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Surface polar optical phonon scattering of carriers in graphene on various substrates

I-Tan Lin、Jia‐Ming Liu2013-08-19Applied Physics Letters

The surface polar optical phonon scattering of carriers in graphene on various substrates is thoroughly studied using Rode's iteration method. The dependence of the scattering rate on carrier energy, temperature, and Fermi energy is investigated. The experimental data in the literature on the temperature dependence of…

Graphene research and applicationsQuantum and electron transport phenomenaThermal properties of materials

Ligand-Induced Changes in the Characteristic Size-Dependent Electronic Energies of CdSe Nanocrystals

Brian P. Bloom、Liu‐Bin Zhao、Yang Wang 等 7 位作者2013-08-19The Journal of Physical Chemistry C

This work explores the electronic energy of CdSe nanoparticles as a function of nanoparticle (NP) size and capping ligand. Differential pulse voltammetry was used to determine the valence band edge of CdSe NPs that are capped with three different ligands (aniline, thiophenol, and phenylphosphonic acid), and the experi…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsElectrochemical Analysis and Applications

Long-Circulating Heparin-Functionalized Magnetic Nanoparticles for Potential Application as a Protein Drug Delivery Platform

Jian Zhang、Meong Cheol Shin、Allan E. David 等 7 位作者2013-08-19Molecular Pharmaceutics

Starch-coated, PEGylated, and heparin-functionalized iron oxide magnetic nanoparticles (DNPH) were successfully synthesized and characterized in detail. The PEGylation (20 kDa) process resulted in an average coating of 430 PEG molecules per nanoparticle. After that, heparin conjugation was carried out to attain the fi…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliveryExtracellular vesicles in disease

A Technique To Pretreat Graphite Which Allows the Rapid Dispersion of Defect-Free Graphene in Solvents at High Concentration

Sebastian Barwich、Umar Khan、Jonathan N. Coleman2013-08-19The Journal of Physical Chemistry C

We have demonstrated a simple method to pretreat graphite powder resulting in a significant reduction in the time required to produce dispersions of solvent-exfoliated graphene. Sonication of graphite in either stabilizing solvents such as NMP or nonstabilizing solvents such as water results in significant breakage of…

Advancements in Battery MaterialsGraphene research and applicationsGraphene and Nanomaterials Applications

Design and implementation of a new portable thermoelectric generator for low geothermal temperatures

Raşit Ahıska、Hayati Mamur2013-08-19IET Renewable Power Generation

In this study, the design and implementation of a new portable thermoelectric generator of 100 W for low geothermal temperatures has been carried out. For this system, a new SCADA‐based testing and measuring system equipped with special software has been developed and employed for the first time. Thus, effects of the…

Advanced Thermoelectric Materials and DevicesInnovative Energy Harvesting TechnologiesThermal Radiation and Cooling Technologies

LHRH-Targeted Nanogels as a Delivery System for Cisplatin to Ovarian Cancer

N. V. Nukolova、Hardeep S. Oberoi、Yi Zhao 等 6 位作者2013-08-19Molecular Pharmaceutics

Targeted drug delivery using multifunctional polymeric nanocarriers is a modern approach for cancer therapy. Our purpose was to prepare targeted nanogels for selective delivery of chemotherapeutic agent cisplatin to luteinizing hormone-releasing hormone (LHRH) receptor overexpressing tumor in vivo. Building blocks of…

Nanoparticle-Based Drug DeliveryHydrogels: synthesis, properties, applicationsRNA Interference and Gene Delivery

Epoxidation of Soybean Oil by Continuous Micro-Flow System with Continuous Separation

Wei He、Zheng Fang、Dong Ji 等 10 位作者2013-08-19Organic Process Research & Development

In the study, the epoxidation process of soybean oil by microflow system (MFS) was investigated. With formic acid as oxygen carrier and EDTA-2Na as stabilizer, the optimal result (epoxidized soybean oil (ESO) with an epoxy number (EN) of 7.3) was obtained in such conditions: temperature 75 °C, H 2 SO 4 concentration 3…

