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Graphene FETs With Aluminum Bottom-Gate Electrodes and Its Natural Oxide as Dielectrics

Wei Wei、Xin Zhou、Geetanjali Deokar 等 9 位作者2015-08-13IEEE Transactions on Electron Devices

In this paper, we present a fabrication process of graphene field effect transistors (GFETs) using natural oxidation of aluminum as dielectrics, which provide an alternative fabrication choice for future flexible electronics with the large scale and arbitrary substrates. The high-quality monolayer graphene is preserve…

Graphene research and applications2D Materials and ApplicationsQuantum and electron transport phenomena

Effect of trace magnesium on carbide improvement in H13 steel

Jiansheng Li、J. Li、Jiansheng Li 等 8 位作者2015-08-13Canadian Metallurgical Quarterly

In the present work, the carbides and inclusions in H13 steel with different magnesium contents were investigated with the scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), and were calculated by the ThermoCalc and FactSage softwares, respectively. The growth of the MgAl2O4 spinel and Al2O3 at…

High-Temperature Coating BehaviorsAdvanced materials and compositesMetal Alloys Wear and Properties

Effect of Ozone Treatment on Nano-Sized Silver Sulfide in Wastewater Effluent

Basilius Thalmann、Andreas Voegelin、Urs von Gunten 等 6 位作者2015-08-13Environmental Science & Technology

Silver nanoparticles used in consumer products are likely to be released into municipal wastewater. Transformation reactions, most importantly sulfidation, lead to the formation of nanoscale silver sulfide (nano-Ag2S) particles. In wastewater treatment plants (WWTP), ozonation can enhance the effluent quality by elimi…

Nanoparticles: synthesis and applicationsHealthcare and Environmental Waste Management

Quantitative Microstructure and Defect Density Analysis of Polycrystalline Tungsten Reference Samples after Different Heat Treatments

A. Manhard、M. Balden、S. Elgeti2015-08-13Practical Metallography

Abstract In order to provide a solid basis for the correlation of microstructure and hydrogen isotope retention in tungsten, reference samples with different microstructures were prepared from a single batch of polycrystalline tungsten by standardised polishing and heat treatment procedures. Representative samples wer…

Fusion materials and technologiesNuclear Materials and PropertiesAdvanced materials and composites

Influence of the Main-Chain Configuration on the Mechanical Properties of Linear Aliphatic Polyesters

Mark P. F. Pepels、Leon E. Govaert、R. Duchateau2015-08-13Macromolecules

Linear aliphatic polyesters have been investigated extensively over the last decades. However, the relation between the configuration of the ester groups in the main chain and the mechanical properties is only poorly understood. Therefore, in this work the influence of the composition of these polymers on the morpholo…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Water and magmas: insights about the water solution mechanisms in alkali silicate melts from infrared, Raman, and 29Si solid-state NMR spectroscopies

Charles Le Losq、Bjørn O. Mysen、George D. Cody2015-08-13Progress in Earth and Planetary Science

Degassing of water during the ascent of hydrous magma in a volcanic edifice produces dramatic changes in the magma density and viscosity. This can profoundly affect the dynamics of volcanic eruptions. The water exsolution history, in turn, is driven by the water solubility and solution mechanisms in the silicate melt.…

Geological and Geochemical AnalysisHigh-pressure geophysics and materialsGlass properties and applications

Ruthenium(II) and Osmium(II) Vinyl Complexes as Highly Sensitive and Selective Chromogenic and Fluorogenic Probes for the Sensing of Carbon Monoxide in Air

Anita Toscani、Cristina Marín‐Hernández、María E. Moragues 等 9 位作者2015-08-13Chemistry - A European Journal

The detection of carbon monoxide in solution and air has been achieved using simple, inexpensive systems based on the vinyl complexes [M(CHCHR)Cl(CO)(BTD)(PPh3 )2 ] (R=aryl, BTD=2,1,3-benzothiadiazole). Depending on the nature of the vinyl group, chromogenic and fluorogenic responses signalled the presence of this od…

