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Microwave-assisted synthesis of novel mixed tail rufigallol derivatives

Shilpa Setia、Akash Soni、Monika Gupta 等 5 位作者2013-06-25Liquid Crystals

Microwave-assisted syntheses of five new series of rufigallol-based mesogens are reported with branched alkyl chains at the peripheral positions. The chemical structures of these newly synthesised compounds were determined by 1H nuclear magnetic resonance (NMR), 13C NMR, infrared spectroscopy, ultraviolet spectroscopy…

Liquid Crystal Research AdvancementsMesoporous Materials and CatalysisPhotochemistry and Electron Transfer Studies

Ion-beam sputtering deposition and magnetoelectric properties of layered heterostructures (FM/PZT/FM)n, where FM – Co or Ni78Fe22

A. I. Stognij、Nikolai N. Novitskii、A. Sazanovich 等 9 位作者2013-06-25The European Physical Journal Applied Physics

Magnetoelectric properties of layered heterostructures (FM/PZT/FM)n (n≤ 3) obtained by ion-beam sputtering deposition of ferromagnetic metal (FM), where FM is the cobalt (Co) or permalloy Ni78Fe22, onto ferroelectric ceramic based on lead zirconate titanate (PZT) have been studied. The polished ferroelectric plates in…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsUnderwater Acoustics Research

Enhanced white photoluminescence in silicon-rich oxide/SiO_2 superlattices by low-energy ion-beam treatment

Chuan‐Feng Shih、Chu-Yun Hsiao、K. W. Su2013-06-25Optics Express

This study presents the crystalline and luminescence properties of silicon-rich oxide (SRO)/SiO2 superlattices in which the SRO layers were prepared with a low-energy (<60 eV) argon ion-beam treatment. Experimental results evidenced that density of the Si nanocrystals (NCs) in the SRO layer was increased by ion-beam t…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceIon-surface interactions and analysis

Electrical control of the spin polarization of a current in “pure-carbon” systems based on partially hydrogenated graphene nanoribbon

Yan-Dong Guo、Xiaohong Yan、Yang Xiao2013-06-25Journal of Applied Physics

Controlling a spin current by electrical means and eliminating the use of ferromagnetic contacts becomes a focus of research in spintronics, as compared with conventional magnetic control methods, electrical one could reduce the dimensions and energy consumption of integrated devices. Inspired by recent progress of co…

Advancements in Battery MaterialsGraphene research and applicationsQuantum and electron transport phenomena

The graphene/Au/Ni interface and its application in the construction of a graphene spin filter

А. А. Рыбкина、А. Г. Рыбкин、V. K. Adamchuk 等 7 位作者2013-06-25Nanotechnology

A modification of the contact of graphene with ferromagnetic electrodes in a model of the graphene spin filter allowing restoration of the graphene electronic structure is proposed. It is suggested for this aim to intercalate into the interface between the graphene and the ferromagnetic (Ni or Co) electrode a Au monol…

Graphene research and applicationsQuantum and electron transport phenomenaMolecular Junctions and Nanostructures

Nanotopography of collagen thin films in correlation with fibroblast response

Andreas Stylianou、Dido Yova、Eleni Alexandratou2013-06-25Journal of Nanophotonics

Collagen thin films consisting of randomly oriented and oriented collagen fibrils/fibers are fabricated by hydrodynamic flow and spin coating, and then they are characterized by atomic force microscopy (AFM). Fibroblasts are cultured on these films in order to correlate their morphology and alignment, which are assess…

Bone Tissue Engineering MaterialsMarine Biology and Environmental ChemistryCollagen: Extraction and Characterization

SnO2–CuO–NaCl/SiO2 Catalysts for Propylene Epoxidation

Aaron Miller、Bahman Zohour、Anusorn Seubsai 等 5 位作者2013-06-25Industrial & Engineering Chemistry Research