Advanced Polymer Synthesis and CharacterizationPolymer composites and self-healingInnovative Microfluidic and Catalytic Techniques Innovation

Multiwalled Carbon Nanotube Deposition on Model Environmental Surfaces

Xiaojun Chang、Dermont Bouchard2013-08-19Environmental Science & Technology

Deposition of multiwalled carbon nanotubes (MWNTs) on model environmental surfaces was investigated using a quartz crystal microbalance with dissipation monitoring (QCM-D). Deposition behaviors of MWNTs on positively and negatively charged surfaces were in good agreement with Derjaguin-Landau-Verwey-Overbeek (DLVO) th…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsNanopore and Nanochannel Transport Studies

Proposal for all-graphene monolithic logic circuits

Jiahao Kang、Deblina Sarkar、Yasin Khatami 等 4 位作者2013-08-19Applied Physics Letters

Since the very inception of integrated circuits, dissimilar materials have been used for fabricating devices and interconnects. Typically, semiconductors are used for devices and metals are used for interconnecting them. This, however, leads to a “contact resistance” between them that degrades device and circuit perfo…

Graphene research and applicationsQuantum and electron transport phenomenaMolecular Junctions and Nanostructures

Heteroleptic Tin(II) Initiators for the Ring‐Opening (Co)Polymerization of Lactide and Trimethylene Carbonate: Mechanistic Insights from Experiments and Computations

Lingfang Wang、Christos E. Kefalidis、Sourisak Sinbandhit 等 7 位作者2013-08-19Chemistry - A European Journal

The tin(II) complexes {LO(x)}Sn(X) ({LO(x)}(-) =aminophenolate ancillary) containing amido (1-4), chloro (5), or lactyl (6) coligands (X) promote the ring-opening polymerization (ROP) of cyclic esters. Complex 6, which models the first insertion of L-lactide, initiates the living ROP of L-LA on its own, but the amido…

Organometallic Complex Synthesis and Catalysisbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Diamond nitrogen-vacancy centers created by scanning focused helium ion beam and annealing

Zhihong Huang、W.-D. Li、C. Santori 等 10 位作者2013-08-19Applied Physics Letters

We demonstrate a method to create nitrogen-vacancy (NV) centers in diamond using focused helium ion microscopy. Near-surface NV centers can be created with spatial resolution below 0.6 μm. We studied the density, creation efficiency, and spectral linewidths at optical and microwave frequencies for NV centers produced…

Diamond and Carbon-based Materials ResearchForce Microscopy Techniques and ApplicationsIon-surface interactions and analysis

Silk Fibroin/Gelatin Blend Films Crosslinked with Enzymes for Biomedical Applications

Paola Taddei、Valeria Chiono、A. Anghileri 等 6 位作者2013-08-19Macromolecular Bioscience

Microbial transglutaminase (mTG) and mushroom tyrosinase (MT) are used to crosslink B. mori silk fibroin/gelatin (SF/G) films. Crosslinked and uncrosslinked SF/G films show no phase separation. The thermal behavior and the conformational structure of SF/G films are strongly affected by blending and enzymatic treatment…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction StudiesSilk-based biomaterials and applications

Shape-Controlled Synthesis of Hollow Silica Colloids

Yong Wang、Xiaowen Su、Panshuang Ding 等 5 位作者2013-08-19Langmuir

In this work, hollow silica colloids with different shapes, such as pseudocubes, ellipsoids, capsules, and peanuts, have been synthesized through the following process: silica coating on the surface of hematite colloidal particles with different shapes (pseudocubes, ellipsoids, capsules, and peanuts) and the sequentia…

Advanced Photocatalysis TechniquesMesoporous Materials and CatalysisPickering emulsions and particle stabilization

One‐Step Formation of a Single Atomic‐Layer Transistor by the Selective Fluorination of a Graphene Film

Kuan‐I Ho、Jia‐Hong Liao、Chi‐Hsien Huang 等 9 位作者2013-08-19Small

In this study, the scalable and one-step fabrication of single atomic-layer transistors is demonstrated by the selective fluorination of graphene using a low-damage CF4 plasma treatment, where the generated F-radicals preferentially fluorinated the graphene at low temperature (<200 °C) while defect formation was suppr…

Graphene research and applicationsDiamond and Carbon-based Materials ResearchGraphene and Nanomaterials Applications

Ether-Bond-Containing Ionic Liquids as Supercapacitor Electrolytes

Anthony J. R. Rennie、Nédher Sánchez-Ramírez、Roberto M. Torresi 等 4 位作者2013-08-19The Journal of Physical Chemistry Letters

Electrochemical capacitors (ECs) are electrical energy storage devices that have the potential to be very useful in a wide range of applications, especially where there is a large disparity between peak and average power demands. The use of ionic liquids (ILs) as electrolytes in ECs can increase the energy density of…

Supercapacitor Materials and FabricationIonic liquids properties and applicationsConducting polymers and applications

Buckling behaviors of the impacted composite plates

Hasan Çallıoğlu、Emin Ergun2013-08-19Science and Engineering of Composite Materials

Abstract The aim of this experimental study is to investigate the buckling behaviors after impact of the composite plates. The increasing impact energies, which ranged from approximately 3–15 J, are performed at three different impact points of the composite plates having three different thicknesses until vicinity of…

Mechanical Behavior of CompositesHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

Fabrication of Contrast Agents for Magnetic Resonance Imaging from Polymer-Brush-Afforded Iron Oxide Magnetic Nanoparticles Prepared by Surface-Initiated Living Radical Polymerization

Kohji Ohno、Chizuru Mori、Tatsuki Akashi 等 7 位作者2013-08-19Biomacromolecules

The aim of this study is to fabricate a contrast agent for magnetic resonance imaging (MRI) by using hybrid particles composed of a core of iron oxide magnetite (Fe3O4) nanoparticles and a shell of hydrophilic polymer brush synthesized by surface-initiated (SI) living radical polymerization. To achieve this, Fe3O4 nan…

Nanoparticle-Based Drug DeliveryIron oxide chemistry and applicationsCharacterization and Applications of Magnetic Nanoparticles

Osteogenetic Properties of Electrospun Nanofibrous PCL Scaffolds Equipped With Chitosan-Based Nanoreservoirs of Growth Factors

Alice Ferrand、Sandy Eap、Ludovic Richert 等 13 位作者2013-08-19Macromolecular Bioscience

Bioactive implants intended for rapid, robust, and durable bone tissue regeneration are presented. The implants are based on nanofibrous 3D-scaffolds of bioresorbable poly-ϵ-caprolactone mimicking the fibrillar architecture of bone matrix. Layer-by-layer nanoimmobilization of the growth factor BMP-2 in association wit…

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Biogenic synthesis of nanostructured iron compounds: applications and perspectives

Amedea B. Seabra、Paula S. Haddad、Nelsón Durán2013-08-19IET Nanobiotechnology

'Green nanotechnology' has attracted increasing attention in recent years because of the possibility to reduce and/or eliminate toxic substances. Indeed, biogenic syntheses of nanomaterials, such as nanoparticles (NPs), are considered economic and valuable alternatives for the production of metallic NPs for diverse ap…

Nanoparticles: synthesis and applicationsEnvironmental remediation with nanomaterialsGraphene and Nanomaterials Applications

Gadolinium(III)‐Hydroxy Ladders Trapped in Succinate Frameworks with Optimized Magnetocaloric Effect

Yan‐Cong Chen、Fu‐Sheng Guo、Yan‐Zhen Zheng 等 10 位作者2013-08-19Chemistry - A European Journal

Two kinds of inorganic gadolinium(III)-hydroxy "ladders", [2×n] and [3×n], were successfully trapped in succinate (suc) coordination polymers, [Gd2(OH)2(suc)2(H2O)]n·2nH2O (1) and [Gd6(OH)8(suc)5(H2O)2 ]n·4n H2O (2), respectively. Such coordination polymers could be regarded as alternating inorganic-organic hybrid mat…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes