Materials Literature
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Solid‐state reactions have the potential for direct preparation of ceramic powders and offer a low‐temperature and low‐cost alternative to conventional techniques for production of oxide powders. This paper describes a simple and effective mechanochemical method based on solid‐state reactions during ball milling for s…
A new lattice gas model has been developed, describing the hydrogen storage in hydride-forming materials. This model is based on the mean-field theory and Bragg-Williams approximation. To describe first-order phase transitions and two-phase coexistence regions, a binary alloy approach has been adopted. A complete set…
Starre und stabförmige helicale Polyacetylen-Moleküle ordnen sich in Gegenwart von Lösungsmitteldämpfen hierarchisch auf Graphit an. Eine Monoschicht aus flach auf der Graphitoberfläche aufliegenden Polyacetylen-Molekülen dient als Fundament für helicale Polyacetylen-Moleküle, die chirale 2D-Bündel mit bestimmter Heli…
In this work we report on a low-energy electron diffraction (LEED) study of $\mathrm{MnO}(100)$ thick films grown on $\mathrm{Ag}(100)$ in order to determine their surface geometry. The LEED results indicate a topmost layer rumple of $(4.8\ifmmode\pm\else\textpm\fi{}2.0)%$ with the oxygen ions moving towards the vacuu…
Combustion synthesis (CS) of α‐silicon nitride (Si 3 N 4 ) powders was accomplished at a nitrogen pressure lower than 3 MPa. The combination of mechanical activation and chemical stimulation was effective in enhancing the reactivity of Si powder reactants, which was responsible for the reduction of the minimum nitroge…
A comprehensive numerical model of an indirect internal reforming tubular Solid Oxide Fuel Cell (IIR-T-SOFC) has been developed. Two-dimensional axisymmetry of the velocity, temperature, and mass transfer fields was assumed in the model, but accommodating the peripheral nonuniformity of electric potential and electric…
We calculate the guided band diagram of a metallic film with a one-dimensional periodic arrangement of cut-through subwavelength slits. We find that this system supports two distinct types of guided modes propagating in a direction perpendicular to the slits when the metal obeys a plasmonic dispersion model. The first…
A simple, efficient, and novel method was developed for the direct preparation of hydrophilic, bamboo-shaped carbon nanotubes by the pyrolysis of ruthenium(III) acetylacetonate in a Swagelock cell is reported. The obtained product exhibits mostly bamboo-shaped, straight, periodic twisted, multiwalled carbon nanotubes…
Amine functionalities were introduced onto the surface of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) films by applying radio frequency ammonia plasma treatment and wet ethylenediamine treatment. The modified surfaces were characterized by X-ray photoelectron spectroscopy (XPS) for chemical composition and Ram…
Silicon nanoparticles ranging from 2 to 16 nm were synthesized by a facile wet chemical route, in which SiO amorphous powder was annealed at 1000 °C, etched in hydrofluoric acid, and surface modified by alkene. After alkyl-termination of the particle surfaces, size selective precipitation technique was applied to sepa…
Syntheses of the four mixed phenol-pyridine derivatives 1,6-bis(2-hydroxyphenyl)pyridyl boron naphthalene (1), 1,6-bis(2-hydroxy-5-methylphenyl)pyridyl boron naphthalene (2), 1,6-bis(2-hydroxyphenyl)pyridyl boron 2-methoxylbenzene (3), and 1,6-bis(2-hydroxy-5-methylphenyl)pyridyl boron 2-methoxylbenzene (4) are report…
Despite the widespread use of gamma-Al2O3, there is still considerable disagreement over the nature of its structure due to both its poor crystallinity and differing preparation techniques during experimentation. Using density-functional theory (DFT) calculations and Rietveld simulations and refinement, the structure…
Abstract A combined approach towards ductile damage and fracture is presented, in the sense that a continuous material degradation is coupled with a discrete crack description for large deformations. Material degradation is modelled by a gradient enhanced damage‐hyperelastoplasticity model. It is assumed that failure…
The atomic-scale structure of nanocrystalline Ba x Sr 1 - x TiO 3 ( x = 1, 0.5, 0) powders has been studied using high-energy X-ray diffraction, Rietveld refinement, and the atomic pair distribution function technique. The studies show that the materials are well-ordered at nanometer length distances. The three-dimens…
Hard piezoelectrics with high dielectric and piezoelectric constants are used for high‐power applications. However, the sintering temperature of these ceramics is high, around 1200°C, restricting the usage of cheap base metal electrodes in fabrication of multi‐layer components. This study investigates the effect of Cu…
The recombination dynamics of zinc-blende-type, deep-red emitting CdTe/CdS core-shell nanocrystals is studied over a wide temperature range. Two characteristic decay regimes are found: a temperature-dependent decay component of a few nanoseconds and a long-living temperature-independent component of approximately 315…
We demonstrate the sphere organization of ZnO, Bi2S3, MnO2, and La(OH)3 nanorods directed by PEG linear polymer. Our study shows that zinc, bismuth, manganese, or lanthanum species added to PEG solutions, in which PEG molecules are well dissolved in a coil state, convert the polymer coils to aggregate structures, whic…
Gold-selective adsorbents were prepared from mesoporous MCM-41 silica by grafting organic amine groups (i.e., RNH2, R2NH, and R3N; R=propyl). NH2-MCM-41, NRH-MCM-41, and NR2-MCM-41 displayed strong affinity for gold and at 1 mmol/g loading adsorbed 0.40, 0.33, and 0.20 mmol/g of gold. Copper and nickel were not adsorb…
The release of the water-soluble drug Captopril is controlled by tailoring the surface properties of mesoporous silica via stepwise silylation. The degree of silylation is manipulated by adjusting the initial concentration of silylanizing reagent (trimethylchlorosilane, TMCS). The silylanized and drug-loaded samples a…
Nanocrystalline MAl 2 O 4 (M=Co, Ni, Cu, Zn) spinel powders are synthesized by pyrolysis of complex compounds of aluminum and transition metal (cobalt, nickel, copper, and zinc) with triethanolamine (TEA). The precursor materials are formed on complete dehydration of the soluble complexes of aluminum–TEA and transitio…