The discovery of heterogeneous catalysts capable of direct gas-phase production of propylene oxide (PO) from propylene and molecular oxygen remains a challenge in industrial catalysis. The SnO 2 –CuO–NaCl/SiO 2 system has been shown to produce PO at 55–60% selectivity with propylene conversion of 1% at 250 °C and 1 ba…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Characterization of oil palm ash (OPA) and thermal properties of OPA-filled natural rubber compounds

Zhong Xian Ooi、H. Ismail、Azhar Abu Bakar2013-06-25Journal of Elastomers & Plastics

In the present study, characterization and morphological study of oil palm ash (OPA) and thermal properties of OPA-filled natural rubber (NR) compounds were carried out. The morphological study revealed that the OPA particle was irregular with rough surface and porous structure. Energy dispersive x-ray analysis and an…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

Subcell misalignment in vertically cascaded metamaterial absorbers

Qin Chen、Fuhe Sun、Shichao Song2013-06-25Optics Express

Metamaterial has demonstrated exotic electromagnetic (EM) properties and various applications, for example perfect absorbers. Cascaded perfect absorbers further extend the spectral engineering ability. Perfect alignment of subcells was usually presumed in previous studies. We numerically investigated the effect of lat…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Molecular Length Dependence of Single Molecule Wobbling within Surfactant- and Solvent-Filled Silica Mesopores

Rajib Pramanik、Takashi Ito、Daniel A. Higgins2013-06-25The Journal of Physical Chemistry C

The confined orientational motions of fluorescent dye molecules diffusing along one dimension (1D) within individual silica mesopores are investigated by simultaneous single molecule tracking (SMT) and single molecule emission dichroism (SMED) methods. Four perylene diimide (PDI) dyes of different lengths are employed…

Mesoporous Materials and CatalysisPorphyrin and Phthalocyanine ChemistrySpectroscopy and Quantum Chemical Studies

Plasma Fluorination of Vertically Aligned Carbon Nanotubes

Nayan Jyoti Saikia、Chris Ewels、Jean‐François Colomer 等 10 位作者2013-06-25The Journal of Physical Chemistry C

Functionalization of vertically aligned multiwalled carbon nanotube carpets was performed via exposure to CF 4 or Ar:F 2 RF plasmas. Rapid fluorination was observed via X-ray photoelectron spectroscopy (XPS) with surface fluorine concentration, bonding type, and patterning dependent on gas mixture and exposure time. S…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Effective models for strong correlations and edge magnetism in graphene

Manuel Schmidt、Michael Golor、Thomas C. Lang 等 4 位作者2013-06-25Physical Review B

We describe a method for deriving effective low-energy theories of electronic interactions at graphene edges. Our method is applicable to general edges of honeycomb lattices (zigzag, chiral, and even disordered) as long as localized low-energy states (edge states) are present. The central characteristic of the effecti…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Enhancement in solar cell efficiency by luminescent down-shifting layers

Hind Ahmed、James Walshe、M. Kennedy 等 6 位作者2013-06-25Advances in Energy Research

In this paper, core-shell semiconductor quantum dots (QDs) CdSeS/ZnS with emission at 490 nm and 450 nm were investigated for their use in luminescent down-shifting (LDS) layers. Luminescent quantum yield (LQY) of the QDs measurements in solution proposed that they were suitable candidates for inclusion in LDS layers.…

TiO2 Photocatalysis and Solar CellsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

High pressure high-temperature behavior and magnetic properties of Fe4N: experiment and theory

Kai Guo、Dieter Rau、Jörg von Appen 等 8 位作者2013-06-25High Pressure Research

Under high pressure high-temperature conditions, namely 8.5(8) GPa and 1373(150) K, γ′-Fe4N (Pm3¯m) is transformed into ϵ-type Fe3N0.75. At ambient temperature, the onset of the transition is observed above 17 GPa by in situ X-ray diffraction data. The nitrogen content of Fe3N0.77(4) deduced on the basis of the observ…