Molecular Sensors and Ion DetectionMass Spectrometry Techniques and ApplicationsPorphyrin and Phthalocyanine Chemistry

First-principles study on phase transition and ferroelectricity in lithium niobate and tantalate

Kazuaki Toyoura、Masataka Ohta、Atsutomo Nakamura 等 4 位作者2015-08-13Journal of Applied Physics

The phase transitions and ferroelectricity of LiNbO3 and LiTaO3 have been investigated theoretically from first principles. The phonon analyses and the molecular dynamics simulations revealed that the ferroelectric phase transition is not conventional displacive type but order-disorder type with strong correlation bet…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsMicrowave Dielectric Ceramics Synthesis

Manganese porphyrin functionalized on Fe 3 O 4 @ n SiO 2 @MCM-41 magnetic composite: Structural characterization and catalytic activity as cytochrome P450 model

Fabrício B. Zanardi、Isaltino A. Barbosa、Paulo C. de Sousa Filho 等 7 位作者2015-08-13Microporous and Mesoporous Materials

This study reports on the preparation of heterogeneous catalysts with two different pore sizes, the Fe3O4@nSiO2@MCM-41-MnP and Fe3O4@nSiO2@MCM-41(E)-MnP catalysts. Such systems ally the catalytic properties of metalloporphyrins (MeP) with the magnetic properties of magnetite nanoparticles (Fe3O4) in a mesoporous MCM-4…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsSurface Chemistry and Catalysis

Disposal Options of Bamboo Fabric-Reinforced Poly(Lactic) Acid Composites for Sustainable Packaging: Biodegradability and Recyclability

M. R. M. Fazita、Krishnan Jayaraman、Debes Bhattacharyya 等 6 位作者2015-08-13Polymers

The present study was conducted to determine the recyclability and biodegradability of bamboo fabric-reinforced poly(lactic) acid (BF-PLA) composites for sustainable packaging. BF-PLA composite was recycled through the granulation, extrusion, pelletization and injection processes. Subsequently, mechanical properties (…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Cure Kinetics of Nanodiamond-Filled Epoxy Resin: Influence of Nanodiamond Surface Functionality

Atousa Aris、Akbar Shojaei、Reza Bagheri2015-08-13Industrial & Engineering Chemistry Research

Thermally oxidized nanodiamond (OND), amine-functionalized ND (AND) and untreated ND (UND) were added to epoxy/TETA at 1 wt % loading. The ND enhanced the dynamic storage modulus of epoxy while decreasing the glass transition temperature because of the increment of free volume in the vicinity of the ND surfaces. The N…

Diamond and Carbon-based Materials ResearchEpoxy Resin Curing ProcessesThermal and Kinetic Analysis

Nanoscale Order and Crystallization in POSS–PCL Shape Memory Molecular Networks

Bonifacio Alvarado‐Tenorio、Angel Romo‐Uribe、Patrick T. Mather2015-08-13Macromolecules

The angstrom- and nanometer-scale crystallization and long-range ordering behavior of polyhedral oligosilsesquioxane–poly(ε-caprolactone) (POSS–PCL) shape memory nanocomposites under thermomechanical shape memory cycles and uniaxial stretching were studied by simultaneous wide-angle and small-angle X-ray scattering (W…

Polymer composites and self-healingMarine Biology and Environmental ChemistrySilicone and Siloxane Chemistry

Effect of Support Preparation and Nanoparticle Size on Catalyst–Support Interactions between Pt and Amorphous Silica

Christopher Ewing、Götz Veser、J. J. McCarthy 等 5 位作者2015-08-13The Journal of Physical Chemistry C

The interaction between catalytic nanoparticles (NPs) and their supports, which are often amorphous oxides, has not been well characterized at the atomic level, although it is known that, in some cases, NP–support interactions dominate the catalytic activity of the system. Furthermore, there is a lack of understanding…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceQuantum Dots Synthesis And Properties

Formation of broadband antireflective and superhydrophilic subwavelength structures on fused silica using one-step self-masking reactive ion etching

Xin Ye、Xiaodong Jiang、Jin Huang 等 8 位作者2015-08-13Scientific Reports

Fused silica subwavelength structures (SWSs) with an average period of ~100 nm were fabricated using an efficient approach based on one-step self-masking reactive ion etching. The subwavelength structures exhibited excellent broadband antireflection properties from the ultraviolet to near-infrared wavelength range. Th…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Impact of Carbon Nano-Onions on Hydra vulgaris as a Model Organism for Nanoecotoxicology

Valentina Marchesano、Alfredo Ambrosone、Juergen Bartelmess 等 8 位作者2015-08-13Nanomaterials

The toxicological effects of pristine and chemically modified carbon nano-onions (CNOs) on the development of the freshwater polyp Hydra vulgaris were investigated in order to elucidate the ecotoxicological effects of CNOs. Chemical modifications of the CNOs were accomplished by surface functionalization with benzoic…

Carbon Nanotubes in CompositesNanoparticles: synthesis and applicationsGraphene and Nanomaterials Applications

Biocompatible Collagen Paramagnetic Scaffold for Controlled Drug Release

Simona Bettini、Valentina Bonfrate、Zois Syrgiannis 等 8 位作者2015-08-13Biomacromolecules

A porous collagen-based hydrogel scaffold was prepared in the presence of iron oxide nanoparticles (NPs) and was characterized by means of infrared spectroscopy and scanning electron microscopy. The hybrid scaffold was then loaded with fluorescein sodium salt as a model compound. The release of the hydrosoluble specie…

Bone Tissue Engineering MaterialsNanoparticle-Based Drug DeliveryElectrospun Nanofibers in Biomedical Applications

Structural Characterisation of Complex Layered Double Hydroxides and TGA‐GC‐MS Study on Thermal Response and Carbonate Contamination in Nitrate‐ and Organic‐Exchanged Hydrotalcites

Eleonora Conterosito、Luca Palin、Diego Antonioli 等 9 位作者2015-08-13Chemistry - A European Journal

Layered double hydroxides (LDHs) are versatile materials used for intercalating bioactive molecules in the fields of pharmaceuticals, nutraceuticals and cosmetics, with the purpose of protecting them from degradation, enhancing their water solubility to increase bioavailability and improving their pharmacokinetic prop…

Mesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and ApplicationsPhosphorus and nutrient management

Visible‐Light‐Driven Photoisomerization and Increased Rotation Speed of a Molecular Motor Acting as a Ligand in a Ruthenium(II) Complex

Sander J. Wezenberg、Kuang‐Yen Chen、Ben L. Feringa2015-08-13Angewandte Chemie International Edition

Toward the development of visible-light-driven molecular rotary motors, an overcrowded alkene-based ligand and the corresponding ruthenium(II) complex is presented. In our design, a 4,5-diazafluorenyl coordination motif is directly integrated into the motor function. The photochemical and thermal isomerization behavio…

Supramolecular Chemistry and ComplexesPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Bioactive Electrospun Fibers of Poly(glycerol sebacate) and Poly(ε‐caprolactone) for Cardiac Patch Application

Ranjana Rai、Marwa Tallawi、Caterina Frati 等 14 位作者2015-08-13Advanced Healthcare Materials

Scaffolds for cardiac patch application must meet stringent requirements such as biocompatibility, biodegradability, and facilitate vascularization in the engineered tissue. Here, a bioactive, biocompatible, and biodegradable electrospun scaffold of poly(glycerol sebacate)-poly(ε-caprolactone) (PGS-PCL) is proposed as…

Electrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative MedicineCardiac Structural Anomalies and Repair

Bioinspired Hybrid White Light‐Emitting Diodes

Michael Weber、Lukas Niklaus、Marlene Pröschel 等 6 位作者2015-08-13Advanced Materials

The first bioinspired hybrid white-light-emitting diodes (bio-HLEDs) featuring protein cascade coatings are presented. For easy fabrication a new strategy to stabilize proteins in rubber-like material was developed. The synergy between the excellent features of fluorescent proteins and the easily processed rubber prod…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesAdvanced Sensor and Energy Harvesting Materials