCs) were investigated. The first was to dye wood flour (WF) before compounding with polypropylene (PP) to make stained composites. The second method involved mixing pigments directly w…
The negatively charged nitrogen-vacancy colour center (NV(-) center) in nanodiamond is an excellent single photon source due to its stable photon generation in ambient conditions, optically addressable nuclear spin state, high quantum yield and its availability in nanometer sized crystals. In order to make practical d…
Summary The soil on mofette sites is affected by ascending geogenic carbon dioxide ( CO 2 ), which partially fills the soil atmosphere. We hypothesized that geogenic CO 2 affects the stabilization of soil organic matter ( SOM ) at lower partial pressures than had been discussed previously for mofette sites. We studied…
Using Raman spectral-mapping, we investigated in situ temperature dependence (100–300 K) of strain and doping of isotopically labelled double-layer graphene, which allows us to simultaneously and independently follow the strain and doping in both layers of the double layer. We find that the strain in both layers of th…
Three new N-benzylideneaniline derivatives [p-nitrobenzylidene-p-phenylamineaniline (I), 2,4-dinitrobenzylidene-p-phenylamineaniline (II) and p-dinitrobenzylidene-p-diethylamineaniline (III)] containing electron-push-pull groups have been prepared. They present a planar N-benzylideneaniline core and neighbouring funct…
We obtained a new strontium germanide (SrGe3) by high-pressure and high-temperature synthesis. It was prepared at 13 GPa and 1100 °C. The space group and cell constants are I4/mmm (No. 139), a = 7.7800(8) Å, c = 12.0561(13) Å, and V = 729.74(17) Å(3). SrGe3 crystallizes in the CaSi3 structure composed of Ge-Ge dumbbel…
The possibility of combining the hardness of diamond with the toughness of WC–Co has attracted a great attention toward the deposition of diamond films on WC–Co substrates due to their potential industrial applications. However, the performance of diamond coated WC–Co machining tools is limited by the coating‐substrat…
Combinations of stearic acid (SA) and organic inhibitor benzotriazole (BTAH) or 2‐mercaptobenzimidazole (2‐MBI) were studied as corrosion inhibitors of brasses Cu10Zn and Cu40Zn and of Zn in simulated urban rain. In Part I, where self‐assembled layers of individual inhibitors (BTAH, 2‐MBI and SA) were studied, the SA…
Abstract Octabromophenylethyl‐functionalized silsesquioxane (BrPh‐SQ) was synthesized by the Friedel–Crafts alkylation of octavinylsilsesquioxane (OVS) with bromobenzene, which acted as both the solvent and reactant and, furthermore, could be recycled after the reaction. The approach possesses the advantages of being…
We theoretically study the absorption property of graphene manipulated by a dielectric cylinder through an analytical method. The distinctive absorption properties of incident waves with different polarizations (TM and TE) are analyzed and they are strongly correlated with the structure resonance and material dispersi…
The ease of preparation as well as the fine tuning of their chemical composition makes layered double hydroxides (LDH) very attractive for a large variety of applications. The aim of this feature article is to provide the keys that permit to finely tune the structure of the materials in controlling simple parameters i…
N,N'-diacetylbacillosamine is a novel sugar that plays a key role in bacterial glycosylation. Three enzymes are required for its biosynthesis in Campylobacter jejuni starting from UDP-GlcNAc. The focus of this investigation, PglE, catalyzes the second step in the pathway. It is a PLP-dependent aminotransferase that co…
The research was planned to test electrical properties of polymer films made from polyurethane cationomers with 0–2 wt.% graphene admixture. The cationomers were synthetized in the reaction of 4,4′-methylenebis(phenyl isocyanate), polycaprolactone diol ( M = 2000), N -methyldiethanolamine, and formic acid. It was foun…
Summary Flame retardancy of fabrics consisting of modacrylic fiber containing with various dispersed metal compounds and cellulosic fiber has been investigated by means of flame test (ISO15025 procedure A) and limiting oxygen index (LOI). It has been found that excellent flame retardancy is achieved by fine‐grained Mo…
INTRODUCTION: Major advances in carrier-mediated agents (CMAs), which include nanoparticles and conjugates, have revolutionized drug delivery capabilities over the past decade. While providing numerous advantages such as increased exposure duration, greater solubility and delivery to tumor sites over their small molec…
The synthesis of fac-[Ir{N,C1′-(2,2′-NC5H4C6H3-5′-C≡C-1-C6H2-3,5-Et2-4-C≡CC6H4-4-C≡CH)}3] (10), which bears pendant ethynyl groups, and its reaction with [RuCl(dppe)2]PF6 to afford the heterobimetallic complex fac-[Ir{N,C1′-(2,2′-NC5H4C6H3-5′-C≡C-1-C6H2-3,5-Et2-4-C≡CC6H4-4-C≡C-trans-[RuCl(dppe)2])}3] (11) is described…
Perovskite oxide heteroepitaxy is realized on the top of inorganic nanosheets that are covering the amorphous oxide surfaces of Si substrates. Utilizing pulsed laser deposition, thin films of SrRuO 3 in a (001) pc and (110) pc orientation on nanosheets of Ca 2 Nb 3 O 10 and Ti 0.87 O 2 are grown, respectively. The two…
We present a detailed spectroscopic investigation of CaF2 doped with Yb(2+) performed at high hydrostatic pressure which is applied in a diamond anvil cell. At ambient pressure and at temperatures lower than 175 K, the luminescence consists of a single broad band peaked at 18 500 cm(-1), attributed to the recombinatio…
Polymeric nanoparticles have many advantages as the reinforcing filler of rubber. To investigate the mechanism of the reinforcement, nanocomposites of poly(styrene‐butadiene) rubber (SBR) filled with polystyrene (PS) particles as the reinforcing agents was prepared. Morphology and dynamical mechanical properties of PS…