Metal and Thin Film MechanicsRare-earth and actinide compoundsBoron and Carbon Nanomaterials Research

Controlled Planar Alignment of Discotic Liquid Crystals in Microchannels Made Using SU8 Photoresist

James Cattle、Peng Bao、Jonathan P. Bramble 等 7 位作者2013-06-25Advanced Functional Materials

Abstract A range of triphenylene and phthalocyanine‐based discotic liquid crystals (DLCs) can be aligned within micrometer‐scale channels formed from SU8 patterned on silicon or glass surfaces. The channels can be filled with the DLC in its isotropic phase using capillary action. Alignment occurs spontaneously as the…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsElectrowetting and Microfluidic Technologies

LC–MS/MS Identification of the O-Glycosylation and Hydroxylation of Amino Acid Residues of Collagen α-1 (II) chain from Bovine Cartilage

Ehwang Song、Yehia Mechref2013-06-25Journal of Proteome Research

O-Glycosylation of collagen is a unique type of posttranslational modifications (PTMs) involving the attachment of galactose (Gal) or glucose-galactose (Glc-Gal) moieties to hydroxylysine (HyK). Also, hydroxyproline (HyP) result from the posttranslational hydroxylation of some proline residues in collagen. Here, LC-MS…

Glycosylation and Glycoproteins ResearchProtease and Inhibitor MechanismsCollagen: Extraction and Characterization

Force Interactions of Nonagglomerating Polylactide Particles Obtained through Covalent Surface Grafting with Hydrophilic Polymers

Robertus Wahyu N. Nugroho、Torbjörn Pettersson、Karin Odelius 等 5 位作者2013-06-25Langmuir

Nonagglomerating polylactide (PLA) particles with various interaction forces were designed by covalent photografting. PLA particles were surface grafted with hydrophilic poly(acrylic acid) (PAA) or poly(acrylamide) (PAAm), and force interactions were determined using colloidal probe atomic force microscopy. Long-range…

Hydrogels: synthesis, properties, applicationsPolymer Surface Interaction StudiesForce Microscopy Techniques and Applications

Oxazolochlorins 11: Tuning the dynamic high pH sensing range of [meso-tetraarylporpholactonato]M(II) complexes by variation of the central metal ion, the aryl substituents, and introduction of a β-nitro group

Jill L. Worlinsky、Gloria Zarate、Mat­thias Zeller 等 6 位作者2013-06-25Journal of Porphyrins and Phthalocyanines

Based on the high pH-sensing ability of [meso-tetrakis(pentafluorophenyl) porpholactonato]-platinum(II), we investigated the influence of the metal ( M = Zn ( II ), Ni ( II ), Cu ( II ), Pd ( II ), Ag ( II ), Pt ( II )), the aryl group ( Ar = C 6 H 5 , C 6 F 5 ), and the presence of a β- NO 2 group on the pH sensing r…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryAnalytical Chemistry and Sensors

Phase and texture evolution in solution deposited lead zirconate titanate thin films: Formation and role of the Pt3Pb intermetallic phase

Krishna Nittala、Sungwook Mhin、Katherine M. Dunnigan 等 8 位作者2013-06-25Journal of Applied Physics

Solution deposition is widely used for the fabrication of lead zirconate titanate (PZT) thin films on platinized silicon substrates. However, phase and texture evolution during the crystallization process is not well understood, particularly due to the difficulty in tracking changes in the thin films in situ during he…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisElectronic and Structural Properties of Oxides

High-pressure phase transformation and elastic behavior of XC (X = Si, Ge, Sn and Pt) compounds

Netram Kaurav2013-06-25Physica Scripta

Pressure-induced structural aspects of ZnS-type ( B 3) to NaCl-type ( B 1) structure in XC (X = Si, Ge, Sn and Pt) compounds are presented. An effective interionic interaction potential with long-range Coulomb, van der Waals (vdW) interaction and the short-range repulsive interaction up to second-neighbor ions within…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications